公开(公告)号：US5009872A

公开(公告)日：1991-04-23

申请号：US275188

申请日：1988-11-23

申请人： Karl T. Chuang ,  James B. McMonagle ,  Robert J. Quaiattini ,  William A. Seddon ,  David E. Clegg

发明人： Karl T. Chuang ,  James B. McMonagle ,  Robert J. Quaiattini ,  William A. Seddon ,  David E. Clegg

IPC分类号： B01J33/00 ,  A62D9/00 ,  B01D53/86 ,  B01D53/94 ,  B01J23/40 ,  B01J23/46 ,  B01J23/89 ,  B01J31/06

CPC分类号： B01J31/06 ,  B01D53/864 ,  B01D53/8668 ,  B01J23/40 ,  B01J23/892 ,  B01J23/8986 ,  B01J2231/70

摘要： A method is provided for oxidizing gases such as, for example, CO, aldehydes having carbon atoms in the range 1 to 5 (e.g. formaldehyde), ketones having carbon atoms in the range 3 to 5, and alcohols having carbon atoms in the range 1 to 5, wherein the gas at a relative humidity in the range 0 to 100% and an input temperature in the range -50.degree. to 150.degree. C. is contacted with a catalyst assembly comprising (a) a hydrophobic support having a surface area in the range 50 to 1,500 m.sup.2 /g and selected from the group consisting of silicalite, silylated silica, and styrene divinylbenzene polymers, and, on said support (b) a catalytically active metal selected from the group consisting of chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, platinum, iridium, nickel, copper and silver, said metal being present in an amount in the range 0.1 to 22 wt % of the total weight of the catalyst assembly. The catalyst assemblies used are generally catalytically active in the presence of liquid water and water vapor for longer periods than known catalyst assemblies and function at ambient temperatures.

摘要翻译： 提供了一种氧化气体的方法，例如CO，具有1至5范围内碳原子的醛（例如甲醛），碳原子在3至5范围内的酮，以及碳原子在1范围内的醇 至5，其中相对湿度在0至100％范围内的气体和-50℃至150℃的输入温度与催化剂组件接触，所述催化剂组件包括（a）疏水性载体，其表面积为 范围为50至1,500m2 / g，选自硅沸石，甲硅烷基化二氧化硅和苯乙烯二乙烯基苯聚合物，并且在所述载体（b）上，选自铬，钼，钨，锰的催化活性金属 铼，铁，钌，锇，钴，铑，铂，铱，镍，铜和银，所述金属的存在量为催化剂组合物总重量的0.1至22重量％。 所用的催化剂组合物在液态水和水蒸气存在下通常具有催化活性，比已知催化剂组件更长的时间段，并且在环境温度下起作用。