公开(公告)号：US5543547A

公开(公告)日：1996-08-06

申请号：US384258

申请日：1995-02-03

申请人： Hiroshi Iwane ,  Hidekazu Miyagi ,  Satoshi Imada ,  Shoichi Seo ,  Takahiro Yoneyama

发明人： Hiroshi Iwane ,  Hidekazu Miyagi ,  Satoshi Imada ,  Shoichi Seo ,  Takahiro Yoneyama

IPC分类号： C07C68/00 ,  C07C69/96

CPC分类号： C07C68/005

摘要： The present invention relates to a method of producing an aromatic carbonate by reacting an aromatic hydroxy compound, carbon monoxide and oxygen using as a catalyst a specified catalyst system containing palladium and cerium compounds. Specifically, the present invention relates to a method of producing an aromatic carbonate by reacting an aromatic hydroxy compound, carbon monoxide and oxygen in the presence of a catalyst containing the following compounds:(A) at least one selected from palladium and palladium compounds;(B) at least one of trivalent or tetravalent cerium compounds;(C) at least one selected from quaternary ammonium salts and quaternary phosphonium salts;(D) at least one selected from quinones and reduction products thereof, i.e., aromatic diols; or(A) and (B) components of the above; and(E) at least one inorganic halide selected from alkali metal halides and alkali earth metal halides.

摘要翻译： 本发明涉及通过使用含有钯和铈化合物的规定催化剂体系的催化剂使芳香族羟基化合物，一氧化碳和氧气反应来制造芳香族碳酸酯的方法。 具体地说，本发明涉及在含有以下化合物的催化剂存在下使芳族羟基化合物，一氧化碳和氧气反应制备芳香族碳酸酯的方法：（A）选自钯和钯化合物中的至少一种; （B）三价或四价铈化合物中的至少一种; （C）选自季铵盐和季鏻盐中的至少一种; （D）选自醌及其还原产物中的至少一种，即芳族二醇; 或（A）和（B）组分; 和（E）至少一种选自碱金属卤化物和碱土金属卤化物的无机卤化物。