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公开(公告)号：US4134979A
公开(公告)日：1979-01-16
申请号：US723834
申请日：1976-09-16
CPC分类号： C07F9/2483
摘要： O-Alkyl-S-n-propyl-N-sulfonyl-phosphoric acid ester amides of the formula ##STR1## in which R.sup.1 is methyl or ethyl,R.sup.2 is C.sub.1 -C.sub.6 alkyl or alkenyl, C.sub.1 -C.sub.6 alkyl substituted by aryl, phenyl, C.sub.1 -C.sub.6 alkylphenyl, or halophenylR.sup.3 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkyl substituted by halogen, phenyl, C.sub.1 -C.sub.6 alkylphenyl, C.sub.1 -C.sub.6 alkoxyphenyl, halophenyl, or nitrophenyl, andX is oxygen or sulfur,Which possess insecticidal, acaricidal and nematicidal properties.
摘要翻译： 式（Ⅰ）的O-烷基-S-丙基-N-磺酰基 - 磷酸酯酰胺，其中R 1是甲基或乙基，R 2是C 1 -C 6烷基或链烯基，被芳基取代的C 1 -C 6烷基， 苯基，C1-C6烷基苯基或卤代苯基R3是C1-C6烷基，被卤素，苯基，C1-C6烷基苯基，C1-C6烷氧基苯基，卤代苯基或硝基苯基取代的C1-C6烷基，X是氧或硫， 杀虫剂，杀虫剂和非特异性物质。
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公开(公告)号：US4290978A
公开(公告)日：1981-09-22
申请号：US131714
申请日：1980-03-19
申请人： Shigeo Kishino , Junichi Saito , Toyohiko Kume , Kunihiro Isono
发明人： Shigeo Kishino , Junichi Saito , Toyohiko Kume , Kunihiro Isono
IPC分类号： C07F9/20
CPC分类号： C07F9/20
摘要： A process for the production of a phosphoro chloride thiolate of the formula ##STR1## wherein R.sup.1 is alkyl, alkoxyalkyl, aryl, or aryl substituted by alkyl, alkoxy or halogen, andR.sup.2 is alkyl,comprising reacting a mixture of a dialkyl chlorophosphite of the formula(R.sup.2 O).sub.2 PCland an alkyl dichloro-phosphite of the formula(R.sup.2 O)PCl.sub.2with a sulphenyl chloride of the formulaR.sup.1 SClto produce a mixture of a phosphorochloridothiolate of the formula ##STR2## and a phosphorodichloridothiolate of the formula ##STR3## and reacting the mixture without isolation with an alcohol of the formulaR.sup.2 OHin the presence of a dehydrochlorinating agent thereby to convert the phosphorodichloridothiolate of the formula ##STR4## to additional phosphorochloridothiolate ##STR5## The starting mixture is produced by reacting phosphorus trichloride with a trialkyl phosphite, or with an alcohol in the presence of a dehydrochlorinating agent.
摘要翻译： 制备式IMAMA的磷酰氯硫醇盐的方法，其中R 1是被烷基，烷氧基或卤素取代的烷基，烷氧基烷基，芳基或芳基，R 2是烷基，包括使二氯甲基亚磷酸二 式（R 2 O）2 PCl和式（R 2 O）PCl 2的烷基二氯 - 亚磷酸酯与式R 1 SCl的磺酰氯反应，生成下式的下式的次氯酸硫代硫酸酯与式“IMAGE”的二氯代硫代磷酸酯的混合物， 该混合物在脱氯化氢剂的存在下不用式R 2 OH的醇分离，从而将式“IMAGE”的二氯二硫代磷酸酯转化为另外的氯代硫代磷酸酯。起始混合物通过使三氯化磷与三烷基亚磷酸酯反应制备，或 在脱氯化氢剂存在下用醇。
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3.发明授权Pesticidal O-ethyl-S-n-propyl-O-(substituted phenyl)-phosphorothiolates 失效杀虫剂O-乙基-S-N-丙基-O-（取代苯基） - 磷酸酯
公开(公告)号：US4000270A
公开(公告)日：1976-12-28
申请号：US457160
申请日：1974-04-01
申请人： Shigeo Kishino , Akio Kudamatsu , Kozo Shiokawa
发明人： Shigeo Kishino , Akio Kudamatsu , Kozo Shiokawa
摘要： O-ethyl S-n-propyl-O-(substituted phenyl)-phosphorothiolates of the general formula ##STR1## wherein X is halogen, lower alkyl, nitro, cyano, lower alkylmercapto, lower alkylsulfinyl, lower alkoxycarbonyl or lower alkyl carbonyl, andm is 1, 2 or 3, which possess insecticidal, acaricidal and nematocidal properties.
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4.发明授权
公开(公告)号：US3947529A
公开(公告)日：1976-03-30
申请号：US471082
申请日：1974-05-17
CPC分类号： C07F9/18
摘要： O-ethyl-S-n-propyl-dithiophosphoric acid phenyl or naphthyl esters, i.e. O-ethyl-S-n-propyl-O- or S- optionally substituted phenyl or naphthyl-phosphorothionothiol-- or dithiolates, of the formula ##EQU1## in which X is an oxygen or sulfur atom, andZ is a group of the formula ##SPC1##Y is a halogen atom or a lower alkyl, lower alkoxy, lower alkylmercapto, lower alkylsulfinyl, nitro, cyano or phenyl group, andm is 0, 1, 2 or 3, which possess insecticidal, acaricidal and nematocidal properties.
摘要翻译： O-乙基-S-丙基 - 二硫代磷酸苯基或萘基酯，即O-乙基-S-丙基-O-或S-任选取代的苯基或萘基 - 硫代硫代硫代或二硫醇化物，其具有式S C2H5O（I）ANGLE PXZ nC 3H7S，其中X是氧或硫原子，Z是式Y的基团是卤素原子或低级烷基，低级烷氧基，低级烷基巯基，低级烷基亚磺酰基，硝基，氰基或苯基，M IS 0，1，2或3，哪些杀虫剂，杀虫剂和杀虫剂属性。
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公开(公告)号：US4161524A
公开(公告)日：1979-07-17
申请号：US917719
申请日：1978-06-21
CPC分类号： C07F9/2483
摘要： O-Alkyl-S-n-propyl-N-sulfonyl-phosphoric acid ester amides of the formula ##STR1## in which R.sup.1 is methyl or ethyl,R.sup.2 is C.sub.1 -C.sub.6 alkyl or alkenyl, C.sub.1 -C.sub.6 alkyl substituted by aryl, phenyl, C.sub.1 -C.sub.6 alkylphenyl, or halophenylR.sup.3 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkyl substituted by halogen, phenyl, C.sub.1 -C.sub.6 alkylphenyl, C.sub.1 -C.sub.6 alkoxyphenyl, or nitrophenyl, andX is oxygen or sulfur.Which possess insecticidal, acaricidal and nematicidal properties.
摘要翻译： 式（Ⅰ）的O-烷基-S-丙基-N-磺酰基 - 磷酸酯酰胺，其中R 1是甲基或乙基，R 2是C 1 -C 6烷基或链烯基，被芳基取代的C 1 -C 6烷基， 苯基，C1-C6烷基苯基或卤代苯基R3是C1-C6烷基，被卤素，苯基，C1-C6烷基苯基，C1-C6烷氧基苯基或硝基苯基取代的C1-C6烷基，X是氧或硫。
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6.发明授权Combatting pests with O-ethyl-S-n-propyl-O-(substituted phenyl)-phosphorothiolates 失效用O-乙基-S-正丙基-O-（取代苯基） - 硫代磷酸酯作为害虫
公开(公告)号：US4027018A
公开(公告)日：1977-05-31
申请号：US628459
申请日：1975-10-31
申请人： Shigeo Kishino , Akio Kudamatsu , Kozo Shiokawa
发明人： Shigeo Kishino , Akio Kudamatsu , Kozo Shiokawa
摘要： Combating insects, acarids and nematodes with O-ethyl-S-n-propyl-O-(substituted phenyl)-phosphorothiolates of the general formula ##STR1## wherein X is halogen, lower alkyl, nitro, cyano, lower alkylmercapto, lower alkylsulfinyl, lower alkoxycarbonyl or lower alkyl carbonyl, andm is 1, 2 or 3.
摘要翻译： 用昆虫，螨虫和线虫与通式为（I）的O-乙基-S-丙基-O-（取代的苯基） - 磷硫醇盐（其中X是卤素，低级烷基，硝基，氰基，低级烷基巯基，低级烷基亚磺酰基 ，低级烷氧基羰基或低级烷基羰基，和M IS 1,2 OR 3。
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公开(公告)号：US3996041A
公开(公告)日：1976-12-07
申请号：US568635
申请日：1975-04-16
申请人： Masahiro Aya , Shigeo Kishino , Nobuo Fukazawa , Toyohiko Kume
发明人： Masahiro Aya , Shigeo Kishino , Nobuo Fukazawa , Toyohiko Kume
CPC分类号： C07F9/4449 , C07F9/4407
摘要： Amidothionophosphonic acid ester compounds of the formula: ##STR1## in which R is alkyl of from 1 to 6 carbon atoms or lower cycloalkyl;Y is hydrogen, halogen or alkyl or alkoxy of from 1 to 6 carbon atoms; andZ is nitro or cyano;Are outstandingly effective as herbicides and exhibit particularly selective action.
摘要翻译： 下式的酰氨基膦酸酯化合物：其中R是1至6个碳原子的烷基或低级环烷基; Y是氢，卤素或具有1至6个碳原子的烷基或烷氧基; Z为硝基或氰基; 作为除草剂非常有效，并展示特别选择的行动。
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8.发明授权
公开(公告)号：US3954919A
公开(公告)日：1976-05-04
申请号：US448587
申请日：1974-03-06
申请人： Shigeo Kishino , Akio Kudamatsu , Kozo Skiokawa
发明人： Shigeo Kishino , Akio Kudamatsu , Kozo Skiokawa
摘要： O-ethyl-S-n-propyl-O-(substituted phenyl)-phosphorothiolates of the general formula ##SPC1##WhereinX is halogen, lower alkyl, nitro, cyano, lower alkylmercapto, lower alkylsulfinyl, lower alkoxycarbonyl or lower alkyl carbonyl, andm is 1, 2 or 3,Which possess insecticidal, acaricidal and nematocidal properties.
摘要翻译： O-乙基-S-丙基-O-（取代的苯基） - 硫代磷酸酯，通式为：X为卤素，低级烷基，硝基，氰基，低级烷基巯基，低级烷基亚磺酰基，低级烷氧基羰基或低级烷基羰基，M IS 1， 2或3，哪些杀虫剂，杀虫剂和杀虫剂属性。
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公开(公告)号：US3948631A
公开(公告)日：1976-04-06
申请号：US384675
申请日：1973-08-01
申请人： Gerhard Schrader , Ludwig Eue , Helmuth Hack , Seiichi Hirane , Masahiro Aya , Shigeo Kishino , Nobuo Fukazawa
发明人： Gerhard Schrader , Ludwig Eue , Helmuth Hack , Seiichi Hirane , Masahiro Aya , Shigeo Kishino , Nobuo Fukazawa
CPC分类号： C07F9/242
摘要： Phosphoro-amido-thioates, i.e. O-alkyl-O-[2-nitro-4-(alkyl, alkoxy and chloro)-phenyl]-N-alkyl-phosphoro-amido-thioates and O-alkyl-O-[2-nitro-4-(optionally alkyl, alkoxy and chloro)-phenyl]-N-cycloalkyl-phosphoro-amido-thioates, or O-alkyl-O-[2-nitro-4-(alkyl, alkoxy and chloro)-phenyl]-N-alkyl-amido-thionophosphates and O-alkyl-O-[2-nitro-4-(optionally alkyl, alkoxy and chloro)-phenyl]-N-cycloalkyl-amido-thionophosphates, which possess herbicidal properties and which may be produced by conventional methods.
摘要翻译： O-烷基-O- [2-硝基-4-（烷基，烷氧基和氯） - 苯基] -N-烷基 - 酰氨基 - 硫酸酯和O-烷基-O- [2- 硝基-4-（任选烷基，烷氧基和氯） - 苯基] -N-环烷基 - 磷酰基 - 硫酸酯，或O-烷基-O- [2-硝基-4-（烷基，烷氧基和氯） - 苯基] N-烷基 - 酰胺基 - 硫代磷酸酯和O-烷基-O- [2-硝基-4-（任选烷基，烷氧基和氯） - 苯基] -N-环烷基 - 酰氨基 - 硫代磷酸酯，其具有除草性质， 通过常规方法生产。
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10.发明授权Pesticidally active O,S-dialkyl-N-substituted-N-sulfonyl-phosphoramidothiolates 失效杀虫活性的O，S-二烷基-N-取代的N-磺酰基 - 氨基硫代磷酸酯
公开(公告)号：US4150155A
公开(公告)日：1979-04-17
申请号：US834862
申请日：1977-09-19
CPC分类号： A01N57/26 , C07F9/2483
摘要： O,S-Dialkyl-N-substituted N-sulfonyl-phosphoramidothiolates of the formula ##STR1## in which R.sup.1 is ethyl, n-butyl or sec.-butyl,R.sup.2 is alkyl with 1-6 carbon atoms, alkenyl with 2-6 carbon atoms, phenyl, or phenyl substituted with up to two substituents selected from the group consisting of halogen and akyl with 1-6 carbon atoms, andR.sup.3 is alkyl or halogen-substituted alkyl with 1-6 carbon atoms, aralkyl, phenyl or phenyl substituted with up to two substituents selected from the group consisting of halogen, alkyl with 1-6 carbon atoms and nitro,Which possess insecticidal, acaricidal and nematicidal properties.
摘要翻译： O，S-二烷基-N-取代的N-磺酰基 - 氨基硫代磷酸酯，其中R 1是乙基，正丁基或仲丁基。
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