公开(公告)号：US5571888A

公开(公告)日：1996-11-05

申请号：US490427

申请日：1995-06-14

Applicant: Yi-Ni Cheng ,  Shinn-Jen Chang ,  Yuung-Ching Sheen ,  Shyue-Pyng Juang

Inventor： Yi-Ni Cheng ,  Shinn-Jen Chang ,  Yuung-Ching Sheen ,  Shyue-Pyng Juang

IPC: C08G63/692

CPC classification number: C08G63/6928

Abstract: A process for preparing a flame-retardant phosphorus-containing unsaturated polyester resin blend, comprising the following steps:(a) reacting(1) a phosphorus-containing monomer having the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are respectively H, C.sub.1 -C.sub.4 alkyl, phenyl, alkaryl or aralkyl, with(2) a saturated dicarboxylic acid, or a saturated dicarboxylic acid anhydride,(3) a double bond-containing unsaturated dicarboxylic acid or a double bond-containing unsaturated dicarboxylic acid anhydride, and(4) a diolin the presence of a metal catalyst combined with an acid to form an unsaturated polyester oligomer having the formula: ##STR2## wherein R.sub.5 and R.sub.6 are respectively C.sub.1 -C.sub.4 alkylene, alkarylene, phenylene or aralkylene,R.sub.4 is a vinyl-containing group,x is an integer of 1-10,y is an integer of 1-10,z is an integer of 1-10, and(b) blending said unsaturated polyester oligomer with a vinyl-containing monomer.

Abstract translation: 一种制备阻燃性含磷不饱和聚酯树脂共混物的方法，包括以下步骤：（a）使（1）具有下式的含磷单体：H，C 1 -C 4烷基，苯基，烷芳基或芳烷基， 与（2）饱和二羧酸或饱和二羧酸酐，（3）含双键的不饱和二羧酸或含双键的不饱和二羧酸酐，和（4）二元醇在金属 催化剂与酸组合以形成具有下式的不饱和聚酯低聚物：其中R 5和R 6分别是C 1 -C 4亚烷基，亚烷基，亚苯基或亚芳烷基，R 4是含乙烯基的基团，x是 整数1-10，y为1-10的整数，z为1-10的整数，（b）将所述不饱和聚酯低聚物与含乙烯基的单体共混。