公开(公告)号：US07618527B2

公开(公告)日：2009-11-17

申请号：US11216492

申请日：2005-08-31

Applicant: Henry W. Schussler ,  Joseph R. Cimini ,  Robert A. Fast ,  Berry G. Garrard ,  Steven T. Richardson

Inventor： Henry W. Schussler ,  Joseph R. Cimini ,  Robert A. Fast ,  Berry G. Garrard ,  Steven T. Richardson

IPC: C25B15/00 ,  C25B13/08 ,  C25B1/46

CPC classification number: C25B15/00 ,  C25B1/46 ,  C25B13/08

Abstract: Describes a method for lowering the flow of liquid anolyte through perforations in the diaphragm of a diaphragm electrolytic cell, e.g., a chlor-alkali diaphragm electrolytic cell, comprising introducing ceramic fiber into the anolyte compartment of the electrolytic cell, e.g., during cell operation. The benefits described for lowering the flow of anolyte liquor through the diaphragm of a chlor-alkali diaphragm electrolytic cell are increasing the concentration of alkali metal hydroxide, e.g., sodium hydroxide, and decreasing the concentration of hypochlorite ion, e.g., sodium hypochlorite, in the catholyte liquor. Also describes introducing dopant material and/or fibers comprising halogen-containing polymer, e.g., fluorocarbon polymer fibers, into the anolyte compartment of the electrolytic cell in conjunction with the addition of ceramic fiber into the anolyte compartment, e.g., during cell operation.

Abstract translation: 本发明描述了一种通过隔膜电解槽（例如氯碱隔膜电解槽）的膜片中的穿孔来降低液体阳极电解液的流动方法，包括将陶瓷纤维引入电解槽的阳极电解液室，例如在电池操作期间。 用于降低阳极电解液通过氯碱隔膜电解池隔膜的流量的优点是增加碱金属氢氧化物（例如氢氧化钠）的浓度，并降低次氯酸钠的浓度，例如次氯酸钠 阴极液 还描述了将包含含卤聚合物（例如碳氟化合物聚合物纤维）的掺杂剂材料和/或纤维引入电解槽的阳极电解液室，结合将陶瓷纤维添加到阳极电解液室中，例如在电池操作期间。