公开(公告)号：US4849467A

公开(公告)日：1989-07-18

申请号：US202029

申请日：1988-06-02

申请人： Leonard M. Shorr ,  Theodor M. Fishler ,  Pierre Georlette ,  Michael Rumack

发明人： Leonard M. Shorr ,  Theodor M. Fishler ,  Pierre Georlette ,  Michael Rumack

IPC分类号： C08K5/34 ,  C08K3/02 ,  C08K3/04 ,  C08K3/22 ,  C08K5/17 ,  C08K5/22 ,  C08K5/3412 ,  C08K5/3415 ,  C08L101/00

CPC分类号： C08K5/3415

摘要： The present invention relates to fire retardant polymer compositions obtained by the blending of monomeric N-tribromophenylmaleimide, as a fire retardant additive with a polymer. The preferred amount of bromine in the composition is above 0.5% by weight thereof. The polymer is selected from styrenic polymers and copolymers, polyolefine, rubbers, epoxy resins, plasticized PVC and polyurethane. If desired, one or more additional fire retardant(s) may be incorporated in the composition. Optionally, synergistic fire retardant additives such as antimony oxide, or organo-phosphorus compounds are also incorporated. The flame retardant polymer compositions have improved properties compared with those obtained with known flame retardant reagents. It was also unexpectedly found that the fire retardant additive provides to the polymer composition stability against ultraviolet light irradiation.

摘要翻译： 本发明涉及通过将单体N-三溴苯基马来酰亚胺作为阻燃添加剂与聚合物共混获得的阻燃聚合物组合物。 组合物中溴的优选量高于其重量的0.5％。 聚合物选自苯乙烯聚合物和共聚物，聚烯烃，橡胶，环氧树脂，增塑PVC和聚氨酯。 如果需要，可以在组合物中掺入一种或多种另外的阻燃剂。 任选地，还掺入协同阻燃添加剂如氧化锑或有机磷化合物。 与使用已知的阻燃剂获得的阻燃聚合物组合物相比，阻燃聚合物组合物具有改进的性能。 还出人意料地发现，阻燃添加剂提供聚合物组合物对紫外线照射的稳定性。

公开(公告)号：US5180787A

公开(公告)日：1993-01-19

申请号：US617379

申请日：1990-11-26

申请人： Leonard M. Shorr ,  Theodor M. Fishler ,  Shaul Yanay ,  Michael Rumack

发明人： Leonard M. Shorr ,  Theodor M. Fishler ,  Shaul Yanay ,  Michael Rumack

IPC分类号： C08F291/00

CPC分类号： C08F291/00

摘要： The present invention relates to fire retardant polymer compositions possessing a non-liner structural configuration resulting by the reaction of N-tribromo-phenylmaleimide, with or without comonomer, with a preformed backbone polymer, in which the bromine content is above 1.2% by weight bromine. The polymer is selected from polystyrene, polyolefins, polyamides, rubbers, polyesters, acrylics, polymeric dienes and mixtures or copolymers thereof. The comonomer present with the N-tribromophenyl-maleimide is selected from the group consisting of acrylonitrile, styrene and vinyl chloride. According to the invention the non-linear structural configurations are obtained either by grafting or crosslinking of the N-tribromophenylmaleimide onto the preformed backbone polymer in the presence of free radical producing means. Optionally, synergistic fire retardant additives such as antimony oxide are incorporated in the compositions. The preformed backbone polymer must be no less than 4% by weight of the total resin present in the compositions. The flame retardant polymer compositions have improved properties compared with those obtained with known flame retardant reagents.

摘要翻译： 本发明涉及具有非线性结构构型的阻燃聚合物组合物，其由具有或不具有共聚单体的N-三溴 - 苯基马来酰亚胺与预制的主链聚合物反应而得，其中溴含量高于1.2重量％ 。 聚合物选自聚苯乙烯，聚烯烃，聚酰胺，橡胶，聚酯，丙烯酸，聚合二烯及其混合物或共聚物。 存在于N-三溴苯基 - 马来酰亚胺的共聚单体选自丙烯腈，苯乙烯和氯乙烯。 根据本发明，非线性结构构型可以通过在自由基产生方式的存在下将N-三溴苯基马来酰亚胺接枝或交联到预先形成的主链聚合物上来获得。 任选地，组合物中加入协同阻燃添加剂如氧化锑。 预制的主链聚合物必须不小于组合物中存在的总树脂的4重量％。 与使用已知的阻燃剂获得的阻燃聚合物组合物相比，阻燃聚合物组合物具有改进的性能。