公开(公告)号：US08518466B2

公开(公告)日：2013-08-27

申请号：US12451544

申请日：2008-09-27

申请人： Changming Chen ,  Yanshen Wen ,  Danyang Li ,  Pengju Mao ,  Yihua Peng

发明人： Changming Chen ,  Yanshen Wen ,  Danyang Li ,  Pengju Mao ,  Yihua Peng

IPC分类号： C01G3/05

CPC分类号： C01B19/007 ,  A23K20/24 ,  A23K20/30 ,  A23V2002/00 ,  C01B19/02 ,  C01G3/00 ,  C01G3/05 ,  C01G3/10 ,  C01P2004/61 ,  C01P2004/84 ,  A23V2250/1626 ,  A23V2250/1588

摘要： A preparation method for selenium covered basic copper chloride includes the steps of: (a) adding crystalline basic copper chloride (TBCC), water and stabilizer in a reactor; adding sodium hydroxide solution with stirring; reacting to form a hydroxyl-modified crystalline basic copper chloride after discharge, washing, and negative pressure leaching; (b) adding the hydroxyl-modified crystalline basic copper chloride and water in the reactor, adding selenous acid with stirring; adding copper sulfate pentahydrate after reaction; forming selenium covered basic copper chloride comprising crystalline basic copper chloride, basic cuprous selenide, and basic cupric sulfate after discharge, rinsing, negative pressure filtration, and drying. The selenium covered basic copper chloride is used as feed addictives of trace elements having nonhygroscopic property, good liquidity, and stable chemical property. The selenium covered basic copper chloride is easy to incorporate with feed, low price, low cost in adding, weak acidic solubility, easy to absorb.

摘要翻译： 硒覆盖的碱性氯化铜的制备方法包括以下步骤：（a）在反应器中加入结晶碱性氯化铜（TBCC），水和稳定剂; 搅拌加入氢氧化钠溶液; 在排出，洗涤和负压浸出后反应形成羟基改性的结晶碱性氯化铜; （b）在反应器中加入羟基改性的结晶碱性氯化铜和水，搅拌加入硒酸; 反应后加入五水硫酸铜; 形成硒覆盖碱性氯化铜，包括结晶碱性氯化铜，碱式亚铜化亚铜和碱性硫酸铜，放电后，冲洗，负压过滤和干燥。 硒覆盖的碱性氯化铜用作具有不吸湿性，流动性好，化学性能稳定的微量元素的添加剂。 硒覆盖碱性氯化铜容易掺入饲料，价格低廉，成本低廉，酸性溶解性弱，易吸收。