公开(公告)号：US3801639A

公开(公告)日：1974-04-02

申请号：US3801639D

申请日：1972-06-02

申请人： AMERICAN CYANAMID CO

发明人： FANELLI A ,  METZLER G ,  RAUCH F

IPC分类号： B01J31/24 ,  C07C103/08

CPC分类号： B01J31/1875 ,  B01J2231/4288 ,  B01J2531/822

摘要： A HOMOGENEOUS CATALYST SYSTEM CONSISTING OF TRANSITION METAL COMPOUND AND A DIARYL OR DIALKYL PHOSPHINE OXIDE IS USED IN SOLUTION WITH WATER AND A SELECTED NITRILE FOR HYDRATION OF THE NITRILE TO MAKE A CORRESPONDING AMIDE. IN A PREFERRED EMBODIMENT ACRYLONITRILE IS HYDRATED WITH WATER IN PRESENCE OF RHODIUM TRICHLORIDE AND DIPHENYL PHOSPHINE OXIDE OR DIETHYL PHOSPHINE OXIDE TO MAKE ACRYLAMIDE.