公开(公告)号：US20230131891A1

公开(公告)日：2023-04-27

申请号：US17509394

申请日：2021-10-25

申请人： Airbus Defence and Space GmbH ,  Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

发明人： Achim O. Seidel ,  Uday B. Pal ,  Peter Quadbeck ,  Astrid Adrian

IPC分类号： C25C5/00 ,  C25C7/04 ,  C25C7/02

摘要： A method for extracting metal and oxygen from powdered metal oxides in electrolytic cell is proposed, the electrolytic cell comprising a container, a cathode, an anode and an oxygen-ion-conducting membrane, the method comprising providing a solid oxygen ion conducting electrolyte powder into a container, providing a feedstock comprising at least one metal oxide in powdered form into the container, applying an electric potential across the cathode and the anode, the cathode being in communication with the electrolyte powder and the anode being in communication with the membrane in communication with the electrolyte powder, such that at least one respective metallic species of the at least one metal oxide is reduced at the cathode and oxygen is oxidized at the anode to form molecular oxygen, wherein the potential across the cathode and the anode is greater than the dissociation potential of the at least one metal oxide and less than the dissociation potential of the solid electrolyte powder and the membrane.

公开(公告)号：US11987893B2

公开(公告)日：2024-05-21

申请号：US17509431

申请日：2021-10-25

申请人： Airbus Defence and Space GmbH ,  Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

发明人： Uday B. Pal ,  Achim O. Seidel ,  Peter Quadbeck ,  Astrid Adrian

IPC分类号： C25B11/02 ,  C25B1/02 ,  C25B11/047 ,  C25B13/07

CPC分类号： C25B11/02 ,  C25B1/02 ,  C25B11/047 ,  C25B13/07

摘要： A system for extracting oxygen from powdered metal oxides, the system comprising a container comprising an electrolyte in the form of meltable or molten salt, at least one cathode, at least one anode, a power supply, and a conducting structure, wherein the cathode is shaped as a receptacle having a porous shell, which has an upper opening, the cathode being arranged in the electrolyte with the opening protruding over the electrolyte, wherein the conducting structure comprises a plurality of conducting elements and gaps between the conducting elements, wherein the power supply is connectable to the at least one cathode and the at least one anode to selectively apply an electric potential across the cathode and the anode, wherein the conducting structure is insertable into the cathode, such that the conducting elements reach into an inner space of the cathode, wherein the conducting structure is electrically connectable to the cathode, and wherein the system is adapted for reducing at least one respective metallic species of at least one metal oxide of feedstock inside the shell of the cathode with inserted conducting structure by applying the electric potential, wherein the potential is greater than the dissociation potential of the at least one metal oxide.

公开(公告)号：US20230131327A1

公开(公告)日：2023-04-27

申请号：US17509431

申请日：2021-10-25

申请人： Airbus Defence and Space GmbH ,  Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

发明人： Uday B. Pal ,  Achim O. Seidel ,  Peter Quadbeck ,  Astrid Adrian

IPC分类号： C25B1/02 ,  C25B11/047

摘要： A system for extracting oxygen from powdered metal oxides, the system comprising a container comprising an electrolyte in the form of meltable or molten salt, at least one cathode, at least one anode, a power supply, and a conducting structure, wherein the cathode is shaped as a receptacle having a porous shell, which has an upper opening, the cathode being arranged in the electrolyte with the opening protruding over the electrolyte, wherein the conducting structure comprises a plurality of conducting elements and gaps between the conducting elements, wherein the power supply is connectable to the at least one cathode and the at least one anode to selectively apply an electric potential across the cathode and the anode, wherein the conducting structure is insertable into the cathode, such that the conducting elements reach into an inner space of the cathode, wherein the conducting structure is electrically connectable to the cathode, and wherein the system is adapted for reducing at least one respective metallic species of at least one metal oxide of feedstock inside the shell of the cathode with inserted conducting structure by applying the electric potential, wherein the potential is greater than the dissociation potential of the at least one metal oxide.