公开(公告)号：US06372687B1

公开(公告)日：2002-04-16

申请号：US09173123

申请日：1998-10-15

申请人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  John Meurig Thomas ,  Brian F. G. Johnson ,  D. S. Shephard ,  T. Maschmeyer

发明人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  John Meurig Thomas ,  Brian F. G. Johnson ,  D. S. Shephard ,  T. Maschmeyer

IPC分类号： B01J2340

CPC分类号： B01J31/1616 ,  B01J21/08 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/0271 ,  B01J31/20 ,  B01J2231/641 ,  B01J2231/70 ,  B01J2231/76 ,  B01J2531/0211 ,  B01J2531/821

摘要： Supported catalysts having a high sintering stability and comprising one or more noble metal cluster carbonyl compounds of the formula (1) [HaMbNcLd(CO)x]n−An+ and their use for the dehydrogenation, hydrogenation and oxidation of organic compounds where M and N are, independently of one another, one or more metals selected from the group consisting of Pt, Rh, Ir, Os, Ru, Ag, Pd, Au, Ni, Fe, Co, Cu, Re, Mn; L is one or more neutral or anionic ligands which may be identical or different; (A)n+ is one or more cations which balance the charge of the complex; a is an integer from 0 to 10, preferably from 0 to 6; b is an integer from 2 to 60; c is an integer from 0 to 30; d is an integer from 0 to 60; x is an integer from 1 to 120; n is the total charge of the complex which results from the individual charges of the constituents and is greater than 0, wherein the compounds of the formula (1) are located in the pores of a mesoporous support material.

摘要翻译： 具有高烧结稳定性并且包含一种或多种式（1）的贵金属簇羰基化合物的负载型催化剂及其用于有机化合物的脱氢，氢化和氧化的用途，其中式（1）的化合物位于孔中 的介孔载体材料。