公开(公告)号：US20190112245A1

公开(公告)日：2019-04-18

申请号：US16089495

申请日：2017-03-29

Applicant: BASF SE

Inventor： Rolf PINKOS ,  Stefan RITTINGER ,  Christoph NUEBLING ,  Olivier ABILLARD

IPC: C07C29/149

CPC classification number: C07C29/149 ,  C07C29/177 ,  C07C31/207 ,  C07C31/20

Abstract: Process for the continuous hydrogenation of a carboxylic acid (I) to an alcohol (II) by means of hydrogen at a temperature of from 100 to 300° C. and a pressure of 10 to 33 MPa abs in a reactor tube through which axial flow occurs and which has a fixed-bed catalyst which is fixed therein and comprises at least one element from the group consisting of Re, Co and Cu, and in which the carboxylic acid (I) to be hydrogenated is present in a liquid mixture (Ill) comprising the carboxylic acid (I), water and alcohol (II), where the mixture (Ill) has an acid number of from 0.2 to 25 mg KOH/g and comprises at least 15% by weight of water and at least 20% by weight of alcohol (II) and the flow velocity of the flowing liquid calculated on the basis of the geometric cross-sectional area of the empty, catalyst-free reactor tube is from 10 to 50 m/h.