公开(公告)号：US20230028994A1

公开(公告)日：2023-01-26

申请号：US17783728

申请日：2020-12-11

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Alvaro Gordillo Bolonio ,  Trees Maria De Baerdemaeker ,  Ulrich Mueller ,  Dirk de Vos ,  Ka Yan Cheung

IPC: C07C213/02 ,  B01J21/06 ,  B01J21/08 ,  B01J23/06 ,  B01J23/755 ,  B01J23/75 ,  B01J35/10

Abstract: The present invention relates to a catalytic material for the preparation of one or more of 4,4′-methylenedianiline, 2,2′-methylenedianiline, 2,4′-methylenedianiline, and oligomers of two or more thereof, the catalytic material comprising an oxidic support, wherein the oxidic support comprises an element EOS1 selected from the group consisting of Ti, Zr, Al, Si, and mixtures of two or more thereof, and further comprising a supported material supported on the oxidic support, wherein the supported material comprises an element ESM1 selected from the group consisting of Ti, Zr, V, Nb, Ta, Mo, W, Ge, Sn, Sc, Y, La, Ce, Nd, Pr, Hf, Cr, Fe, Co, Ni, Cu Zn, Pb and mixtures of two or more thereof. Further, the present invention relates in particular to a process for the preparation of a catalytic material and to a process for the preparation of one or more of 4,4′-methylenedianiline, 2,2′-methylenedianiline, 2,4′-methylenedianiline and oligomers of two or more thereof.