Abstract:
The invention relates to an electrolyte composition containing at least one compound of (I) wherein R1 is selected from C1 to C10 alkyl, and R2 is selected from O(C1 to C10 alkyl), OC(O)(C1 to C10 alkyl), OC(O)O(C1 to C10 alkyl), OS(O)2(C1 to C10 alkyl) and S(O)2O(C1 to C10 alkyl), wherein C1 to C10 alkyl may be substituted by one or more F and wherein one or more CH2— groups of C1 to C10 alkyl which are not bound directly to O may be replaced by O.
Abstract:
Process for making a cathode comprising the following steps (a) Providing a cathode active material selected from layered lithium transition metal oxides, lithiated spinels, lithium transition metal phosphate with olivine structure, and lithium nickel-cobalt aluminum oxides, (b) treating said cathode active material with an oligomer bearing units according to general formula (I a), wherein R1 are the same or different and selected from hydrogen and C1-C4-alkyl, aryl, and C4-C7-cycloalkyl, R2 and R3 are selected independently at each occurrence from phenyl and C1-C8-alkyl, C4-C7-cycloalkyl, C1-C8-haloalkyl, OPR1(O)—*, and —(CR92)p—Si(R2)2—* wherein one or more non-vicinal CR92-groups may be replaced by oxygen, R9 is selected independently at each occurrence from H and C1-C4-alkyl, and p is a variable from zero to 6, and wherein the overall majority of R2 and R3 is selected from C1-C8-alkyl, and, optionally, at least one of carbon in electrically conductive form and, optionally, a binder, (c) applying a slurry of said treated cathode active material to a current collector, and (d) at least partially removing solvent used in step (c).
Abstract:
The invention relates to an electrolyte composition containing (i) at least one aprotic polar organic solvent having a flash point above 80° C. and a dielectric constant above 10 at 25° C.; (ii) at least one flame retardant and/or non-flammable solvent; (iii) at least one compound of formula (I) R1—O(O)C—(CH2)n—C(O)O—R2 (I) wherein R1 and R2 are independently from each other selected from C1-C6 alkyl and n is 1, 2 or 3; (iv) at least one conducting salt; (v) at least one aprotic organic solvent having a dynamic viscosity below 1 mPa s at 25° C.; and (vi) optionally one or more additives.
Abstract:
Process for making a cathode comprising the following steps (a) Providing a cathode active material selected from layered lithium transition metal oxides, lithiated spinels, lithium transition metal phosphate with olivine structure, and lithium nickel-cobalt aluminum oxides, (b) treating said cathode active material with an oligomer bearing units according to general formula (I a), wherein R1 are the same or different and selected from hydrogen and C1-C4-alkyl, aryl, and C4-C7-cycloalkyl, R2 and R3 are selected independently at each occurrence from phenyl and C1-C8-alkyl, C4-C7-cycloalkyl, C1-C8-haloalkyl, OPR1(O)—*, and —(CR92)p—Si(R2)2—* wherein one or more non-vicinal CR92 groups may be replaced by oxygen, R9 is selected independently at each occurrence from H and C1-C4-alkyl, and p is a variable from zero to 6, and wherein the overall majority of R2 and R3 is selected from C1-C8-alkyl, and, optionally, at least one of carbon in electrically conductive form and, optionally, a binder, c) applying a slurry of said treated cathode active material to a current collector, and d) at least partially removing solvent used in step (c).