公开(公告)号：US20220235015A1

公开(公告)日：2022-07-28

申请号：US17617205

申请日：2020-06-02

Applicant: BASF SE

Inventor： Martin ERNST ,  Tatjana HUBER ,  Johann-Peter MELDER ,  Stephanie JAEGLI ,  Thomas KRUG

IPC: C07D251/04 ,  C07C209/62 ,  C07C213/08

Abstract: A process for the manufacture of ethyleneamines and ethanolamines, comprising the steps of (i) converting a glycolaldehyde derivative of formula (II), in which R2, R3 are—the same or different—hydrogen, alkyl, such as C1-6-alkyl, or cycloalkyl such as Cs-e-cycloalkyl; and an animating agent of formula (III); in which R1 is hydrogen (H), alkyl, such as C1-6-alkyl, or cycloalkyl such as C3-6-cycloalkyl, in the gas or liquid phase; (ii) feeding the reaction products obtained in step (i) into a hydrogenation reactor, where the reaction products are converted with hydrogen in the presence of a hydrogenation catalyst.

公开(公告)号：US20150353491A1

公开(公告)日：2015-12-10

申请号：US14764010

申请日：2014-01-27

Applicant: BASF SE

Inventor： Stephanie JAEGLI ,  Thomas SCHMIDT ,  Alfred OFTRING ,  Alexander PANCHENKO ,  Kirsten DAHMEN ,  Oliver MOLT

IPC: C07D211/26

CPC classification number: C07D211/26 ,  C07D211/60

Abstract: The present invention relates to 2,6-bis(aminomethyl)piperidine derivatives as such (in the following text abbreviated to “2,6-BAMP derivatives”) which are defined by the general formula (I) shown in the following text. In addition, the present invention relates to a process for preparing such 2,6-BAMP derivatives by hydrogenation of the corresponding 2,6-dicyanopiperidine derivatives (hereinafter abbreviated to “2,6-DCP derivatives”) in the presence of a catalyst. The present invention further provides for the use of the 2,6-BAMP derivatives of the invention as hardeners for epoxy resins, as intermediate in the preparation of diisocyanates, which play an important role in the production of polyurethanes, as starters in the preparation of polyetherols and/or as monomers for polyamide production. The present invention further relates to the diisocyanates as such prepared from the 2,6-BAMP derivatives and also the corresponding preparative process.

Abstract translation: 本发明涉及如下文所示的由通式（I）定义的2,6-二（氨基甲基）哌啶衍生物（以下简称为“2,6-BAMP衍生物”）。 此外，本发明涉及通过在催化剂存在下氢化相应的2,6-二氰基哌啶衍生物（以下简称为“2,6-DCP衍生物”）制备这种2,6-BAMP衍生物的方法。 本发明还提供了本发明的2,6-BAMP衍生物作为环氧树脂的硬化剂的用途，作为制备二异氰酸酯的中间体，其在聚氨酯的生产中起重要作用，作为起始剂在制备 聚乙烯醇和/或作为聚酰胺生产的单体。 本发明还涉及由2,6-BAMP衍生物制备的二异氰酸酯以及相应的制备方法。

公开(公告)号：US20220259139A1

公开(公告)日：2022-08-18

申请号：US17617335

申请日：2020-06-02

Applicant: BASF SE

Inventor： Martin ERNST ,  Tatjana HUBER ,  Johann-Peter MELDER ,  Stephanie JAEGLI ,  Thomas KRUG

IPC: C07C209/26 ,  C07C213/04 ,  C07C209/84 ,  C07C213/10

Abstract: A process for the conversion of glycolaldehyde with an aminating agent in the presence of hydrogen and of a catalyst in a glycolaldehyde conversion reactor, wherein one or more organic carboxylic acids are fed into the glycolaldehyde conversion reactor.

公开(公告)号：US20200317603A1

公开(公告)日：2020-10-08

申请号：US16464495

申请日：2017-11-27

Applicant: BASF SE

Inventor： Stephanie JAEGLI ,  Martin ERNST ,  Alexander PANCHENKO ,  Frank HETTCHE ,  Bjoern LUDOLPH

IPC: C07C209/90

Abstract: A process for stabilizing monoalkyl-substituted diaminocyclohexanes, the process containing: adding a reductant and optionally water to a first composition containing a monoalkyl-substituted diaminocyclohexane and optionally water to obtain a second composition, wherein the second composition contains the reductant, the monoalkyl-substituted diaminocyclohexane and additionally at least 0.05% by weight of water based on the total weight of the second composition.

公开(公告)号：US20220234991A1

公开(公告)日：2022-07-28

申请号：US17617503

申请日：2020-06-02

Applicant: BASF SE

Inventor： Tatjana HUBER ,  Martin ERNST ,  Johann-Peter MELDER ,  Stephanie JAEGLI ,  Thomas KRUG

IPC: C07C213/02 ,  C07C209/16 ,  C07C29/154

Abstract: A process for the conversion of glycolaldehyde with an aminating agent in the presence of hy-5 drogen and of a catalyst, wherein the conversion is carried out in the gas phase.

公开(公告)号：US20170217874A1

公开(公告)日：2017-08-03

申请号：US15125850

申请日：2015-03-11

Applicant: BASF SE

Inventor： Hermann LUYKEN ,  Stephanie JAEGLI ,  Michael LORENZ ,  Gordon BRASCHE ,  Markus JEGELKA ,  Barbara BECKER ,  Robert BAUMANN ,  Johann-Peter MELDER ,  Boris BUSCHHAUS ,  Thomas KRUG

IPC: C07C209/84

CPC classification number: C07C209/84 ,  C07C209/16 ,  C07C209/48 ,  C07C213/04 ,  C07C253/08 ,  C07C253/30 ,  C07C211/10 ,  C07C255/16 ,  C07C255/25 ,  C07C215/08

Abstract: The present invention relates to a process for purifying ethylenediamine (EDA) by distillation, wherein the process comprises the steps a) and b). In step a), a mixture (G1) comprising water, EDA and N-methylethylenediamine (N-MeEDA) is fed into a distillation apparatus (D1), and the major part of the water comprised in the mixture (G1) is separated off overhead at a pressure of greater than 4.8 bara. From the bottom of (D1), the water-enriched mixture (G2) is fed into a distillation apparatus (D2) in step b). At the top of (D2), the major part of the N-MeEDA is distilled off. The stream (S3) obtained from the bottom of (D2) comprises EDA, with the components water and N-MeEDA comprised in the mixture (G1) having been largely or completely removed. Further distillation steps can optionally be carried out in order to obtain pure EDA, for example when diethylenetriamine (DETA) is additionally comprised in the mixture (G1). If ammonia is additionally comprised in the mixture (G1), an ammonia removal is preferably additionally carried out before carrying out the step a) in the process of the invention.

公开(公告)号：US20190169112A1

公开(公告)日：2019-06-06

申请号：US16323578

申请日：2017-09-01

Applicant: BASF SE

Inventor： Christian EIDAMSHAUS ,  Thomas KRUG ,  Johann-Peter MELDER ,  Joerg PASTRE ,  Regine Helga BEBENSEE ,  Stephanie JAEGLI

IPC: C07C209/48 ,  C07C213/02 ,  B01J23/46

Abstract: The present invention relates to a process for hydrogenating nitriles with hydrogen in the presence of a ZrO2-supported ruthenium catalyst.

公开(公告)号：US20160304445A1

公开(公告)日：2016-10-20

申请号：US15101964

申请日：2014-11-21

Applicant: BASF SE

Inventor： Stephanie JAEGLI ,  Monika CHARRAK ,  Alexander PANCHENKO ,  Thomas SCHMIDT ,  Johann-Peter MELDER

IPC: C07C265/04 ,  C07C209/48 ,  C07C263/10 ,  C07C211/14

CPC classification number: C07C265/04 ,  C07C209/48 ,  C07C211/14 ,  C07C263/10

Abstract: The present invention relates to 2-N,N-(bis-2-aminoalkyl)-1,2-alkyldiamine derivatives of formula (I) as such, to a process for preparing the 2-N,N-(bis-2-aminoalkyl)-1,2-alkyldiamine derivatives, to the use of the 2-N,N-(bis-2-aminoalkyl)-1,2-alkyldiamine derivatives as hardeners for epoxy resins, as an intermediate in the preparation of triisocyanates, as initiators for polyetherols and/or as monomers for the preparation of polyamides, to triisocyanates derived from the 2-N,N-(bis-2-aminoalkyl)-1,2-alkyldiamine derivatives of formula (I) and also to a process for preparing these triisocyanates.

Abstract translation: 本发明涉及式（I）的2-N，N-（二-2-氨基烷基）-1,2-烷基二胺衍生物本身涉及制备2-N，N-（双-2- 使用2-N，N-（二-2-氨基烷基）-1,2-烷基二胺衍生物作为环氧树脂的硬化剂，作为制备三异氰酸酯的中间体， 作为用于制备聚酰胺的聚醚和/或单体的引发剂，衍生自式（I）的2-N，N-（二-2-氨基烷基）-1,2-烷基二胺衍生物的三异氰酸酯，还涉及一种方法 用于制备这些三异氰酸酯。

公开(公告)号：US20160009633A1

公开(公告)日：2016-01-14

申请号：US14771409

申请日：2014-02-12

Applicant: BASF SE

Inventor： Hermann LUYKEN ,  Stephanie JAEGLI ,  Michael LORENZ ,  Gordon BRASCHE ,  Markus JEGELKA ,  Barbara BECKER ,  Robert BAUMANN ,  Johann-Peter MELDER ,  Boris BUSCHHAUS ,  Thomas KRUG

IPC: C07C209/48 ,  C07C253/00 ,  C07C253/30

CPC classification number: C07C209/48 ,  C07C209/86 ,  C07C253/00 ,  C07C253/08 ,  C07C253/30 ,  C07C255/12 ,  C07C255/25 ,  C07C211/10

Abstract: The present invention relates to a process for preparing ethylenediamine (EDA), where the process comprises the steps a) to c). In step a), formaldehyde is reacted with hydrocyanic acid (HCN) to form formaldehyde cyanohydrin (FACH), where the hydrocyanic acid is completely free or largely free of sulfur dioxide (SO2). The FACH prepared in this way is reacted with ammonia (NH3) to form aminoacetonitrile (AAN) in step b), whereupon a hydrogenation of AAN in the presence of a catalyst to form EDA is carried out in step c).

Abstract translation: 本发明涉及一种制备乙二胺（EDA）的方法，其中该方法包括步骤a）至c）。 在步骤a）中，甲醛与氢氰酸（HCN）反应形成甲醛氰醇（FACH），其中氢氰酸完全游离或大部分不含二氧化硫（SO2）。 在步骤b）中，以这种方式制备的FACH与氨（NH 3）反应形成氨基乙腈（AAN），于是在催化剂存在下形成EDA的AAN的氢化在步骤c）中进行。