公开(公告)号：US3890382A

公开(公告)日：1975-06-17

申请号：US46957574

申请日：1974-05-13

Applicant: BAYER AG

Inventor： HOFER WOLFGANG ,  SCHLIEBS REINHARD ,  SCHMIDT ROBERT RUDOLF ,  EUE LUDWIG

IPC: C07F9/42 ,  C07F9/44 ,  C07F9/26

CPC classification number: C07F9/425 ,  C07F9/4407

Abstract: Novel 2-chloroethanephosphonic acid and 2chloroethanethionophosphonic acid derivatives of the formula

WHEREIN X is oxygen or sulfur; and R is aryloxy, optionally substituted with hydroxy, alkyl, halogen, or nitro, or monoarylamino, or monoalkylamino of from 1 to 6 carbon atoms; exhibit marked plant growth influencing properties, e.g. inhibition or stimulation or alteration of plant growth.

Abstract translation: 新型2-氯乙烷膦酸和式WHEREIN X的2-氯乙硫醇膦酸衍生物是氧或硫; 任选被羟基，烷基，卤素或硝基取代的芳氧基，或具有1至6个碳原子的单芳基氨基或单烷基氨基; 表现出显着的植物生长影响特性，例如 抑制或刺激或改变植物生长。

公开(公告)号：US3907540A

公开(公告)日：1975-09-23

申请号：US46957474

申请日：1974-05-13

Applicant: BAYER AG

Inventor： HOFER WOLFGANG ,  SCHLIEBS REINHARD ,  SCHMIDT ROBERT RUDOLF ,  EUE LUDWIG

IPC: C07F9/42 ,  C07F9/44 ,  A01N9/36

CPC classification number: C07F9/425 ,  C07F9/4407

Abstract: Novel 2-chloroethanephosphonic acid and 2chloroethanethionophosphonic acid derivatives of the formula

wherein X is oxygen or sulfur; and R is aryloxy, optionally substituted with hydroxy, alkyl, halogen, or nitro, or monoarylamino, or monoalkylamino of from 1 to 6 carbon atoms; exhibit marked plant growth influencing properties, e.g. inhibition or stimulation or alteration of plant growth.

Abstract translation: 新颖的2-氯乙烷膦酸和式XCl的2-氯乙硫醇膦酸衍生物PARALLEL Cl-CH2-CH2-P ANGLE R其中X是氧或硫; 任选被羟基，烷基，卤素或硝基取代的芳氧基，或具有1至6个碳原子的单芳基氨基或单烷基氨基; 表现出显着的植物生长影响特性，例如 抑制或刺激或改变植物生长。

公开(公告)号：US3707587A

公开(公告)日：1972-12-26

申请号：US3707587D

申请日：1971-03-16

Applicant: BAYER AG

Inventor： SCHLIEBS REINHARD ,  UHLIG KONRAD ,  OERTEL GUNTER ,  DIEHR HANS-JOACHIM

IPC: C07F9/40 ,  C07F9/6571 ,  C07F9/6584 ,  C08G18/38

CPC classification number: C08G18/3889 ,  C07F9/4006 ,  C07F9/6571 ,  C07F9/6584

Abstract: THE INVENTION RELATES TO AN IMPROVED PROCESS FOR THE PREPARATION OF ORGANIC PHOSPHORUS COMPOUNDS HAVING FREE HYDROXY GROUPS AND WHICH ARE USEFUL FOR THE PRODUCTION OF FLAME RESISTANT POLYURETHANE RESINS. PRODUCTION OF ORGANIC PHOSPHORUS COMPOUNDS BY REACTING SPIROCYCLIC COMPOUNDS WITH CARBONYL C OMPOUNDS AND ALKANOLAMINES AND THE UTILITY THEREOF IN THE PRODUCTION OF FLAME-RESISTANT POLYURETHANE RESINS.

公开(公告)号：US3686349A

公开(公告)日：1972-08-22

申请号：US3686349D

申请日：1969-08-20

Applicant: BAYER AG ,  ERDOELCHEMIE GMBH

Inventor： SCHLIEBS REINHARD ,  BRANDT HANS-WALTHER ,  ENGELHARD BRUNO ,  STEUDE HEINRICH ,  SCHERB HELMUT ,  SCHNUCHEL GUNTHER

IPC: B01D11/04 ,  C07C7/00 ,  C07C7/08 ,  C07C7/10 ,  C10G21/24 ,  B01D3/40

CPC classification number: C10G21/24 ,  B01D11/0488 ,  C07C7/005 ,  C07C7/08 ,  C07C7/10 ,  C07C13/12 ,  C07C11/18

Abstract: A cyclopentene rich fraction, an isoprene rich fraction, and a diolefin (essentially 1,3-pentadiene and cyclopentadiene) rich fraction are recovered from the C5 cut obtained by petroleum cracking. First, said fractions are extracted in a liquid-liquid extraction with 1-oxo-1-methylphospholine. The extractant is then distilled to separate therefrom said fractions.

Abstract translation: 从通过石油裂化获得的C5馏分中回收富含环戊烯馏分，富含异戊二烯馏分和富含二烯烃（基本上1,3-戊二烯和环戊二烯）馏分的馏分。 首先，所述级分用1-氧代-1-甲基磷酸二乙酯萃取液液萃取。 然后将萃取剂蒸馏以与其分离。

公开(公告)号：US3644598A

公开(公告)日：1972-02-22

申请号：US3644598D

申请日：1969-06-03

Applicant: BAYER AG

Inventor： SCHLIEBS REINHARD ,  SCHLOR HANSHELMUT ,  HOMEYER BERNHARD

IPC: A01N57/16 ,  A01N57/36 ,  C07F9/6568 ,  A01N9/36 ,  C07D105/04

CPC classification number: C07F9/65681 ,  A01N57/16 ,  A01N57/36

Abstract: 1-ALKOXY(-ALKENYLOXY. -PHENOXY)-1-THINONO-3-CHLORO(3ALKYL)PHOSPHOLINES, I.E. 1-(ALKOXY, ALKENYLOXY. CHLOROALKOXY, ALKYLPHENOXY, ALKYLMERCAPTOPHENOXY AND CHLOROSUBSTITUTED PHENOXY)-3-(CHLORO AND ALKYL)-$3 AND $2PHOSPHOLINES, WHICH PSSES NEMATOCIDAL, ARTHROPODICIDAL, ESPECIALLY ACARICIDAL AND INSECTICIDAL,M AND FUNGICIDAL PROPERTIES.

Abstract translation: 包含1-烷氧基（ - 烯氧基， - 苯氧基）-1-硫代-3-氯（3-烷基）磷酸酯，即1-（烷氧基，烯氧基，氯代烷氧基，烷基苯氧基，烷基巯基苯氧基和氯取代的苯氧基）-3- （氯和烷基）-TATA 3和DELTA 2-磷杂环戊二烯，以及它们在防治线虫，节肢动物，特别是螨虫和昆虫以及真菌中的应用。

公开(公告)号：US3901679A

公开(公告)日：1975-08-26

申请号：US7659570

申请日：1970-09-29

Applicant: BAYER AG

Inventor： HOFER WOLFGANG ,  SCHLIEBS REINHARD ,  SCHMIDT ROBERT RUDOLF ,  EUE LUDWIG

IPC: C07F9/44 ,  A01N

CPC classification number: C07F9/4407

Abstract: 2-CHLOROETHANE-(THIONO)-PHOSPHONIC ACID AMIDO COMPOUNDS OF THE FORMULA

in which X is oxygen or sulfur; R is lower alkyl radical of from 1 to 6 carbon atoms or phenyl; and R'' is hydrogen atom or a phenyl radical which may be substituted by nitro, halogen, alkyl or hydroxy; or R'' can represent an agriculturally acceptable salt moiety, e.g., R'' can be an alkali metal or equivalent, an alkaline earth metal or equivalent, an ammonium radical or equivalent, ARE OUTSTANDINGLY EFFECTIVE AS PLANT GROWTH REGULANTS TO STIMULATE, INHIBIT OR ALTER THE GROWTH OF PLANTS OR PARTS THEREOF.

公开(公告)号：US3892805A

公开(公告)日：1975-07-01

申请号：US44154874

申请日：1974-02-11

Applicant: BAYER AG

Inventor： EICHENHOFER KURT-WILHELM ,  SCHLIEBS REINHARD

IPC: C07C251/88 ,  C07C20060101 ,  C07C67/00 ,  C07C241/00 ,  C07C119/00

CPC classification number: C07C251/88

Abstract: A process for the production of an azine of the formula

in which R1 and R2 each independently is hydrogen, an alkyl or cycloalkyl radical with up to about 12 carbon atoms, a phenyl radical or a hydrocarbon radical of up to about 12 carbon atoms containing a benzene ring, or R1 and R2 together form a ring with the carbon atom to which they are attached, COMPRISING REACTING A CARBONYL COMPOUND OF THE FORMULA

Abstract translation: 制备下式的吖嗪的方法R1R1} ANGLE C = NN = C ANGLE（I）} R2R2}其中R1和R2各自独立地为氢，具有至多约12个碳原子的烷基或环烷基， 含有苯环的苯基或至多约12个碳原子的烃基，或者R 1和R 2一起与它们所连接的碳原子一起形成环，包含反应式R 1 -CO 2 R 2的碳化合物 （II）与至少一种选自由过氧硫酸，过氧二硫酸及其碱金属和碱土金属盐组成的组的至少一种过氧硫酸化合物。 有利地，反应在银或铑作为催化剂的存在下进行。

公开(公告)号：US3886205A

公开(公告)日：1975-05-27

申请号：US44155074

申请日：1974-02-11

Applicant: BAYER AG

Inventor： GEFFERS HANS ,  RADT WALTER ,  SCHULZ HARTMUT ,  SCHLIEBS REINHARD

IPC: C02F5/14 ,  C07F9/38 ,  C11D3/00 ,  C11D3/36

CPC classification number: C11D3/365 ,  C02F5/14 ,  C07F9/3808

Abstract: IN WHICH R is hydrogen, lower alkyl or a carboxyl group, and R1 is hydrogen or methyl, AND SALTS THEREOF, AND THEIR USE AS COMPLEX FORMERS FOR ALKALINE EARTH METAL IONS.
2-PHOSPHONO-BUTANE-1,2,4-TRICARBOXYLIC ACIDS OF THE GENERAL FORMULA

Abstract translation: 其中R为氢，低级烷基或羧基，R1为氢或甲基的通式为2-磷杂 - 丁烷-1,2,4-三羧酸，以及它们的盐，以及它们作为碱性化合物的复合物 地球金属离子

公开(公告)号：US3886204A

公开(公告)日：1975-05-27

申请号：US44154974

申请日：1974-02-11

Applicant: BAYER AG

Inventor： GEFFERS HANS ,  RADT WALTER ,  SCHULTZ HARTMUT ,  SCHLIEBS REINHARD

IPC: C02F5/14 ,  C07F9/38 ,  C11D3/00 ,  C11D3/36

CPC classification number: C11D3/365 ,  C02F5/14 ,  C07F9/3808

Abstract: 2-PHOSPHONO-BUTANE-1,2,4-TRICARBOXYLIC ACIDS OF THE GENERAL FORMULA

IN WHICH R is hydrogen, lower alkyl or a carboxyl group, and R1 is hydrogen or methyl, AND SALTS THEREOF, AND THEIR USE AS COMPLEX FORMERS FOR ALKALINE EARTH METAL IONS.

Abstract translation: 其中R为氢，低级烷基或羧基，R1为氢或甲基的通式为2-磷杂 - 丁烷-1,2,4-三羧酸，以及它们的盐，以及它们作为碱性化合物的复合物 地球金属离子

公开(公告)号：US3655835A

公开(公告)日：1972-04-11

申请号：US3655835D

申请日：1969-05-05

Applicant: BAYER AG

Inventor： SCHLIEBS REINHARD

IPC: C07F9/202 ,  C07F9/48 ,  C07F9/16

CPC classification number: C07F9/202 ,  C07F9/48

Abstract: REACTING TRIMETHYLPOSPHITE OR ORGANO-PHOSPHONOUS ACID O,O-DIMETHYL ESTER WITH HYDROGEN SULFIDE IN THE PRESENCE OF A WEAK ORGANIC BASE (THE PKA OF WHICH IN AQUEOUS SOLUTION IS ABOT 0.5-8) AT A TEMPERATURE OF SUBSTANTIALLY BETWEEN ABOUT 0-70*C. AND A STARTING PRESSURE OF SUBSTANTIALLY BETWEEN ABOUT 1-65 ATMOSPHERES ABSOLUTE, TO FORM IN HIGH YIELD AND PURITY THE CORRESPONDING KNOWN DIMETHYL-THIOPHOSPHITE OR ORGANO-THIOPHOSPHONOUS ACIDO-MONO METHYL ESTER, WHICH ARE KNOWN INTERMEDIATES USEABLE FOR THE SYNTHESIS OF KNOWN BIOCIDAL, ESPECIALLY INSECTICIDAL, PHOSPHORIC ACID ESTERS.