公开(公告)号：US3903209A

公开(公告)日：1975-09-02

申请号：US41460173

申请日：1973-11-08

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  HOMEYER BERNHARD ,  HAMMANN INGEBORG ,  UNTERSTENHOFER GUNTER

IPC: C07F9/24

CPC classification number: C07F9/24

Abstract: O,S,N-tri-aliphatic hydrocarbon-thionothiolphosphoric acid ester amides of the general formula

in which R, R1 and R2, which may be the same or different, each is an alkyl, alkenyl or alkynyl radical with up to 6 carbon atoms, optionally substituted with at least one halo, phenyl, cyano, alkoxy, alkylmercapto, phenylmercapto or naphthylmercapto radical, the mercapto radicals being optionally chloro- or cyano-substituted, WHICH POSSESS NEMATOCIDAL, INSECTICIDAL, ACARIDICAL, FUNGICIDAL AND MAMMALIAN-REPELLENT PROPERTIES.

Abstract translation: O，S，N-三脂族烃硫代硫代磷酸酯酰胺，其通式为ROS PARALLEL ANGLE PS-R2（I）R1NH，其中R，R1和R2可以相同或不同，各自为烷基， 苯基，氰基，烷氧基，烷基巯基，苯巯基或萘基巯基，巯基任选被氯代或氰基取代，具有至多6个碳原子的链烯基或炔基，任选被至少一个卤素，苯基， 杀菌，杀真菌剂和马马里亚特性。

公开(公告)号：US3705928A

公开(公告)日：1972-12-12

申请号：US3705928D

申请日：1970-04-20

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  HAMMANN INGEBORG ,  UNTERSTENHOFER GUNTER

IPC: A01N57/28 ,  C07F9/24 ,  A01N9/36

CPC classification number: C07F9/2408

Abstract: O-alkyl-N-monoalkylamido-(thiono)thiolphosphoric acid S-(N'', N'' -dialkylaminocarbamyl)-methyl esters, which may be substituted on the methyl ester group and which possess arthropodicidal, especially acaricidal and insecticidal, properties, and a process for their production.

Abstract translation: O-烷基-N-单烷基酰胺基 - （硫代）硫醇磷酸S-（N'，N'-二烷基氨基甲酰基） - 甲基酯，其可在甲基酯基上被取代并且具有杀虫，特别是杀螨和杀虫的性质， 一个生产过程。

公开(公告)号：US3895108A

公开(公告)日：1975-07-15

申请号：US41743273

申请日：1973-11-19

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  BEHRENZ WOLFGANG

IPC: C07F9/113 ,  C07F9/173 ,  C07F9/24 ,  A01N9/36

CPC classification number: C07F9/2412 ,  C07F9/113 ,  C07F9/173

Abstract: Reacting 2-(alkoxy, alkylphenoxy, alkylmercapto, dialkylamino, dialkenylamino and 1''-alkyl-2''-alkoxy carbonylvinyloxy)-4(optionally alkyl, haloalkyl and alkenyloxyalkyl substituted)1,3,2-dioxaphospholanes with bromo-dichloroacetaldehyde, optionally in the presence of an inert diluent or organic solvent, for example at a temperature of about 0-100*C, to form the corresponding 0-(2-bromo-1-(optionally alkyl, haloalkyl and alkenyloxyalkyl substituted)-ethyl)-0-(2'',2''-dichloro-vinyl)- (0(alkyl and alkylphenyl)-phosphoric acid esters; S-(alkyl)thiolphosphoric acid esters; and N,N-(dialkyl and dialkenyl)phosphoric acid amides), some of which are new compounds and all of which possess insecticidal properties.

Abstract translation: 反应2-（烷氧基，烷基苯氧基，烷基巯基，二烷基氨基，二烯基氨基和1'-烷基-2'-烷氧基羰基乙烯基氧基）-4-（任选烷基，卤代烷基和烯氧基烷基取代的）-1,3,2-二氧磷杂环戊烷与溴 - 二氯乙醛， 任选地在惰性稀释剂或有机溶剂的存在下，例如在约0-100℃的温度下，形成相应的O- [2-溴-1-（任选烷基，卤代烷基和烯氧基烷基取代的） - 乙基] -O-（2'，2'-二氯 - 乙烯基） - [O-（烷基和烷基苯基） - 磷酸酯; S-（烷基） - 硫代磷酸酯; 和N，N-（二烷基和二烯基） - 磷酸酰胺]，其中一些是新的化合物，并且都具有杀虫性质。

公开(公告)号：US3860646A

公开(公告)日：1975-01-14

申请号：US34753773

申请日：1973-04-03

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  HAMMANN INGEBORG ,  UNTERSTENHOFER GUNTHER

IPC: A01N41/06 ,  A01N20060101 ,  C07C20060101 ,  C07C67/00 ,  C07C313/00 ,  C07C319/14 ,  C07C323/49 ,  C07C143/74

CPC classification number: C07D471/04

Abstract: Halogenoalkanesulfonic acid amides of the formula

IN WHICH R and R'' each independently is hydrogen, halogen, alkyl of up to 6 carbon atoms, or halogen-substituted alkyl of up to 6 carbon atoms, Hal is halogen, R'''' is hydrogen, alkyl of up to 6 carbon atoms or lower alkenyl, Y is hydrogen or trichloromethyl, and Ar is phenyl, naphthyl, benzyl or phenylethyl, optionally substituted by fluorine, chlorine, bromine, nitro, nitrile, trifluoromethyl, trichloromethyl, lower alkyl, lower alkoxy, lower alkylmercapto or lower alkenyl, WHICH POSSESS ACARICIDAL AND FUNGICIDAL PROPERTIES.

Abstract translation: 式I的卤代烷基磺酰胺，其中R和R'各自独立地是氢，卤素，至多6个碳原子的烷基或至多6个碳原子的卤素取代的烷基，Hal是卤素，R“是氢，烷基 最多6个碳原子或低级烯基，Y是氢或三氯甲基，Ar是苯基，萘基，苄基或苯基乙基，任选被氟，氯，溴，硝基，腈，三氟甲基，三氯甲基，低级烷基，低级烷氧基， 低级烷基巯基或低级链烯基，其具有无毒的杀虫剂和杀真菌性质。

公开(公告)号：US3691277A

公开(公告)日：1972-09-12

申请号：US3691277D

申请日：1970-04-21

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  HAMMANN INGEBORG ,  UNTERSTENHOFER GUNTER

IPC: A01N57/02 ,  A01N57/14 ,  A01N57/20 ,  A01N57/22 ,  C07F9/165 ,  C07F9/40 ,  C07F9/16 ,  A01N9/36 ,  C07F9/38

CPC classification number: C07F9/4075 ,  A01N57/02 ,  C07F9/1651

Abstract: Phosphorylated and phosphonylated derivatives of mercaptoacetic acid-N'',N''-dialkylhydrazides, which are alkyl-or aryl-substituted in the 2-position, i.e. alkyl-esters of phosphoric or alkyl phosphonic (thiono) thiol acids attached through the thiol group to the 2-carbon of an alkyl-or aryl-substituted acetic acid whose carbonyl group is bound up as a dialkyl hydrazide, which possess arthropodicidal, especially acaricidal and insecticidal, properties, and processes for their production.

公开(公告)号：US3907938A

公开(公告)日：1975-09-23

申请号：US38500173

申请日：1973-08-02

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  HAMMANN INGEBORG ,  UNTERSTENHOFER GUNTER

IPC: A01N57/26 ,  A01N57/28 ,  A01N57/30 ,  C07F9/24 ,  C07F9/6533 ,  C07F9/6553 ,  A01N9/36

CPC classification number: C07F9/24

Abstract: S-(amidocarbonyl)-methyl-O-alkyl-monothiophosphoric acid ester amides of the formula

in which R and R'' each independently is alkyl of 1 to 6 carbon atoms, R'''' is alkyl or alkenyl of 1 to 6 carbon atoms optionally carrying at least one chlorine, C1-C6 alkoxy, C1-C6 alkylmercapto or nitrile radical, R'''''' is hydrogen or acyl, with the proviso that R'''''' is not hydrogen if R'''' is unsubstituted alkyl, or R'''' and R'''''' conjointly with the nitrogen atom to which they are attached form a heterocyclic ring, WHICH POSSESS INSECTICIDAL AND ACARICIDAL PROPERTIES.

Abstract translation: 式R-OO的S-（酰氨基羰基） - 甲基-O-烷基 - 一硫代磷酸酯酰胺ANGLE P ANGLE R“（I）R'-NH S-CH2-CN ANGLE PARALLEL R”'，其中R 和R'各自独立地为1至6个碳原子的烷基，R“为1至6个碳原子的烷基或烯基，任选地带有至少一个氯，C 1 -C 6烷氧基，C 1 -C 6烷基巯基或腈基，R” “是氢或酰基，条件是如果R”是未取代的烷基，R“不是氢，或者R”和R“与它们所连接的氮原子结合形成杂环，其中R” 有毒的杀虫剂和杀虫剂性质。

公开(公告)号：US3897520A

公开(公告)日：1975-07-29

申请号：US36968873

申请日：1973-06-13

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  HAMMANN INGEBORG ,  UNTERSTENHOFER GUNTER

IPC: A01N57/28 ,  C07F9/24 ,  A01N9/36

CPC classification number: C07F9/2408

Abstract: O-alkyl-N-mono-alkyl-S-(amidocarbonyl)-methyl-monothiophosphoric acid ester amides of the formula

in which R, R'' and R'''' each independently is alkyl of 1 to 6 carbon atoms, which possess insecticidal, acaricidal and nematocidal properties.

Abstract translation: 式R-OO的O-烷基-N-单烷基-S-（酰胺基羰基） - 甲基 - 一硫代磷酸酯酰胺ANGLE P ANGLE O（I）R'-NHS-CH2-C ANGLE NH-R“ 其中R，R'和R“各自独立地为具有1至6个碳原子的烷基，其具有杀虫，杀螨和杀线虫性质。

公开(公告)号：US3705927A

公开(公告)日：1972-12-12

申请号：US3705927D

申请日：1970-04-20

Applicant: BAYER AG

Inventor： STOLZER CLAUS ,  HAMMANN IGEBORG ,  UNTERSTENHOFER GUNTHER

IPC: A01N57/18 ,  C07F9/40 ,  A01N9/36

CPC classification number: A01N57/18 ,  C07F9/4075

Abstract: Alkyl- or aryl-thiolphosphonic acid O-alkyl-S-(N,N-disubstituted amino carbamyl)-methyl esters, which possess arthropodicidal, especially acaricidal and insecticidal, properties, and which may be produced by conventional methods.

Abstract translation: 具有杀虫，特别是杀螨和杀虫的性能的烷基或芳基硫羟基膦酸O-烷基-S-（N，N-二取代的氨基甲酰基） - 甲基酯，并且可以通过常规方法制备。