摘要:
The process for manufacturing a spinnable polyamide from a dinitrile, a diamine, water and a catalyst is improved by using as a catalyst a metal salt of an oxygenated phosphorus compound. For example, high quality nylon-6,6 is manufactured by contacting adiponitrile, hexamethylene diamine, water and disodium phosphite at an elevated temperature and pressure.
摘要:
Nylon-type polyamides are produced from a diamine and a diamide in contact with a catalyst comprising a carboxamide. For example, high quality nylon-6,6 is manufactured by contacting hexamethylenediamine and adipamide in water with a carboxamide, at an elevated temperature and pressure.
摘要:
Nylon-type polyamides are produced from a diamine and a diamide in contact with a catalyst comprising a urea, thiourea, or derivatives thereof. For example, high quality nylon-6,6 is manufactured by contacting hexamethylenediamine and adipamide in water with urea, thiourea, or derivatives thereof catalyst, at an elevated temperature and pressure.
摘要:
Polyamides are produced from diamines, dinitriles, and water in contact with a two-component catalyst system comprising (1) at least one copper containing compound and (2) at least one oxygen containing compound of phosphorus or sulfur.
摘要:
A catalytic process for the production of high molecular weight nylon-type polyamides from omega-aminonitriles has been discovered. The process comprises contacting an omega-aminonitrile, water and a catalytic amount of an oxygenated phosphorus compound catalyst.
摘要:
Nylon-type polyamides are produced from a diamine and a diamide in contact with a catalyst comprising a phosphorus amide. For example, high quality nylon-6,6 is manufactured by contacting hexamethylenediamine and adipamide in water with a phosphorus amide compound at an elevated temperature and pressure.
摘要:
Nylon-type polyamides are produced from a diamine and a diamide in contact with an oxygenated compound of carbon, boron, nitrogen or sulfur catalyst. For example, high quality nylon-6,6 is manufactured by contacting hexamethylenediamine and adipamide in water with an oxygenated compound of carbon, boron, nitrogen or sulfur at an elevated temperature and pressure.
摘要:
The process for manufacturing a nylon-type polyamide from a dinitrile, a diamine and water in the presence of a catalyst is improved by using as a catalyst an oxygenated phosphorus compound and an oxygenated boron compound. For example, high quality nylon-6,6 is manufactured by contacting adiponitrile, hexamethylene diamine and water with boric acid and phosphorous acid at an elevated temperature and pressure.
摘要:
The process for manufacturing a nylon-type polyamide from a dinitrile, a diamine and water in the presence of a catalyst is improved by using as a catalyst an ester of oxygenated phosphorus compound in conjunction with a strong base. For example, high quality nylon-6,6 is manufactured by contacting adiponitrile, hexamethylene diamine and water with an ester of an oxygenated phosphorous compound and sodium hydroxide at an elevated temperature and pressure.
摘要:
Nylon-type polyamides are produced from a diamine and a diamide in contact with a catalyst comprising a silicon compound. For example, high quality nylon-6,6 is manufactured by contacting hexamethylenediamine and adipamide in water with silica gel, at an elevated temperature and pressure.