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1.发明授权Schiff base reaction products of aldehydes and alkyl anthranilates and organoleptic uses thereof 失效醛和烷基邻氨基苯甲酸酯的席夫碱反应产物及其感官用途
公开(公告)号：US4775720A
公开(公告)日：1988-10-04
申请号：US114247
申请日：1987-10-29
申请人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
发明人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
IPC分类号： C07D311/96 , C11B9/00 , C11D3/50
CPC分类号： C07D311/96 , C11B9/0061 , C11D3/50
摘要： Described are schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R.sub.3 represents methyl or ethyl and aldehydes of the generic structure: ##STR2## wherein R represents unsaturated hydrocarbyl and alkoxy hydrocarbyl moieties or mixtures of aldehydes having the structures: ##STR3## wherein R.sub.1 and R.sub.2 are different alkoxy hydrocarbyl moieties and hydrocarbyl moieties including the aldehydes:(a) bergamal having the structure: ##STR4## (b) floralozone having the structure: ##STR5## (c) pino acetaldehyde having the structure: ##STR6## (d) pino isobutyraldehyde having the structure: ##STR7## (e) melonal having the structure: ##STR8## and (f) canthoxal having the structure: ##STR9## and organoleptic uses thereof in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, colognes, perfumed articles, foodstuffs, chewing gums and beverages.
摘要翻译： 描述了具有以下结构的邻氨基苯甲酸烷基酯的席夫碱反应产物：其中R 3表示甲基或乙基，以及通式结构的醛：其中R表示不饱和烃基和烷氧基烃基部分或具有以下结构的醛的混合物： 其中R1和R2是不同的烷氧基烃基部分和包含醛的烃基部分：（a）具有以下结构的bergamal：（b）具有以下结构的花色素：（c）具有以下结构的苯乙醛： （d）具有以下结构的β-异丁醛：（e）具有以下结构的甜味剂：（IMA）和（f）具有以下结构的肉豆蔻酸酯和（f）具有以下结构的肉豆蔻醇和感官用途：增强或增强香味或味道 消耗材料包括香水组合物，古龙水，香料制品，食品，口香糖和饮料。
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2.发明授权Flavoring with schiff base reaction products of aldehydes and alkyl anthranilates 失效调味与醛和烷基邻氨基苯甲酸酯的席夫碱反应产物
公开(公告)号：US4865853A
公开(公告)日：1989-09-12
申请号：US323951
申请日：1989-03-15
申请人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
发明人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
IPC分类号： C07D311/96 , C11B9/00 , C11D3/50
CPC分类号： C07D311/96 , C11B9/0061 , C11D3/50
摘要： Described are schiff base reaction products of alkyl anthanilates having the structure: ##STR1## wherein R.sub.3 represents methyl or ethyl and aldehydes of the generic structure: ##STR2## wherein R represents unsaturated hydrocarbyl and alkoxy hydrocarbyl moieties or mixtures of aldehydes having the structures: ##STR3## wherein R.sub.1 and R.sub.2 are different alkoxy hydrocarbyl moieties and hydrocarbyl moieties including the aldehydes:(a) bergamal having the structure: ##STR4## (b) floralozone having the structure: ##STR5## (c) pino acetaldehyde having the structure: ##STR6## (d) pino isobutyraldehyde having the structure: ##STR7## (e) melonal having the structure: ##STR8## and (f) canthoxal having the structure: ##STR9## and organoleptic uses thereof in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, colognes, perfumed articles, foodstuffs, chewing gums and beverages.
摘要翻译： 描述了具有以下结构的烷基苯基苯基酯的席夫碱反应产物：其中R 3表示甲基或乙基，以及通式结构的醛：其中R表示不饱和烃基和烷氧基烃基部分或具有以下结构的醛的混合物： 其中R1和R2是不同的烷氧基烃基部分和包含醛的烃基部分：（a）具有以下结构的bergamal：（b）具有以下结构的花色素：（c）具有以下结构的苯乙醛： （d）具有以下结构的β-异丁醛：（e）具有以下结构的甜味剂：（IMA）和（f）具有以下结构的肉豆蔻酸酯和（f）具有以下结构的肉豆蔻醇和感官用途：增强或增强香味或味道 消耗材料包括香水组合物，古龙水，香料制品，食品，口香糖和饮料。
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3.发明授权Use of Schiff base reaction product of methyl anthranilate and canthoxal in augmenting or enhancing aroma or taste of foodstuff or chewing gum 失效使用邻苯二甲酸甲酯和canthoxal的席夫碱反应产物来增强或增强食品或口香糖的香气或味道
公开(公告)号：US4840801A
公开(公告)日：1989-06-20
申请号：US202046
申请日：1988-06-03
申请人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
发明人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
IPC分类号： C07D311/96 , C11B9/00 , C11D3/50
CPC分类号： C11B9/0061 , C07D311/96 , C11D3/50
摘要： Described is a process for augmenting or enhancing the aroma or taste of a foodstuff or chewing comprising the step of intimately admixing with a foodstuff or chewing gum base an aroma or taste augmenting or enhancing quantity of a composition of matter prepared by reacting canthoxal having the structure: ##STR1## with methyl anthranilate to produce a composition of matter containing a compound having the structure:
摘要翻译： 描述了用于增强或增强食品或咀嚼物的香味或味道的方法，其包括与食品或口香糖基料紧密混合的步骤，其香味或味道增强或增加量通过使具有结构的canthoxal反应制备的物质组合物 ：
与邻氨基苯甲酸甲酯以产生含有具有以下结构的化合物的物质组合物： -
4.发明授权Schiff base reaction products of aldehydes and alkyl anthranilates and organoleptic uses thereof 失效醛和烷基邻氨基苯甲酸酯的席夫碱反应产物及其感官用途
公开(公告)号：US4824828A
公开(公告)日：1989-04-25
申请号：US202047
申请日：1988-06-03
申请人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
发明人： Braja D. Mookherjee , Robert W. Trenkle , Nicholas Calderone , Keith P. Sands , Myrna L. Hagedorn
IPC分类号： C07D311/96 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C07D311/96 , C11B9/0061 , C11D3/50
摘要： Described are schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R.sub.3 represents methyl or ethyl and aldehydes of the generic structure: ##STR2## wherein R represents unsaturated hydrocarbyl and alkoxy hydrocarbyl moieties or mixtures of aldehydes having the structures: ##STR3## wherein R.sub.1 and R.sub.2 are different alkoxy hydrocarbyl moieties and hydrocarbyl moieties including the aldehydes:(a) bergamal having the structure: ##STR4## (b) floralozone having the structure: ##STR5## (c) pino acetaldehyde having the structure: ##STR6## (d) pino isobutyraldehyde having the structure: ##STR7## (e) melonal having the structure: ##STR8## and (f) canthoxal having the structure: ##STR9## and organoleptic uses thereof in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, colognes, perfumed articles, foodstuffs, chewing gums and beverages.
摘要翻译： 描述了具有以下结构的邻氨基苯甲酸烷基酯的席夫碱反应产物：其中R 3表示甲基或乙基，以及通式结构的醛：其中R表示不饱和烃基和烷氧基烃基部分或具有以下结构的醛的混合物： 其中R1和R2是不同的烷氧基烃基部分和包含醛的烃基部分：（a）具有以下结构的bergamal：（b）具有以下结构的花色素：（c）具有以下结构的苯乙醛： （d）具有以下结构的β-异丁醛：（e）具有以下结构的甜味剂：（IMA）和（f）具有以下结构的肉豆蔻酸酯和（f）具有以下结构的肉豆蔻醇和感官用途：增强或增强香味或味道 消耗材料包括香水组合物，古龙水，香料制品，食品，口香糖和饮料。
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5.发明授权Schiff base reaction products of mixtures of aldehydes including helional and alkyl anthranilates; derivatives thereof; and organoleptic uses thereof 失效醛类的混合物的席夫碱反应产物，包括邻苯二甲酸和烷基邻氨基苯甲酸酯; 衍生物 和感官用途
公开(公告)号：US4915866A
公开(公告)日：1990-04-10
申请号：US295465
申请日：1989-01-10
IPC分类号： C07D311/96 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , C07D311/96 , C11B9/0061
摘要： Described are schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R.sub.3 represents methyl or ethyl; helional having the structure: ##STR2## and aldehydes having the generic structure: ##STR3## wherein R represents a hydrocarbyl or hydroxy hydrocarbyl moiety including the aldehydes:(a) pinoacetaldehyde having the structure: ##STR4## (b) pinoisobutyraldehyde having the structure: ##STR5## and (c) lyral, a mixture of compounds having the structures: ##STR6## and derivatives there and organoleptic uses thereof in augmenting or enhanving the aroma or taste of consumable materials including perfume compositions, colognes, perfumed articles, foodstuffs, chewing gums and beverages. Also described are processes for deodorizing articles and compositions of matter and axillary regions of mammalian species comprising the step of treating such articles, compositions or axillary regions with schiff base reaction products of such alkyl anthranilates and helional; or schiff base reaction products of such alkyl anthranilates, helional and aldehydes defined according to the structure: ##STR7##
摘要翻译： 描述了具有以下结构的邻氨基苯甲酸烷基酯的席夫碱反应产物：其中R 3表示甲基或乙基; 具有以下结构的具有以下结构的芳族化合物：具有通式结构的
和醛：其中R表示包含醛的烃基或羟基烃基部分：（a）具有以下结构的苯乙醛：（b）具有以下结构的异丁醛： 和（c）具有以下结构的化合物的混合物：＆lt; IMAGE＆gt;和＆lt; IMAGE＆gt;及其衍生物及其感官用途，用于增强或增强消耗材料的香气或味道，包括香料组合物，古龙水，香水制品 食品，口香糖和饮料。 还描述了用于对物质和哺乳动物物种和腋窝区域的组合物进行除臭的方法，包括用这种烷基邻氨基苯甲酸酯和天冬氨酸的席夫碱反应产物处理这些制品，组合物或腋窝区域的步骤; 或这些烷基邻氨基苯甲酸酯，炔和醛的席夫碱反应产物，其结构如下： -
6.发明授权
公开(公告)号：US4806363A
公开(公告)日：1989-02-21
申请号：US171778
申请日：1988-03-22
CPC分类号： C11D3/50 , A23L27/29 , C11B9/0061
摘要： Described are the schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R" represents ethyl or methyl with ketones and aldehydes defined according to the structure: ##STR2## wherein R' represents methyl or hydrogen and R represents one of the moieties: ##STR3## including compounds defined according to the generic structure: ##STR4## wherein R, R' and R" are defined, supra. Also described are uses of such schiff base reaction products in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, perfumed articles (including perfumed polymers, detergents and fabric softeners), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos. The schiff base reaction products of our invention also have unexpected, unobvious and advantageous utilities for their deodorancy properties in addition to having valuable properties as fragrance materials and as flavor materials.
摘要翻译： 描述了具有以下结构的烷基邻氨基苯甲酸酯的席夫碱反应产物：其中R“表示乙基或甲基与酮和醛根据以下结构定义：其中R'表示甲基或氢，R表示 包括根据通用结构定义的化合物：
+ TR ，其中R，R'和R“定义如上。 还描述了这样的席夫碱反应产物在增强或增强消耗材料（包括香料组合物，香料制品（包括加香聚合物，洗涤剂和织物柔软剂）），古龙水，食品，口香糖，牙膏，药用产品和 咀嚼烟草 本发明的席夫碱反应产物除了具有作为香料和香料的有价值的特性之外，还具有出乎意料的，非显而易见的和有利的除臭性能。 -
公开(公告)号：US4880640A
公开(公告)日：1989-11-14
申请号：US260578
申请日：1988-10-21
CPC分类号： C11D3/50 , A23L27/29 , C11B9/0061
摘要： Described are the schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R" represents ethyl or methyl with ketones and aldehydes defined according to the structure: ##STR2## wherein R' represents methyl or hydrogen and R represents one of the moieties: ##STR3## including compounds defined according to the generic structure: ##STR4## wherein R, R' and R" are defined, supra. Also described are uses of such schiff base reaction products in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, perfumed articles (including perfumed polymers, detergents and fabric softeners), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos. The schiff base reaction products of our invention also have unexpected, unobvious and advantageous utilities for their deodorancy properties in addition to having valuable properties as fragrance materials and as flavor materials.
摘要翻译： 描述了具有以下结构的烷基邻氨基苯甲酸酯的席夫碱反应产物：其中R“表示乙基或甲基与酮和醛根据以下结构定义：其中R'表示甲基或氢，R表示 部分：
包括根据通用结构定义的化合物：其中R，R'和R“定义如上。 还描述了这样的席夫碱反应产物在增强或增强消耗材料（包括香料组合物，香料制品（包括加香聚合物，洗涤剂和织物柔软剂）），古龙水，食品，口香糖，牙膏，药用产品和 咀嚼烟草 本发明的席夫碱反应产物除了具有作为香料和香料的有价值的特性之外，还具有出乎意料的，非显而易见的和有利的除臭性能。 -
8.发明授权Schiff base reaction products of mixtures of aldehydes including helional and alkyl anthranilates; derivatives thereof; and organoleptic uses thereof 失效醛类的混合物的席夫碱反应产物，包括邻苯二甲酸和烷基邻氨基苯甲酸酯; 衍生物 和感官用途
公开(公告)号：US4839083A
公开(公告)日：1989-06-13
申请号：US164503
申请日：1988-03-04
IPC分类号： C07D311/96 , C11B9/00 , C11D3/50
CPC分类号： C07D311/96 , C11B9/0061 , C11D3/50
摘要： Described are schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R.sub.3 represents methyl or ethyl; helional having the structure: ##STR2## and aldehydes having the generic structure: ##STR3## wherein R represents a hydrocarbyl or hydroxy hydrocarbyl moiety including the aldehydes:(a) pinoacetaldehyde having the structure: ##STR4## (b) pinoisobutyraldehyde having the structure: ##STR5## and (c) lyral, a mixture of compounds having the structures: ##STR6## and derivatives there and organoleptic uses thereof in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, colognes, perfumed articles, foodstuffs, chewing gums and beverages. Also described are processes for deodorizing articles and compositions of matter and axillary regions of mammalian species comprising the step of treating such articles, compositions or axillary regions with schiff base reaction products of such alkyl anthranilates and helional; or schiff base reaction products of such alkyl anthranilates, helional and aldehydes defined according to the structure: ##STR7##
摘要翻译： 描述了具有以下结构的邻氨基苯甲酸烷基酯的席夫碱反应产物：其中R 3表示甲基或乙基; 具有以下结构的具有以下结构的芳族化合物：具有通式结构的
和醛：其中R表示包含醛的烃基或羟基烃基部分：（a）具有以下结构的苯乙醛：（b）具有以下结构的异丁醛： 和（c）具有以下结构的化合物的混合物：＆lt; IMAGE＆gt;和＆lt; IMAGE＆gt;及其衍生物及其感官用途，用于增强或增强消耗材料的香气或味道，包括香料组合物，古龙水，香水制品 食品，口香糖和饮料。 还描述了用于对物质和哺乳动物物种和腋窝区域的组合物进行除臭的方法，包括用这种烷基邻氨基苯甲酸酯和天冬氨酸的席夫碱反应产物处理这些制品，组合物或腋窝区域的步骤; 或这些烷基邻氨基苯甲酸酯，炔和醛的席夫碱反应产物，其结构如下： -
9.发明授权Uses for augmenting or enhancing the aroma or taste of foodstuffs and chewing gums of schiff base reaction products of alkyl anthranilates 失效用于增强或增强邻苯二甲酸烷基酯的席夫碱反应产物的食品和口香糖的香气或味道
公开(公告)号：US4948597A
公开(公告)日：1990-08-14
申请号：US356504
申请日：1989-05-25
CPC分类号： C11B9/0061 , A23L27/29 , C11D3/50
摘要： Described are the schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R" represents ethyl or methyl with ketones and aldehydes defined according to the structure: ##STR2## wherein R' represents methyl or hydrogen and R represents one of the moieties: ##STR3## including compounds defined according to the generic structure: ##STR4## wherein R, R' and R" are defined, supra. Also described are uses of such schiff base reaction products in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, perfurmed articles (including perfumed polymers, detergents and fabric softeners), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos. The schiff base reaction products of our invention also have unexpected, unobvious and advantageous utilities for their deodorancy properties in addition to having valuable properties as fragrance materials and as flavor materials.
摘要翻译： 描述了具有以下结构的烷基邻氨基苯甲酸酯的席夫碱反应产物：其中R“表示乙基或甲基与酮和醛根据以下结构定义：其中R'表示甲基或氢，R表示 包括根据通用结构定义的化合物：
或+ TR ：其中R，R'和R“定义如上。 还描述了这种席夫碱反应产物在增加或增强消耗材料（包括香料组合物，膨胀制品（包括加香聚合物，洗涤剂和织物柔软剂）），古龙水，食品，口香糖，牙膏，药用产品和 咀嚼烟草 本发明的席夫碱反应产物除了具有作为香料和香料的有价值的特性之外，还具有出乎意料的，非显而易见的和有利的除臭性能。 -
10.发明授权Schiff base reaction products of alkyl anthranilates and organoleptic uses thereof and deodorancy uses thereof 失效烷基邻氨基苯甲酸酯的席夫碱反应产物及其感官用途及其除臭用途
公开(公告)号：US4879271A
公开(公告)日：1989-11-07
申请号：US255023
申请日：1988-10-07
CPC分类号： C11B9/0061 , A23L27/29 , C11D3/50
摘要： Described are the schiff base reaction products of alkyl anthranilates having the structure: ##STR1## wherein R" represents ethyl or methyl with ketones and aldehydes defined according to the structure: ##STR2## wherein R' represents methyl or hydrogen and R represents one of the moieties: ##STR3## including compounds defined according to the generic structure: ##STR4## wherein R, R' and R" are defined, supra. Also described are uses of such schiff base reaction products in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, perfumed articles (including perfumed polymers, detergents and fabric softeners), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos. The schiff base reaction products of our invention also have unexpected, unobvious and advantageous utilities for their deodorancy properties in addition to having valuable properties as fragrance materials and as flavor materials.
摘要翻译： 描述了具有以下结构的烷基邻氨基苯甲酸酯的席夫碱反应产物：其中R“表示乙基或甲基与酮和醛根据以下结构定义：其中R'表示甲基或氢，R表示 部分：
或 包括根据通用结构定义的化合物：其中R，R'和R“定义如上。 还描述了这样的席夫碱反应产物在增强或增强消耗材料（包括香料组合物，香料制品（包括加香聚合物，洗涤剂和织物柔软剂）），古龙水，食品，口香糖，牙膏，药用产品和 咀嚼烟草 本发明的席夫碱反应产物除了具有作为香料和香料的有价值的特性之外，还具有出乎意料的，非显而易见的和有利的除臭性能。
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