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1.发明授权Olefin polymerization process with novel supported titanium catalyst compositions 失效烯烃聚合工艺与新型载体钛催化剂组合物
公开(公告)号：US4393182A
公开(公告)日：1983-07-12
申请号：US318649
申请日：1981-11-05
CPC分类号： C08F10/00
摘要： An olefin polymerization process comprises contacting the monomer to be polymerized with a catalyst composition comprising: an organoaluminum compound, a first electron donor, and a product obtained by contacting a solid component comprising a magnesium halide in which the atomic ratio of chlorine to magnesium is at least 1.2, a titanium halide and a second electron donor, with a halohydrocarbon and thereafter with a tetravalent titanium compound.
摘要翻译： 烯烃聚合方法包括使待聚合的单体与催化剂组合物接触，所述催化剂组合物包含：有机铝化合物，第一电子给体和通过使包含氯与镁的原子比在其中的卤化镁的固体组分 至少1.2，卤化钛和第二电子给体，与卤代烃，然后用四价钛化合物。
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2.发明授权
公开(公告)号：US4414132A
公开(公告)日：1983-11-08
申请号：US316475
申请日：1981-10-30
CPC分类号： C08F10/00
摘要： A highly active and stereoselective olefin polymerization catalyst component is obtained by halogenating a magnesium compound of the formula MgR.sub.1 R.sub.2 wherein R.sub.1 is an alkoxide or aryloxide group and R.sub.2 is an alkoxide or aryloxide group or halogen, with a halide of tetravalent titanium in the presence of a halohydrocarbon and an electron donor, and contacting the halogenated product with a tetravalent titanium halide.
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公开(公告)号：US4400302A
公开(公告)日：1983-08-23
申请号：US145566
申请日：1980-05-01
CPC分类号： C08F10/00
摘要： An olefin polymerization catalyst composition comprising: (a) a reaction product of an organoaluminum compound and an electron donor, and (b) a solid component which has been obtained by halogenating a magnesium compound with the formula MgR.sub.1 R.sub.2 wherein R.sub.1 is an alkyl, aryl, alkoxide or aryloxide group and R.sub.2 is an alkyl, aryl, alkoxide or aryloxide group or halogen, with a halide of tetravalent titanium in the presence of a halohydrocarbon, and contacting the halogenated product with a tetravalent titanium compound.
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公开(公告)号：US4195069A
公开(公告)日：1980-03-25
申请号：US807696
申请日：1977-06-17
申请人： Andras G. Th. G. Kortbeek , Adrianus A. van der Nat , Wilhelmina J. M. van der Linden Lemmers , Willem Sjardijn
发明人： Andras G. Th. G. Kortbeek , Adrianus A. van der Nat , Wilhelmina J. M. van der Linden Lemmers , Willem Sjardijn
CPC分类号： C08F10/00
摘要： A process for the preparation of violet TiCl.sub.3 by reducing TiCl.sub.4 with an organo-aluminum compound, characterized in that:(a) the TiCl.sub.4 is premixed with a complexing agent in an inert organic solvent, the molar ratio complexing agent:TiCl.sub.4 being within the range from 0.3:1 to 2:1;(b) the organo-aluminum compound is premixed with a complexing agent in an inert organic solvent, the molar ratio complexing agent:organo-aluminum compound being at least 0.25:1;(c) the reduction to TiCl.sub.3 and precipitation of TiCl.sub.3 are carried out by combining at least one stoichiometric equivalent of TiCl.sub.4 in the premixed composition of step (a) with one stoichiometric equivalent of the organoaluminum compound in the premixed composition of step (b) over a period of less than one hour at a temperature within the range 60.degree. to 110.degree. C.; and(d) the final concentration of violet TiCl.sub.3 in the reaction mixture is at least 0.2 mol./liter.
摘要翻译： 一种通过用有机铝化合物还原TiCl 4制备紫色TiCl 3的方法，其特征在于：（a）TiCl 4与络合剂在惰性有机溶剂中预混合，络合剂：TiCl 4的摩尔比在 从0.3：1至2：1; （b）有机铝化合物与络合剂在惰性有机溶剂中预混合，络合剂：有机铝化合物的摩尔比为至少0.25:1; （c）通过将步骤（a）的预混合组合物中的至少一种化学计量当量的TiCl 4与步骤（b）的预混合组合物中的一种化学计量当量的有机铝化合物结合在一起，进行TiCl 3的还原和TiCl 3的沉淀， 在60℃至110℃的温度下不到一小时的时间; 和（d）反应混合物中的紫色TiCl 3的最终浓度为至少0.2mol / L。
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公开(公告)号：US4192774A
公开(公告)日：1980-03-11
申请号：US4435
申请日：1979-01-18
CPC分类号： C08F10/00 , Y10S526/908
摘要： A process for the preparation of an active TiCl.sub.3 catalyst which comprises:(a) reacting TiCl.sub.4 with a complexing agent in a molar ratio of from 1:0.3 to 1:2;(b) reacting an organo-aluminum compound with a complexing agent in a molar ratio of at most 1:0.25;(c) reducing the complexed TiCl.sub.4 with the complexed organo-aluminum compound over a period of less than one hour at a temperature within the range 60.degree. to 110.degree. C. to produce TiCl.sub.3 particles having an average particle size of from 50 to 500 .mu.m;(d) subjecting the TiCl.sub.3 particles to a treatment to reduce the average particle size thereof to less than 50 .mu.m, and(e) classifying the TiCl.sub.3 particles to separate a fraction having an average particle size of from 0.1 to 30 .mu.m.
摘要翻译： 一种制备活性TiCl 3催化剂的方法，其包括：（a）使TiCl 4与络合剂以摩尔比为1:0.3至1:2的比例反应; （b）有机铝化合物与络合剂的摩尔比至多为1:0.25; （c）在60℃至110℃的温度下，在少于1小时的时间内，用络合的有机铝化合物还原络合的TiCl 4，以制备平均粒径为50-500μm的TiCl3颗粒 m; （d）使TiCl 3颗粒进行处理以将其平均粒径减小到小于50μm，以及（e）分选TiCl 3颗粒以分离平均粒度为0.1至30μm的级分。
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