摘要:
A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine or chlorine-containing compounds by oxygen delignifying the pulp to a K No. of about 14 or less and a viscosity of greater than about 10 cps and thereafter further delignifying the partially delignified pulp by lifting, displacing and tossing the pulp in a radial direction while advancing it in an axial direction in a plug flow-like manner with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 6 or less, a viscosity of at least about 7 cps and a GE brightness of at least about 35. The substantially delignified pulp may then be brightened to a final product having a GE brightness of at least about 75, or alternately up to about 83 or more by contacting the ozonated pulp with chlorine dioxide or a peroxide compound. Because of the absence of elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.
摘要:
The present invention relates to a Kraft pulp bleaching stage which is to be carried out after conventional bleaching stages to high brightness. It has been discovered that ambient-temperature bleaching with inorganic peroxy acid salts, such as peroxymonosulfates, at this point can provide substantial increases in pulp brightness without significant decreases in pulp viscosity. Peroxy acid bleaching according to the present invention is carried out at ambient temperature and no greater than about 40.degree. C. and at an initial pH that is slightly alkaline and preferably about 7.25.
摘要:
Systems and methods by which to subject cellulosic fibers to alkaline treatment are provided. The systems and methods of the invention include equipment, such as nanofiltration units and slurry concentrators, which result in a lowered overall consumption of alkaline solution during alkaline treatment. The systems and methods of the invention further allow the components of hemicaustic streams produced by such alkaline treatments to be utilized in higher value end uses.