公开(公告)号：US09029483B2

公开(公告)日：2015-05-12

申请号：US13582010

申请日：2011-02-28

申请人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B. M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

发明人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B. M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

IPC分类号： C08G77/398 ,  C08G77/388 ,  C08G77/395 ,  C07F7/21

CPC分类号： C08G77/398 ,  C07F7/21 ,  C08G77/388 ,  C08G77/395

摘要： Polyhedral oligomeric silsesquioxanes (POSS) linked ligand of the general formula (I) L[(R1a)n-1(SiO1,5)nR2a]k[(R1b)n-1SiO1,5)nR2b]l[(R1c)n-1SiO1,5)nR2c]m  (I) in which (R1a,b,c)n-1(SiO1,5)n is a polyhedral oligomeric silsesquioxanes (POSS) with n=4, 6, 8, 10, 12, 14, 16 or 18 and R1a, R1b, R1c is each independently selected from the group consisting of same or different branched or linear C1-C20 alkyl chains, cyclo alkyl, C1-C20 alkoxy, aryl, aryloxy, heteroaryl and arylalkyl groups, k, l, m is 0 or 1 provided that k+l+m≧1, R2a, R2b, R2c is a spacer that binds the polyhedral oligomeric silsesquioxane (POSS) to the ligand L and ligand L is an uncharged electron donor.

摘要翻译： 通式（I）L [（R1a）n-1（SiO1,5）nR2a] k [（R1b）n-1SiO1,5）nR2b] l [（R1c）n-1（SiO1））的多面体低聚倍半硅氧烷（POSS） 1SiO1,5）nR2c] m（I）其中（R1a，b，c）n-1（SiO1,5）n是具有n = 4,6,8,10,12,14的多面体低聚倍半硅氧烷（POSS） ，16或18，并且R 1a，R 1b，R 1c各自独立地选自相同或不同的支链或直链C 1 -C 20烷基链，环烷基，C 1 -C 20烷氧基，芳基，芳氧基，杂芳基和芳基烷基，k， l，m为0或1，条件是k + 1 +m≥1，R2a，R2b，R2c是将多面体低聚倍半硅氧烷（POSS）与配体L结合的间隔物，配体L是不带电子的电子给体。

公开(公告)号：US20130131284A1

公开(公告)日：2013-05-23

申请号：US13582010

申请日：2011-02-28

申请人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B.M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

发明人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B.M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

IPC分类号： C08G77/398 ,  C08G77/388 ,  C08G77/395

CPC分类号： C08G77/398 ,  C07F7/21 ,  C08G77/388 ,  C08G77/395

摘要： Polyhedral oligomeric silsesquioxanes (POSS) linked ligand of the general formula (I) L[(R1a)n-1(SiO1,5)nR2a]k[(R1b)n-1SiO1,5)nR2b]l[(R1c)n-1SiO1,5)nR2c]m  (I) in which (R1a,b,c)n-1(SiO1,5)n is a polyhedral oligomeric silsesquioxanes (POSS) with n=4, 6, 8, 10, 12, 14, 16 or 18 and R1a, R1b, R1c is each independently selected from the group consisting of same or different branched or linear C1-C20 alkyl chains, cyclo alkyl, C1-C20 alkoxy, aryl, aryloxy, heteroaryl and arylalkyl groups, k, l, m is 0 or 1 provided that k+l+m≧1, R2a, R2b, R2c is a spacer that binds the polyhedral oligomeric silsesquioxane (POSS) to the ligand L and ligand L is an uncharged electron donor.

摘要翻译： 通式（I）L [（R1a）n-1（SiO1,5）nR2a] k [（R1b）n-1SiO1,5）nR2b] l [（R1c）n-1（SiO1））的多面体低聚倍半硅氧烷（POSS）连接的配体 1SiO1,5）nR2c] m（I）其中（R1a，b，c）n-1（SiO1,5）n是具有n = 4,6,8,10,12,14的多面体低聚倍半硅氧烷（POSS） ，16或18，并且R 1a，R 1b，R 1c各自独立地选自相同或不同的支链或直链C 1 -C 20烷基链，环烷基，C 1 -C 20烷氧基，芳基，芳氧基，杂芳基和芳基烷基，k， l，m为0或1，条件是k + 1 + m> = 1，R2a，R2b，R2c是将多面体低聚倍半硅氧烷（POSS）与配体L结合的间隔基，配体L是不带电子的电子给体。