公开(公告)号：US07867940B2

公开(公告)日：2011-01-11

申请号：US11334472

申请日：2006-01-19

申请人： Chan-ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol ah Lee ,  Gongguan Sun ,  Luhua Jiang ,  Qin Xin

发明人： Chan-ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol ah Lee ,  Gongguan Sun ,  Luhua Jiang ,  Qin Xin

IPC分类号： H01M4/02 ,  H01M4/88 ,  B01J31/00 ,  B01J21/18 ,  B01J23/00 ,  B01J23/40 ,  B01J23/74 ,  H01M4/36 ,  H01M4/92 ,  H01M4/90 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

摘要翻译： 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂，其含有平均尺寸较小的催化金属颗粒，而不管催化剂载体的类型如何，这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

公开(公告)号：US20100081034A1

公开(公告)日：2010-04-01

申请号：US12615514

申请日：2009-11-10

申请人： Chan-ho PAK ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

发明人： Chan-ho PAK ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

IPC分类号： H01M4/90 ,  B01J31/06

CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

摘要翻译： 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂，其含有平均尺寸较小的催化金属颗粒，而不管催化剂载体的类型如何，这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

公开(公告)号：US07981826B2

公开(公告)日：2011-07-19

申请号：US12615514

申请日：2009-11-10

申请人： Chan-ho Pak ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

发明人： Chan-ho Pak ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

IPC分类号： B01J31/00 ,  B01J37/00 ,  B01J21/18 ,  B01J23/40 ,  B01J23/74 ,  C08F4/02 ,  C08F4/60 ,  H01M4/88 ,  H01M4/02 ,  H01M4/36 ,  H01M4/92 ,  H01M4/90

CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

公开(公告)号：US20130252806A1

公开(公告)日：2013-09-26

申请号：US13989810

申请日：2010-11-30

申请人： Gongquan Sun ,  Qiwen Tang ,  Luhua Jiang ,  Suli Wang

发明人： Gongquan Sun ,  Qiwen Tang ,  Luhua Jiang ,  Suli Wang

IPC分类号： B01J23/68 ,  H01M4/90

CPC分类号： B01J23/688 ,  C25B11/0484 ,  H01M4/9016 ,  H01M4/9041 ,  H01M4/9083 ,  H01M8/083 ,  H01M12/06 ,  Y02E60/50 ,  Y02P70/56

摘要： An Ag/MnyOx/C catalyst is disclosed, wherein MnOyx is one of Mn3O4 and MnO, or the mixture of Mn3O4 and MnO, or the mixture of Mn3O4 and MnO2 with the mass content of MnO2 in the mixture of Mn3O4 and MnO2 being 0.01-99.9%. The catalyst is obtained by pyrolyzing AgMnO4 at a high temperature. The preparation method comprises two steps: (1) preparing AgMnO4 crystal as the precursor; (2) preparing the Ag/MnyOx/C catalyst. The catalyst has advantages such as high oxygen reduction reaction (ORR) catalytic activity in an alkaline environment, good stability, abundant availability and low cost of raw materials, safety, non-toxicity and pollution-free, environmental friendliness, and adaptive capacity for massive production. The catalyst can be used as oxygen reduction catalyst in metal air fuel cell, alkali anion exchange membrane fuel cell and other alkaline environments.

摘要翻译： 公开了一种Ag / MnyOx / C催化剂，其中，MnO 4 x 4和MnO 3中的Mn 3 O 4和MnO中的一种，或Mn 3 O 4和MnO的混合物，或Mn 3 O 4和MnO 2的混合物中Mn 3 O 4和MnO 2的混合物中的MnO 2的混合物为0.01- 99.9％。 该催化剂通过在高温下热解AgMnO 4得到。 制备方法包括两步：（1）制备AgMnO4晶体作为前体; （2）制备Ag / MnyOx / C催化剂。 该催化剂具有碱性环境中氧还原反应（ORR）催化活性高，稳定性好，可用性高，原料成本低，安全无毒，无污染，环保，适应能力强等优点 生产。 该催化剂可用作金属空气燃料电池，碱性阴离子交换膜燃料电池等碱性环境中的氧还原催化剂。

公开(公告)号：US08895467B2

公开(公告)日：2014-11-25

申请号：US13989810

申请日：2010-11-30

申请人： Gongquan Sun ,  Qiwen Tang ,  Luhua Jiang ,  Suli Wang

发明人： Gongquan Sun ,  Qiwen Tang ,  Luhua Jiang ,  Suli Wang

IPC分类号： B01J21/18 ,  B01J23/00 ,  B01J23/32 ,  H01M4/13 ,  H01M4/34 ,  H01M4/50 ,  H01M4/54 ,  H01M10/32 ,  B01J23/68 ,  C25B11/04 ,  H01M4/90 ,  H01M8/08 ,  H01M12/06

CPC分类号： B01J23/688 ,  C25B11/0484 ,  H01M4/9016 ,  H01M4/9041 ,  H01M4/9083 ,  H01M8/083 ,  H01M12/06 ,  Y02E60/50 ,  Y02P70/56

摘要： An Ag/MnyOx/C catalyst is disclosed, wherein MnyOx is one of Mn3O4 and MnO, or the mixture of Mn3O4 and MnO, or the mixture of Mn3O4 and MnO2 with the mass content of MnO2 in the mixture of Mn3O4 and MnO2 being 0.01-99.9%. The catalyst is obtained by pyrolyzing AgMnO4 at a high temperature. The preparation method comprises two steps: (1) preparing AgMnO4 crystal as the precursor; (2) preparing the Ag/MnyOx/C catalyst. The catalyst has advantages such as high oxygen reduction reaction (ORR) catalytic activity in an alkaline environment, good stability, abundant availability and low cost of raw materials, safety, non-toxicity and pollution-free, environmental friendliness, and adaptive capacity for massive production. The catalyst can be used as oxygen reduction catalyst in metal air fuel cell, alkali anion exchange membrane fuel cell and other alkaline environments.

摘要翻译： 公开了一种Ag / MnyOx / C催化剂，其中MnyOx是Mn 3 O 4和MnO中的一种，或者Mn 3 O 4和MnO 2的混合物中的Mn 3 O 4和MnO的混合物，或Mn 3 O 4和MnO 2的混合物中MnO 2的质量含量为0.01〜 99.9％。 该催化剂通过在高温下热解AgMnO 4得到。 制备方法包括两步：（1）制备AgMnO4晶体作为前体; （2）制备Ag / MnyOx / C催化剂。 该催化剂具有碱性环境中氧还原反应（ORR）催化活性高，稳定性好，可用性高，原料成本低，安全无毒，无污染，环保，适应能力强等优点 生产。 该催化剂可用作金属空气燃料电池，碱性阴离子交换膜燃料电池等碱性环境中的氧还原催化剂。