公开(公告)号：US5654483A

公开(公告)日：1997-08-05

申请号：US575091

申请日：1995-12-19

申请人： Chiyuki Kikuchi ,  Hiroshi Naruse ,  Masaru Wada ,  Teruyuki Nagata

发明人： Chiyuki Kikuchi ,  Hiroshi Naruse ,  Masaru Wada ,  Teruyuki Nagata

IPC分类号： C07C213/02 ,  C07C213/08 ,  C07C217/84 ,  C07C209/04 ,  C07C209/18

CPC分类号： C07C213/02 ,  C07C213/08 ,  C07C217/84

摘要： A process for producing an alkoxy-substituted tri-phenylamine comprising reacting an alkoxy-substituted cyclohexanone with a diphenylamine or an aniline, while forming said cyclohexanone in the same system from an alkoxy-substituted phenol by using said phenol as a hydrogen acceptor, in the presence of a hydrogen transfer catalyst and a catalytic amount of the alkoxy-substituted cyclohexanone corresponding to the alkoxy-substituted phenol used for the reaction, or after converting partially the alkoxy-substituted phenol to a catalytic amount of the alkoxy-substituted cyclohexanone under a hydrogen pressure in the presence of a hydrogen transfer catalyst, wherein a surface-supported catalyst is used as the hydrogen transfer catalyst.

摘要翻译： 一种制备烷氧基取代的三苯胺的方法，包括使烷氧基取代的环己酮与二苯胺或苯胺反应，同时通过使用所述苯酚作为氢受体，从烷氧基取代的苯酚形成所述环己酮，同时在 存在氢转移催化剂和催化量的对应于用于反应的烷氧基取代的苯酚的烷氧基取代的环己酮，或在氢气下部分将烷氧基取代的苯酚转化为催化量的烷氧基取代的环己酮之后 在氢转移催化剂存在下的压力，其中使用表面负载的催化剂作为氢转移催化剂。