公开(公告)号：US20140170314A1

公开(公告)日：2014-06-19

申请号：US14125202

申请日：2012-07-17

申请人： Chunming Zhang ,  Aman A. Desai ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Abhishek Roy ,  XiaoHua S. Qiu

发明人： Chunming Zhang ,  Aman A. Desai ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Abhishek Roy ,  XiaoHua S. Qiu

IPC分类号： B01D71/56 ,  B01D69/12

CPC分类号： B01D71/56 ,  B01D69/125

摘要： A method for making a composite polyamide membrane comprising the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a monomer comprising at least one phosphorous-containing functional group or salt thereof and an at least one amine-reactive functional group; and/or ii) applying such a monomer to the thin film polyamide layer.

摘要翻译： 一种制备复合聚酰胺膜的方法，包括以下步骤：将多官能胺单体和多官能酰基卤单体施用到多孔载体的表面并使单体界面聚合以形成薄膜聚酰胺层，其中该方法包括至少一种 的步骤：i）在包含至少一个含磷官能团或其盐和至少一个胺反应性官能团的单体存在下进行界面聚合; 和/或ii）将这样的单体施加到薄膜聚酰胺层上。

公开(公告)号：US09399196B2

公开(公告)日：2016-07-26

申请号：US14125202

申请日：2012-07-17

申请人： Chunming Zhang ,  Aman A. Desai ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Abhishek Roy ,  XiaoHua S. Qiu

发明人： Chunming Zhang ,  Aman A. Desai ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Abhishek Roy ,  XiaoHua S. Qiu

IPC分类号： B01D71/56 ,  B01D69/12

CPC分类号： B01D71/56 ,  B01D69/125

摘要： A method for making a composite polyamide membrane comprising the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a monomer comprising at least one phosphorous-containing functional group or salt thereof and an at least one amine-reactive functional group; and/or ii) applying such a monomer to the thin film polyamide layer.

摘要翻译： 一种制备复合聚酰胺膜的方法，包括以下步骤：将多官能胺单体和多官能酰基卤单体施用到多孔载体的表面并使单体界面聚合以形成薄膜聚酰胺层，其中该方法包括至少一种 的步骤：i）在包含至少一个含磷官能团或其盐和至少一个胺反应性官能团的单体存在下进行界面聚合; 和/或ii）将这样的单体施加到薄膜聚酰胺层上。

公开(公告)号：US20140370191A1

公开(公告)日：2014-12-18

申请号：US14241731

申请日：2013-01-03

申请人： Steven Rosenberg ,  Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Qiu ,  Abhishek Roy ,  Chunming Zhang ,  Aman A. Desai

发明人： Steven Rosenberg ,  Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Qiu ,  Abhishek Roy ,  Chunming Zhang ,  Aman A. Desai

IPC分类号： B01D71/56 ,  B01D67/00 ,  B01D69/12

CPC分类号： B01D71/56 ,  B01D67/0002 ,  B01D67/0006 ,  B01D67/0093 ,  B01D69/125 ,  B01D2323/40

摘要： A method for making a composite polyamide membrane including the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a subject monomer comprising at least one carboxylic acid group linked to an aromatic moiety and wherein the aromatic moiety is further substituted with at least one of an acyl halide or anhydride functional group and ii) applying the subject monomer to the thin film polyamide layer. The invention includes many additional embodiments.

摘要翻译： 一种制备复合聚酰胺膜的方法，包括以下步骤：将多官能胺单体和多官能酰卤单体施用于多孔载体的表面，并使单体界面聚合以形成薄膜聚酰胺层，其中该方法包括至少一种 的步骤：i）在包含至少一个与芳族部分连接的羧酸基团的主体单体的存在下进行界面聚合，其中芳族部分进一步被酰卤或酸酐官能团中的至少一种取代 和ii）将所述单体施加到所述薄膜聚酰胺层。 本发明包括许多额外的实施例。

公开(公告)号：US09073015B2

公开(公告)日：2015-07-07

申请号：US14241731

申请日：2013-01-03

申请人： Steven Rosenberg ,  Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Qiu ,  Abhishek Roy ,  Chunming Zhang ,  Aman A. Desai

发明人： Steven Rosenberg ,  Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Qiu ,  Abhishek Roy ,  Chunming Zhang ,  Aman A. Desai

IPC分类号： B01D71/56 ,  B01D67/00 ,  B01D69/12

CPC分类号： B01D71/56 ,  B01D67/0002 ,  B01D67/0006 ,  B01D67/0093 ,  B01D69/125 ,  B01D2323/40

摘要： A method for making a composite polyamide membrane including the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a subject monomer comprising at least one carboxylic acid group linked to an aromatic moiety and wherein the aromatic moiety is further substituted with at least one of an acyl halide or anhydride functional group and ii) applying the subject monomer to the thin film polyamide layer. The invention includes many additional embodiments.

摘要翻译： 一种制备复合聚酰胺膜的方法，包括以下步骤：将多官能胺单体和多官能酰卤单体施用于多孔载体的表面，并使单体界面聚合以形成薄膜聚酰胺层，其中该方法包括至少一种 的步骤：i）在包含至少一个与芳族部分连接的羧酸基团的主体单体的存在下进行界面聚合，其中芳族部分进一步被酰卤或酸酐官能团中的至少一种取代 和ii）将所述单体施加到所述薄膜聚酰胺层。 本发明包括许多额外的实施例。

公开(公告)号：US09029600B2

公开(公告)日：2015-05-12

申请号：US14125208

申请日：2012-09-14

申请人： XiaoHua S. Qiu ,  Steven D. Jons ,  Joseph D. Koob ,  Martin H. Peery ,  Steven Rosenberg ,  Abhishek Roy ,  Ian A. Tomlinson

发明人： XiaoHua S. Qiu ,  Steven D. Jons ,  Joseph D. Koob ,  Martin H. Peery ,  Steven Rosenberg ,  Abhishek Roy ,  Ian A. Tomlinson

IPC分类号： C07C51/58 ,  C07C51/62 ,  C07C53/42 ,  C07F9/11

CPC分类号： C07C51/58 ,  C07C51/62 ,  C07C53/42 ,  C07F9/11

摘要： A method for preparing a high purity (e.g. greater than 70 wt. %) mono-hydrolyzed acyl halide compound as a precipitate from solution comprising the steps of preparing a solution comprising: i) at least 80 v/v % of a hydrocarbon solvent, ii) water at a molar concentration greater than its solubility limit within the solvent but less that its solubility limit in solution, iii) a tri-hydrocarbyl phosphate compound, and iv) a polyfunctional acyl halide compound at molar ratio to both water and the tri-hydrocarbyl phosphate compound of at least 1:1.

摘要翻译： 从溶液中制备作为沉淀物的高纯度（例如大于70重量％）的单水解酰卤化合物的方法，包括以下步骤：制备溶液，其包含：i）至少80v / v％的烃溶剂， ii）水的摩尔浓度大于溶剂中的溶解度极限，但少于其在溶液中的溶解度极限，iii）三烃基磷酸盐化合物，和iv）多官能酰卤化合物与水和三元醇的摩尔比 - 磷烷基磷酸酯化合物为至少1：1。

公开(公告)号：US20140206900A1

公开(公告)日：2014-07-24

申请号：US14125208

申请日：2012-09-14

申请人： XiaoHua S. Qiu ,  Steven D. Jons ,  Joseph D. Koob ,  Martin H. Peery ,  Steven Rosenberg ,  Abhishek Roy ,  Ian A. Tomlinson

发明人： XiaoHua S. Qiu ,  Steven D. Jons ,  Joseph D. Koob ,  Martin H. Peery ,  Steven Rosenberg ,  Abhishek Roy ,  Ian A. Tomlinson

IPC分类号： C07C51/58

CPC分类号： C07C51/58 ,  C07C51/62 ,  C07C53/42 ,  C07F9/11

摘要： A method for preparing a high purity (e.g. greater than 70 wt. %) mono-hydrolyzed acyl halide compound as a precipitate from solution comprising the steps of preparing a solution comprising: i) at least 80 v/v % of a hydrocarbon solvent, ii) water at a molar concentration greater than its solubility limit within the solvent but less that its solubility limit in solution, iii) a tri-hydrocarbyl phosphate compound, and iv) a polyfunctional acyl halide compound at molar ratio to both water and the tri-hydrocarbyl phosphate compound of at least 1:1.

摘要翻译： 从溶液中制备作为沉淀物的高纯度（例如大于70重量％）的单水解酰卤化合物的方法，包括以下步骤：制备溶液，其包含：i）至少80v / v％的烃溶剂， ii）水的摩尔浓度大于溶剂中的溶解度极限，但少于其在溶液中的溶解度极限，iii）三烃基磷酸盐化合物，和iv）多官能酰卤化合物与水和三元醇的摩尔比 - 磷烷基磷酸酯化合物为至少1：1。

公开(公告)号：US20130287946A1

公开(公告)日：2013-10-31

申请号：US13990133

申请日：2012-01-20

申请人： Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Sam Qiu ,  Steven Rosenberg ,  Abhishek Roy

发明人： Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Sam Qiu ,  Steven Rosenberg ,  Abhishek Roy

IPC分类号： B01D69/12

CPC分类号： B01D69/125 ,  B01D67/0093 ,  B01D71/56 ,  B01D2323/36

摘要： A method for making a composite polyamide membrane including the steps of applying a polyfunctional amine monomer and polyfunctional acid halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of an additional monomer comprising an aromatic moiety at least one carboxylic acid functional group or salt thereof and a single amine-reactive functional group; and/or ii) applying such a monomer to the thin film polyamide layer. Many additional embodiments are described including applications for such membranes.

摘要翻译： 一种制备复合聚酰胺膜的方法，包括以下步骤：向多孔载体的表面施加多官能胺单体和多官能酰卤单体，并使所述单体界面聚合以形成薄膜聚酰胺层，其中所述方法包括至少一种 的步骤：i）在包含芳族部分至少一个羧酸官能团或其盐和单个胺反应性官能团的另外的单体的存在下进行界面聚合; 和/或ii）将这样的单体施加到薄膜聚酰胺层上。 描述了许多另外的实施例，包括这种膜的应用。

公开(公告)号：US20130287945A1

公开(公告)日：2013-10-31

申请号：US13990139

申请日：2012-01-20

申请人： Abhishek Roy ,  Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Sam Qiu ,  Steven Rosenberg

发明人： Abhishek Roy ,  Steven D. Jons ,  Joseph D. Koob ,  Mou Paul ,  XiaoHua Sam Qiu ,  Steven Rosenberg

IPC分类号： B01D69/10

CPC分类号： B01D69/10 ,  B01D67/0093 ,  B01D69/125 ,  B01D71/56 ,  B01D2323/36

摘要： A method for making a composite polyamide membrane comprising the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a C2-C20 aliphatic monomer comprising at least one carboxylic acid functional group or salt thereof, and a single amine-reactive functional group; and ii) applying a C2-C20 aliphatic monomer comprising at least one carboxylic acid functional group or salt thereof, and a single amine-reactive functional group to the thin film polyamide layer. Many additional embodiments are described including applications for such membranes.

摘要翻译： 一种制备复合聚酰胺膜的方法，包括以下步骤：将多官能胺单体和多官能酰基卤单体施用到多孔载体的表面并使单体界面聚合以形成薄膜聚酰胺层，其中该方法包括至少一种 的步骤：i）在包含至少一个羧酸官能团或其盐的C 2 -C 20脂族单体和单个胺反应性官能团的存在下进行界面聚合; 和ii）将包含至少一种羧酸官能团或其盐的C 2 -C 20脂族单体和单胺反应性官能团施加到薄膜聚酰胺层上。 描述了许多另外的实施例，包括这种膜的应用。

公开(公告)号：US09630149B2

公开(公告)日：2017-04-25

申请号：US14407366

申请日：2013-07-03

申请人： Abhishek Roy ,  Tina L. Arrowood ,  Anand S. Badami ,  Robert C. Cieslinski ,  David D. Hawn ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Huang Wu

发明人： Abhishek Roy ,  Tina L. Arrowood ,  Anand S. Badami ,  Robert C. Cieslinski ,  David D. Hawn ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Huang Wu

IPC分类号： B01D71/56 ,  B01D39/14 ,  B01D29/00 ,  B05D5/00 ,  B01D67/00 ,  B01D69/12 ,  B01D61/02 ,  B01D69/10

CPC分类号： B01D67/0006 ,  B01D61/025 ,  B01D67/0002 ,  B01D69/10 ,  B01D69/12 ,  B01D69/125 ,  B01D71/56 ,  B01D2323/00 ,  B01D2323/38 ,  B01D2323/40 ,  B01D2325/20

摘要： A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.

公开(公告)号：US20150165387A1

公开(公告)日：2015-06-18

申请号：US14407366

申请日：2013-07-03

申请人： Abhishek Roy ,  Tina L. Arrowood ,  Anand S. Badami ,  Robert C. Cieslinski ,  David D. Hawn ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Huang Wu

发明人： Abhishek Roy ,  Tina L. Arrowood ,  Anand S. Badami ,  Robert C. Cieslinski ,  David D. Hawn ,  Steven D. Jons ,  Mou Paul ,  Steven Rosenberg ,  Huang Wu

IPC分类号： B01D71/56 ,  B01D69/12 ,  B01D69/10 ,  B01D67/00

CPC分类号： B01D67/0006 ,  B01D61/025 ,  B01D67/0002 ,  B01D69/10 ,  B01D69/12 ,  B01D69/125 ,  B01D71/56 ,  B01D2323/00 ,  B01D2323/38 ,  B01D2323/40 ,  B01D2325/20

摘要： A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.

摘要翻译： 一种具有多孔载体的薄膜复合聚酰胺膜和包含间苯二胺（mPD）和均苯三酰氯（TMC）的反应产物的薄膜聚酰胺层，其特征在于薄膜聚酰胺层的临界应变值小于 10％。 在另一个实施方案中，薄膜聚酰胺层的模量大于0.75（GPa）。 在另一个实施方案中，薄膜聚酰胺层具有至少45％的平衡溶胀值。 在另一个实施方案中，薄膜聚酰胺层具有至少230nm的厚度。