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公开(公告)号:US20210388255A1
公开(公告)日:2021-12-16
申请号:US17412152
申请日:2021-08-25
Applicant: ConocoPhillips Company , University of Kansas
Inventor: Ying-Ying LIN , Cory BERKLAND , Jenn-Tai LIANG , Ahmad MORADI-ARAGHI , Terry M. CHRISTIAN , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , Faye L. SCULLY , David R. ZORNES
Abstract: The disclosure is directed to polyelectrolyte complex nanoparticles that can be used to deliver agents deep into hydrocarbon reservoirs. Methods of making and using said polyelectrolyte complex nanoparticles are also provided.
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公开(公告)号:US20140162912A1
公开(公告)日:2014-06-12
申请号:US14182901
申请日:2014-02-18
Applicant: University of Kansas , ConocoPhillips Company
Inventor: Ahmad MORADI-ARAGHI , James H. HEDGES , David R. ZORNES , Riley B. NEEDHAM , Huili GUAN , Jenn-Tai LIANG , Cory BERKLAND , James P. JOHNSON , Min CHENG , Faye Lynn SCULLY
IPC: C09K8/88
Abstract: The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.
Abstract translation: 本发明涉及长效交联水溶性可溶胀聚合物,其制备方法及其用途。 更具体地说,本发明涉及包含具有阳离子位点的可发性聚合物颗粒以及不稳定的交联剂和稳定的交联剂的组合物,所述颗粒与流体混合。 特别重要的用途是作为石油生产中的注入流体,其中将可发性聚合物颗粒注入到储存器中的目标区域中,并且当储存器中的热量和/或合适的pH引起不稳定交联剂的降解时, 膨胀,聚合物中的阳离子部位吸附在地层中的岩石的负位点,从而将水转移到较低的渗透率区域并提高油的回收率。 然而,许多其他用途是可能的。
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公开(公告)号:US20140209305A1
公开(公告)日:2014-07-31
申请号:US14060749
申请日:2013-10-23
Applicant: University of Kansas , ConocoPhillips Company
Inventor: Ying-Ying LIN , Cory BERKLAND , Jenn-Tai LIANG , Ahmad MORADI-ARAGHI , Terry M. CHRISTIAN , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , Faye L. SCULLY , David R. ZORNES
IPC: C09K8/60
CPC classification number: C09K8/604 , C09K8/035 , C09K8/584 , C09K2208/10
Abstract: The disclosure is directed to polyelectrolyte complex nanoparticles that can be used to deliver agents deep into hydrocarbon reservoirs. Methods of making and using said polyelectrolyte complex nanoparticles are also provided.
Abstract translation: 本公开涉及可用于将试剂深入烃储层的聚电解质复合纳米颗粒。 还提供了制备和使用所述聚电解质复合纳米颗粒的方法。
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公开(公告)号:US20140102707A1
公开(公告)日:2014-04-17
申请号:US14100958
申请日:2013-12-09
Applicant: ConocoPhillips Company
Inventor: Ahmad MORADI-ARAGHI , David R. ZORNES , Riley B. NEEDHAM , James H. Hedges , Everett L. JOHNSTON , Faye L. Scully
CPC classification number: C09K8/588 , C09D5/4411 , E21B43/16
Abstract: The invention is directed to stable crosslinked water-soluble swellable polymers, methods for making same, and their various uses in the hygiene and medical arts, gel electrophoresis, packaging, agriculture, the cable industry, information technology, in the food industry, papermaking, use as flocculation aids, and the like. More particularly, the invention relates to a composition comprising expandable polymeric microparticles having labile crosslinkers and stable crosslinkers, said microparticle mixed with a fluid and an unreacted tertiary crosslinker that is capable of further crosslinking the microparticle on degradation of the labile crosslinker so as to form a stable gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a well and when the heat and/or pH of the well cause degradation of the labile crosslinker and when the particle expands, the tertiary crosslinker crosslinks the polymer to form a stable gel, thus diverting water to lower permeability regions and improving oil recovery.
Abstract translation: 本发明涉及稳定交联的水溶性可溶胀聚合物,其制备方法及其在卫生和医学领域,凝胶电泳,包装,农业,电缆工业,信息技术,食品工业,造纸, 用作絮凝助剂等。 更具体地说,本发明涉及包含具有不稳定交联剂和稳定交联剂的可发性聚合物微粒的组合物,所述微粒与流体和未反应的三价交联剂混合,所述三价交联剂能够在不稳定交联剂降解时进一步交联微粒,从而形成 稳定的凝胶。 特别重要的用途是石油生产中的注入流体,其中将可发性聚合物颗粒注入井中,并且当井的热和/或pH引起不稳定交联剂的降解时,当颗粒膨胀时,三价交联剂交联 聚合物形成稳定的凝胶,从而将水转移到渗透率较低的区域,并提高油的回收率。
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公开(公告)号:US20190071598A1
公开(公告)日:2019-03-07
申请号:US16152557
申请日:2018-10-05
Applicant: ConocoPhillips Company , University of Kansas
Inventor: Ying-Ying LIN , Cory BERKLAND , Jenn-Tai LIANG , Ahmad MORADI-ARAGHI , Terry M. CHRISTIAN , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , Faye L. SCULLY , David R. ZORNES
Abstract: The disclosure is directed to polyelectrolyte complex nanoparticles that can be used to deliver agents deep into hydrocarbon reservoirs. Methods of making and using said polyelectrolyte complex nanoparticles are also provided.
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公开(公告)号:US20140131043A1
公开(公告)日:2014-05-15
申请号:US14157902
申请日:2014-01-17
Applicant: University of Kansas , ConocoPhillips Company
Inventor: Ahmad MORADI-ARAGHI , James H. HEDGES , David R. ZORNES , Riley B. NEEDHAM , Huili GUAN , Jenn-Tai LIANG , Cory BERKLAND , James P. JOHNSON , Min CHENG , Faye Lynn SCULLY
Abstract: The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.
Abstract translation: 本发明涉及稳定的交联水溶性可溶胀聚合物及其制备方法。 更具体地说,本发明涉及包含具有阴离子位点和不稳定交联剂和稳定交联剂的可发性聚合物颗粒的组合物,所述颗粒与流体和阳离子交联剂混合,所述流体和阳离子交联剂能够在不稳定交联剂降解时进一步交联颗粒, 阴离子位点以形成凝胶。 特别重要的用途是作为石油生产中的注入流体,其中将可发性聚合物颗粒注入目标区域,并且当目标区域的热和/或合适的pH导致不稳定交联剂和颗粒膨胀时,阳离子交联剂 交联聚合物以形成凝胶,从而将水转移到较低渗透性区域并改善油回收率。
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