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公开(公告)号:US20230014347A1
公开(公告)日:2023-01-19
申请号:US17895529
申请日:2022-08-25
发明人: Yuuta HASUMOTO , Tatsuya TAKAKUWA , Osamu YAMAMOTO , Hideki NAKAYA , Masao NOUMI , Kazuyuki SATOU , Kohei YAMANOI , Akihiro OSHIMA
IPC分类号: C07C17/278
摘要: This disclosure provides a method for producing a hydrofluoroolefin (HFO) or fluoroolefin (FO), which is a target compound, with high selectivity, without requiring a high temperature and a catalyst in a synthesis process of the target compound. Specifically, the present disclosure provides a method for producing a hydrofluoroolefin or fluoroolefin having two, three, or four carbon atoms, comprising irradiating at least one starting material compound selected from the group consisting of hydrofluorocarbons having one or two carbon atoms and hydrofluoroolefin As having two or three carbon atoms with ionizing radiation and/or an ultraviolet ray having a wavelength of 300 nm or less, with the proviso that when the at least one starting material compound is the hydrofluoroolefin A, the resulting hydrofluoroolefin is different from the hydrofluoroolefin A.
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2.
公开(公告)号:US20230391696A1
公开(公告)日:2023-12-07
申请号:US18209652
申请日:2023-06-14
发明人: Tatsuya TAKAKUWA , Tomo OTSUKA , Atsushi NOGUCHI , Yuuta HASUMOTO
IPC分类号: C07C17/281
CPC分类号: C07C17/281
摘要: The present disclosure provides a method for producing a reaction gas containing 1,1,2-trifluoroethane (R-143) and/or (E,Z)-1,2-difluoroethylene (R-1132(E,Z)) using a starting material that is easier to obtain than those used in conventional methods. Specifically, the present disclosure provides a method for producing a reaction gas containing 1,1,2-trifluoroethane (R-143) and/or (E,Z)-1,2-difluoroethylene (R-1132(E,Z)), the method comprising subjecting a starting material gas containing difluoromethane (R-32) to a reaction that involves thermal decomposition at a pressure of 0.6 MPaG or more and 2.0 MPaG or less and a temperature of 600° C. or more and 1000° C. or less, thereby obtaining the reaction gas.
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公开(公告)号:US20210130267A1
公开(公告)日:2021-05-06
申请号:US16481300
申请日:2018-01-31
IPC分类号: C07C17/20 , C07C17/383
摘要: A method for producing a fluorine-containing halogenated hydrocarbon comprising reacting a chlorine-containing compound and hydrogen fluoride in a vapor phase, and a separation step of separating a reaction product containing hydrogen fluoride, hydrogen chloride, and organic matter containing the fluorine-containing halogenated hydrocarbon into multiple components, the separation step comprising: separating the reaction product into a gas phase and a liquid phase, increasing the pressure of the liquid phase and supplying the liquid phase into a distillation column, compressing the gas phase and supplying the gas phase into the distillation column, separating a first stream containing the hydrogen chloride from the top of the distillation column, and separating a second stream containing the organic matter and the hydrogen fluoride from the bottom of the distillation column. The method is for stably obtaining a target compound by preventing hydrogen fluoride contained in the outlet gas from condensing during compression.
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公开(公告)号:US20210107850A1
公开(公告)日:2021-04-15
申请号:US17130421
申请日:2020-12-22
IPC分类号: C07C17/278 , C09K5/04
摘要: The present disclosure provides a method for producing a reaction gas containing R-1132(E) with selectivity higher than that of known methods. Specifically, the present disclosure provides a method for producing a reaction gas containing (E)-1,2-difluoroethylene (R-1132(E)), (1) the method comprising a step of subjecting a starting material gas containing one or more fluoromethanes selected from the group consisting of chlorodifluoromethane (R-22), difluoromethane (R-32), and fluoromethane (R-41) to a reaction that involves thermal decomposition to obtain the reaction gas, and (2) the starting material gas having a water vapor content of 1 volume % or less.
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公开(公告)号:US20210087446A1
公开(公告)日:2021-03-25
申请号:US16772011
申请日:2018-12-18
发明人: Mitsushi ITANO , Daisuke KARUBE , Yuuki YOTSUMOTO , Kazuhiro TAKAHASHI , Tatsuya TAKAKUWA , Yuzo KOMATSU
IPC分类号: C09K5/04
摘要: An object is to provide a mixed refrigerant having four types of performance, i.e., a coefficient of performance and a refrigerating capacity that are equivalent to those of R410A, a sufficiently low GWP, and a lower flammability (Class 2L) according to the ASHRAE standard. Provided as a means for a solution is a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, and the refrigerant comprising 62.5 mass % to 72.5 mass % of HFO-1132(E) based on the entire refrigerant.
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公开(公告)号:US20210079279A1
公开(公告)日:2021-03-18
申请号:US17049432
申请日:2019-04-18
IPC分类号: C09K5/04
摘要: The present disclosure provides a composition comprising a refrigerant characterized by having a GWP lower than that of R410A and a COP equivalent to that of R410A. Specifically, the present disclosure provides a composition comprising a refrigerant, the refrigerant comprising CO2 (R744) and at least one compound A selected from the group consisting of trans-1,2-difluoroethylene [(E)-HFO-1132], cis-1,2-difluoroethylene [(Z)-HFO-1132], fluoroethylene (HFO-1141), and 3,3,3-trifluoropropyne (TFP).
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公开(公告)号:US20200333041A1
公开(公告)日:2020-10-22
申请号:US16955222
申请日:2018-12-17
发明人: Mitsushi ITANO , Daisuke KARUBE , Yuuki YOTSUMOTO , Kazuhiro TAKAHASHI , Tatsuya TAKAKUWA , Yuzo KOMATSU , Shun OHKUBO , Tetsushi TSUDA , Takeo ABE , Yumi TODA
IPC分类号: F24F13/30 , F24F1/0059 , F24F1/24 , C09K5/04
摘要: A refrigeration cycle apparatus that can improve operation efficiency when a refrigerant that contains at least 1,2-difluoroethylene is used is provided. An air conditioning apparatus 1 includes a compressor (21), an outdoor heat exchanger (23), an outdoor expansion valve (24), an indoor heat exchanger (31), and a suction injection pipe (40), and uses a refrigerant that contains at least 1,2-difluoroethylene. The suction injection pipe (40) allows a part of a refrigerant that flows toward the indoor heat exchanger (31) from the outdoor heat exchanger (23) to merge with a low-pressure refrigerant that is sucked into the compressor (21).
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公开(公告)号:US20200332166A1
公开(公告)日:2020-10-22
申请号:US16955565
申请日:2018-12-18
发明人: Eiji KUMAKURA , Takuro YAMADA , Atsushi YOSHIMI , Ikuhiro IWATA , Mitsushi ITANO , Daisuke KARUBE , Yuuki YOTSUMOTO , Kazuhiro TAKAHASHI , Tatsuya TAKAKUWA , Yuzo KOMATSU , Shun OHKUBO , Keisuke OHTSUKA , Yoshinari ASANO , Keiji AOTA , Yuuichi YANAGI , Yoshikazu NAKAO , Takeo ABE , Yumi TODA , Tetsushi TSUDA
摘要: A refrigeration cycle apparatus (1) is capable of performing a refrigeration cycle using a small-GWP refrigerant. The refrigeration cycle apparatus (1) includes a refrigerant circuit (10) and a refrigerant enclosed in the refrigerant circuit (10). The refrigerant circuit includes a compressor (21), a condenser (23), a decompressing section (24), and an evaporator (31). The refrigerant contains at least 1,2-difluoroethylene.
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公开(公告)号:US20170166522A1
公开(公告)日:2017-06-15
申请号:US15373131
申请日:2016-12-08
IPC分类号: C07C407/00
CPC分类号: C07C407/00 , B01J19/0093 , C08G65/007 , C08G2650/48
摘要: The present invention provides a process for producing a perfluoropolyoxyalkylene peroxide compound comprising a step of reacting a perfluoroalkene with oxygen, wherein the reaction of the perfluoroalkene with oxygen is performed in a microreactor.
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10.
公开(公告)号:US20230150902A1
公开(公告)日:2023-05-18
申请号:US18084715
申请日:2022-12-20
IPC分类号: C07C17/383 , C09K5/04
CPC分类号: C07C17/383 , C09K5/045 , C09K2205/126 , C09K2205/32 , C09K2205/22
摘要: The present disclosure provides a method for producing purified trans-1,2-difluoroethylene (HFO-1132(E)) and/or 1,1,2-trifluoroethylene (HFO-1123), comprising a distillation step of distilling composition 1 comprising difluoromethane (HFC-32) and HFO-1132(E) and/or HFO-1123 to obtain composition 2 in which HFC-32 is reduced from composition 1; and an extractive distillation step of bringing composition 2 into contact with an extraction solvent to obtain a composition comprising HFO-1132(E) and/or HFO-1123, in which HFC-32 is reduced from composition 2, composition 2 being an azeotropic composition or azeotrope-like composition comprising HFC-32 and HFO-1132(E) and/or HFO-1123.
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