公开(公告)号：US3901683A

公开(公告)日：1975-08-26

申请号：US38173973

申请日：1973-07-23

Applicant: DIAMOND SHAMROCK CORP

Inventor： LIMPEL LAWRENCE E ,  IGNATOSKI JOSEPH A

IPC: A01N47/24 ,  A01N9/12

CPC classification number: A01N47/24

Abstract: Disclosed is a method of reducing insect damage and improving crop yield, which method comprises treating seeds of the crop in question with 3,3-dimethyl-1-methylthio-2-butanone 0methylcarbamoyloxime and/or the sulfoxide or sulfone thereof. Particularly disclosed are cotton seeds so treated.

公开(公告)号：US3663664A

公开(公告)日：1972-05-16

申请号：US3663664D

申请日：1969-05-05

Applicant: DIAMOND SHAMROCK CORP

Inventor： RETALLICK LAWRENCE A ,  LIMPEL LAWRENCE E ,  BLUESTONE HENRY

IPC: A01N57/06 ,  C07F9/09 ,  C07F9/14 ,  C07F9/165 ,  C07F9/20 ,  C07F9/40 ,  C07F9/06 ,  A01N9/36

CPC classification number: A01N57/06 ,  C07F9/097 ,  C07F9/14 ,  C07F9/1657 ,  C07F9/20 ,  C07F9/4096

Abstract: NOVEL OXIMINO ESTERS OF PARA-SUBSTITUTED-PHENYL PHOSPHORUS AND THIOPHOSPHORUS COMPOUNDS HAVE THE FORMULA

1-(R1-C(-R2)=N-O-P(-Z)(=Y)-O-),4-X-BENZENE

WHEREIN X IS NITRO, CYANO, AZIDE, TRIHALOMETHYL, CARBOALKOXY OR ALKANSEUFONYL; Y IS O OR S; R1 AND R2 CAN BE THE SAME OR DIFFERENT AND ARE SELECTED FROM THE GROUP CONSISTING OF H, ALKYL RADICALS OF 1-6 C ATOMS AND PHENYL; AND Z IS SELECTED FROM THE GROUP CONSISTING OF ALKALYL AND ALKOXY RADICALS EACH HAVING 1-6 C ATOMS, PHENYL, CL AND

-O-N=C(-R3)-R4

WHEREIN R3 AND R4 ARE AS DEFINED FOR F1 AND R2. MANY OF THESE COMPOUNDS ARE PREPARED BY REACTING AN OXIME WITH EITHER A PARA-SUBSTITUTED-PHENYL PHOSPHOROCHLORIDATE. A SIMILARLY SUBSTITUTED THIOPHOSPHOROCHLORIDATE OR PHENYLTHIOPHOSPHONIC CHLORIDE UNDER ALKALINE CONDITIONS. NOVEL ALKYLIDENIMINO PARA-SUBSTITUTED-PHENYL PHOSPHOCHLORIDATES AND ANALOGOUS THIOPHOSPHOROCHLORIDATES ARE ALSO DISCLOSED.