公开(公告)号：US11479734B2

公开(公告)日：2022-10-25

申请号：US16496020

申请日：2018-03-19

Applicant: Dow Global Technologies LLC

Inventor： Martin R. Greaves ,  Evelyn A. Zaugg-Hoozemans

IPC: C10M141/08 ,  C10M107/34 ,  C10N30/10 ,  C10N40/04 ,  C10N40/08 ,  C10N40/25 ,  C10N40/30

Abstract: Embodiments of the present disclosure directed towards synthetic lubricant compositions. In various embodiments, the present disclosure provides a synthetic lubricant compositions including an aromatic amine antioxidant comprising 0.25 to 5 weight percent of a total weight of the synthetic lubricant composition, dithiocarbamate antioxidant comprising 0.25 to 5 weight percent of the total weight of the synthetic lubricant composition, and a polyalkylene glycol PAG comprising 99.25 to 85 weight percent of the total weight of the synthetic lubricant composition, where the synthetic lubricant composition has a total acidic number (TAN) increase of 2 milligrams of potassium hydroxide per gram of the synthetic lubricant composition over 27 days or greater as measured in accordance with modified ASTM D-664, and where the synthetic lubricant composition does not include any of a Group I, II, III, IV base oil.

公开(公告)号：US20220306961A1

公开(公告)日：2022-09-29

申请号：US17632818

申请日：2019-08-08

Applicant: Dow Global Technologies LLC

Inventor： Edward Daugs ,  Martin R. Greaves ,  Yaokun Han

IPC: C10M107/34 ,  C08G65/04 ,  C08G65/332

Abstract: Embodiments of the present disclosure are directed processes to produce a low-color esterified oil soluble polyalkylene glycol, the process comprising forming a reaction mixture including a low viscosity oil soluble polyalkylene glycol and an excess amount of valeric acid, where the reaction mixture is formed in the presence of a catalytic amount of ortho-phosphoric acid catalyst to yield an organic phase including the low-color esterified oil soluble polyalkylene glycol.

公开(公告)号：US20220127542A1

公开(公告)日：2022-04-28

申请号：US17427793

申请日：2019-03-05

Applicant: Dow Global Technologies LLC

Inventor： Yaokun Han ,  Martin R. Greaves ,  Yong Zhao ,  Cheng Shen ,  Tao Wang ,  Jieying Chen

IPC: C10M145/38 ,  C10M169/04 ,  C10M101/00 ,  C10M129/10 ,  C10M145/32 ,  C10M145/34

Abstract: The present disclosure provides A lubricant composition comprises an antioxidant; and an esterified polyalkylene glycol: R1[O(R2O)n(R3O)m(C═O)R4]p, wherein R1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R2O is an oxypropylene moiety derived from 1,2-propylene oxide; R3O is an oxybutylene moiety derived from butylene oxide, wherein R2O and R3O are in a block or a random distribution; R4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4, wherein the antioxidant is present in an amount by weight of at least 0.5% to 20% based upon the weight of the antioxidant and the esterified polyalkylene glycol and the antioxidant is soluble in the esterified polyalkylene glycol in an amount of at least 0.5% by weight. The lubricant composition may be used as an additive to form a hydrocarbon lubricant composition.

公开(公告)号：US20220002536A1

公开(公告)日：2022-01-06

申请号：US16322638

申请日：2017-08-03

Applicant: Dow Global Technologies LLC

Inventor： Aikaterini Tsoutsoura ,  Timothy A. Morley ,  Rainer Koeniger ,  Rene P. Geiger ,  Luis G. Madrigal ,  Luca Lotti ,  Nebojsa Jelic ,  Zeljko Sikman ,  Evelyn A. Zaugg-Hoozemans ,  Martin R. Greaves

IPC: C08L63/00

Abstract: Alkoxylated hydrophobes that include a poly(alkylene oxide) chain of at least 5 oxyalkylene units having a terminal secondary hydroxyl group or a terminal C1−8 hydrocarbyl group are effective internal mold release agents for epoxy resin moldings. The alkoxylated hydrophobe, when mixed with an epoxy resin, forms a mixture that is highly stable when heated to 80 to 100° C. and held at that temperature for a period of as much as 22 days.

公开(公告)号：US10526924B2

公开(公告)日：2020-01-07

申请号：US15775446

申请日：2016-11-02

Applicant: Dow Global Technologies LLC

Inventor： Christoph Lang ,  Martin R. Greaves ,  Evelyn A. Zaugg-Hoozemans

IPC: F01K25/06 ,  C08L71/02 ,  C10M107/34 ,  C09K5/04 ,  C10M145/10 ,  C10M169/04 ,  F01K13/02

Abstract: A thermodynamic cycle such as an organic Rankine cycle system, utilizing a lubricant and a working fluid, for a machine in which pressurized gaseous working fluid is expanded to a lower pressure level and the energy from the fluid expansion is transformed into mechanical rotation energy; the lubricant includes a polyalkylene glycol based lubricant composition and the working fluid includes a mixture of alcohol and water.

公开(公告)号：US20180371957A1

公开(公告)日：2018-12-27

申请号：US15775446

申请日：2016-11-02

Applicant: Dow Global Technologies LLC

Inventor： Christoph Lang ,  Martin R. Greaves ,  Evelyn A. Zaugg-Hoozemans

IPC: F01K25/06 ,  F01K13/02 ,  C10M107/34 ,  C10M145/10 ,  C10M169/04 ,  C09K5/04

Abstract: A thermodynamic cycle such as an organic Rankine cycle system, utilizing a lubricant and a working fluid, for a machine in which pressurized gaseous working fluid is expanded to a lower pressure level and the energy from the fluid expansion is transformed into mechanical rotation energy; the lubricant includes a polyalkylene glycol based lubricant composition and the working fluid includes a mixture of alcohol and water.

公开(公告)号：US20180245016A1

公开(公告)日：2018-08-30

申请号：US15753448

申请日：2016-08-17

Applicant: Dow Global Technologies LLC

Inventor： Martin R. Greaves ,  Evelyn A. Zaugg-Hoozemans

IPC: C10M169/04 ,  C10M105/18 ,  C10M135/36 ,  C10M133/12 ,  C10M129/72

Abstract: A fluid contains a base oil consisting of an alcohol-initiated polyalkylene glycol where polyalkylene glycol component is selected from a homopolymer of 1,2-butylene oxide and copolymer of 1,2-butylene oxide and propylene oxide; a glycerol-initiated unsaturated ester that is free of tertiary carbon atoms and quaternary carbon atoms; and an antioxidant.

公开(公告)号：US11566200B2

公开(公告)日：2023-01-31

申请号：US17427793

申请日：2019-03-05

Applicant: Dow Global Technologies LLC

Inventor： Yaokun Han ,  Martin R. Greaves ,  Yong Zhao ,  Cheng Shen ,  Tao Wang ,  Jieying Chen

IPC: C10M145/38 ,  C10M101/00 ,  C10M129/10 ,  C10M145/32 ,  C10M145/34 ,  C10M169/04 ,  C10N20/02 ,  C10N30/10 ,  C10N40/25

Abstract: The present disclosure provides A lubricant composition comprises an antioxidant; and an esterified polyalkylene glycol: R1[O(R2O)n(R3O)m(C═O)R4]p, wherein R1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R2O is an oxypropylene moiety derived from 1,2-propylene oxide; R3O is an oxybutylene moiety derived from butylene oxide, wherein R2O and R3O are in a block or a random distribution; R4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4, wherein the antioxidant is present in an amount by weight of at least 0.5% to 20% based upon the weight of the antioxidant and the esterified polyalkylene glycol and the antioxidant is soluble in the esterified polyalkylene glycol in an amount of at least 0.5% by weight. The lubricant composition may be used as an additive to form a hydrocarbon lubricant composition.

公开(公告)号：US11279897B2

公开(公告)日：2022-03-22

申请号：US16956759

申请日：2017-12-25

Applicant: Dow Global Technologies LLC

Inventor： Yaokun Han ,  Cheng Shen ,  Martin R. Greaves ,  Yong Zhao

IPC: C10M105/48 ,  C10M107/34 ,  C08G65/332 ,  C10N30/00 ,  C10N20/02 ,  C10N20/04 ,  C10N30/02

Abstract: Embodiments of the present disclosure are directed towards esterified oil soluble polyalkylene glycols of Formula (I): R1[O(R2O)n(R3O)m(C═O)R4]p, where R1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R3O is an oxybutylene moiety derived from butylene oxide, where R2O and R3O are in a block or a random distribution; R4 is a linear alkyl with to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4.

公开(公告)号：US20200332217A1

公开(公告)日：2020-10-22

申请号：US16957433

申请日：2017-12-25

Applicant: Dow Global Technologies LLC

Inventor： Martin R. Greaves ,  Yaokun Han ,  Yong Zhao

IPC: C10M145/38 ,  C10M169/04

Abstract: The present disclosure provides for a lubricant formulation and a method of forming the lubricant formulation for use in an internal combustion engine. The lubricant formulation includes a base oil and an esterified oil-soluble polyalkylene glycol (E-OSP) of Formula (I): R1 [O(R2O)n(R3O)m(C═O)R4]p wherein R1 is a linear alkyi having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R2O is an oxypropylene moiety derived from 1, 2-propylene oxide; R3O is an oxvbutvlene moiety derived from butylene oxide, wherein R2O and R3O are in a block or a random distribution; R4 is a linear alkyl with to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4.