公开(公告)号：US20140105555A1

公开(公告)日：2014-04-17

申请号：US14106258

申请日：2013-12-13

Applicant: DSM IP ASSETS B.V.

Inventor： Xiaosong Dean WU ,  Steven R. SCHMID ,  Edward J MURPHY ,  John M ZIMMERMAN ,  Anthony Joseph TORTORELLO

IPC: C03C25/10 ,  G02B6/036

CPC classification number: C03C25/1065 ,  C03C25/106 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  G02B6/036 ,  Y10T428/2964 ,  C08G18/48

Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and processes to coat the optical fiber are described and claimed. The radiation curable coating is a radiation curable Primary Coating composition comprising: an oligomer; a first diluent monomer; a second diluent monomer, a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, and wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; wherein a cured film of said radiation curable primary coating composition has a peak tan delta Tg of from about −25° C. to about −45° C. and a modulus of from about 0.50 MPa to about 1.2 MPa.

Abstract translation: 用于光纤的主要涂层的辐射固化涂层，涂覆有所述涂层的光纤和涂覆光纤的方法被描述和要求保护。 可辐射固化涂层是可辐射固化的初级涂料组合物，其包含：低聚物; 第一稀释剂单体; 第二稀释剂单体，光引发剂; 抗氧化剂 和粘合促进剂; 其中所述低聚物是以下物质的反应产物：丙烯酸羟乙酯; 芳香族异氰酸酯; 脂族异氰酸酯; 多元醇 催化剂 和抑制剂，并且其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 其中所述可辐射固化的初级涂料组合物的固化膜的峰值tanδTg为约-25℃至约-45℃，模量为约0.50MPa至约1.2MPa。

公开(公告)号：US20140226943A1

公开(公告)日：2014-08-14

申请号：US14104290

申请日：2013-12-12

Applicant: DSM IP ASSETS B.V.

Inventor： Xiaosong Dean WU ,  Steven R. SCHMID ,  Edward J. MURPHY ,  John M. ZIMMERMAN ,  Anthony Joseph TORTORELLO

IPC: G02B6/036 ,  C03B37/012

CPC classification number: G02B6/036 ,  C03B37/01262 ,  C03C25/106 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964 ,  C08G18/48

Abstract: A wet-on-dry process for coating a glass optical fiber with a radiation curable Primary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable Primary Coating composition onto the surface of the optical fiber; (c) applying radiation to effect curing of said radiation curable Primary Coating composition; (d) applying a secondary coating to the Primary Coating; and (e) applying radiation to effect curing of said secondary coating. Also, a wet-on-wet process for coating a glass optical fiber with a radiation curable Primary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable Primary Coating composition onto the surface of the optical fiber; (c) applying a secondary coating to the Primary Coating; and (d) applying radiation to effect curing of the Primary Coating and the secondary coating.

Abstract translation: 一种用于涂覆具有可辐射固化的初级涂层的玻璃光纤的湿法干燥方法，包括（a）操作玻璃拉伸塔以制备玻璃光纤; （b）将可辐射固化的初级涂层组合物施加在光纤表面上; （c）施加辐射以实现所述可辐射固化的初级涂料组合物的固化; （d）将二次涂层施加到初级涂层; 和（e）施加辐射以实现所述二次涂层的固化。 另外，用于将可辐射固化的初级涂层涂覆在玻璃光纤上的湿法湿式方法，包括：（a）操作玻璃拉伸塔以制备玻璃光纤; （b）将可辐射固化的初级涂层组合物施加在光纤表面上; （c）将二次涂层施加到初级涂层; 和（d）施加辐射以实现初级涂层和二次涂层的固化。

公开(公告)号：US20140126866A1

公开(公告)日：2014-05-08

申请号：US14105632

申请日：2013-12-13

Applicant: DSM IP ASSETS B.V.

Inventor： Xiaosong Dean WU ,  Steven R. SCHMID ,  Edward J. MURPHY ,  John M. ZIMMERMAN ,  Anthony Joseph TORTORELLO

IPC: C03C25/10 ,  G02B6/02

CPC classification number: C03C25/1065 ,  C03C25/106 ,  C08G18/672 ,  C08G18/724 ,  C08G18/755 ,  C08G18/7621 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964

Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. A radiation curable Primary Coating composition comprising: an oligomer; a diluent monomer; a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, wherein said catalyst is an organo bismuth catalyst; wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein a cured film of said radiation curable coating composition has a peak tan delta Tg of from about −25° C. to about −45° C.; and a modulus of from about 0.50 MPa to about 1.2 MPa.

Abstract translation: 用作光纤的主要涂层的辐射固化涂层，涂覆有所述涂层的光纤以及用于制备涂覆的光纤的方法。 一种可辐射固化的初级涂料组合物，其包含：低聚物; 稀释剂单体; 光引发剂; 抗氧化剂 和粘合促进剂; 其中所述低聚物是以下物质的反应产物：丙烯酸羟乙酯; 芳香族异氰酸酯; 脂肪族异氰酸酯; 多元醇 催化剂 和抑制剂，其中所述催化剂是有机铋催化剂; 其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 并且其中所述可辐射固化涂料组合物的固化膜具有约-25℃至约-45℃的峰值tanδTg。 和约0.50MPa至约1.2MPa的模量。