公开(公告)号：US06667016B1

公开(公告)日：2003-12-23

申请号：US09530133

申请日：2000-10-06

申请人： Daniel Meyer ,  OLivier Conocar ,  Joël Moreau ,  Michel Wong Chi Man

发明人： Daniel Meyer ,  OLivier Conocar ,  Joël Moreau ,  Michel Wong Chi Man

IPC分类号： C01G5600

CPC分类号： B01J45/00

摘要： Inorganic-organic hybrid gels can be employed to extract chemical species such as lanthanides and actinides and their preparation. The gels include a network of inorganic components with the formula: where M is Si, Ti, Zr or Al, wherein organic molecules which can complex the species to be extracted are integrated, with each organic molecule being covalently linked to one or several M atoms in the network. The network is made by a sol-gel process from metallic alkoxides functionalized with complexing groups (amino, ether, hydroxy, amido, pyridino and bipyridino), capable of extracting metals such as lanthanides and actinides.

摘要翻译： 无机 - 有机杂化凝胶可用于提取化学物质如镧系元素和锕系元素及其制备。凝胶包括具有下式的无机组分网络：其中M是Si，Ti，Zr或Al，其中可以复合的有机分子 要提取的物质是整合的，每个有机分子共价连接到网络中的一个或多个M原子。 该网络由能够提取金属如镧系元素和锕系元素的络合基团（氨基，醚，羟基，酰胺基，吡啶基和联吡啶基）官能化的金属醇化物制成。