Regenerative recovery of sulfur dioxide from effluent gases

    公开(公告)号:US10272380B2

    公开(公告)日:2019-04-30

    申请号:US13283671

    申请日:2011-10-28

    摘要: This invention relates to processes for selective removal of contaminants from effluent gases. A sulfur dioxide absorption/desorption process for selective removal and recovery of sulfur dioxide from effluent gases utilizes a buffered aqueous absorption solution comprising weak inorganic or organic acids or salts thereof, to selectively absorb sulfur dioxide from the effluent gas. Absorbed sulfur dioxide is subsequently stripped to regenerate the absorption solution and produce a sulfur dioxide-enriched gas. A process for simultaneous removal of sulfur dioxide and nitrogen oxides (NOx) from effluent gases and recovery of sulfur dioxide utilizes a buffered aqueous absorption solution including a metal chelate to absorb sulfur dioxide and NOx from the gas and subsequently reducing absorbed NOx to form nitrogen. A process to control sulfate salt contaminant concentration in the absorption solution involves partial crystallization and removal of sulfate salt crystals.

    Energy recovery in manufacture of sulfuric acid
    6.
    发明授权
    Energy recovery in manufacture of sulfuric acid 有权
    能量回收硫酸制造

    公开(公告)号:US08586001B2

    公开(公告)日:2013-11-19

    申请号:US13574023

    申请日:2011-01-20

    IPC分类号: C01B17/74 C01B17/765

    摘要: This invention relates to the recovery of energy in the manufacture of sulfuric acid, and more particularly to enhanced recovery of energy from the absorption of wet SO3 in sulfuric acid. The invention is further directed to control of mist formation during SO3 absorption, and of the sulfuric acid mist content of the gas stream leaving the SO3 absorption step in a process wherein SO3 absorption energy is recovered from absorption acid in useful form.

    摘要翻译: 本发明涉及硫酸制造中的能量回收,更具体地说,涉及在硫酸中吸收湿SO 3的能量回收。 本发明进一步涉及在SO 3吸收期间控制雾形成和在离开SO 3吸收步骤的气流中的硫酸雾含量在其中SO 3吸收能量从有用形式的吸收酸中回收的方法中。