公开(公告)号：US3748361A

公开(公告)日：1973-07-24

申请号：US3748361D

申请日：1971-04-28

申请人： EXXON RESEARCH ENGINEERING CO

发明人： ROSENFELD D ,  LIPPINCOTT S ,  KILSHEIMER J

IPC分类号： A01N57/06 ,  C07F9/09 ,  C07F9/165 ,  C07F9/40 ,  C07C

CPC分类号： A01N57/06 ,  C07F9/097 ,  C07F9/1657 ,  C07F9/4096

摘要： MONO OR POLY HALO-SUBSTITUTED OXIME CARBAMATES AND PHOSPHATES CHARACTERIZED BY EITHER ONE OF THE FOLLOWING FORMULAS:

R-C6H4-C(-CF3)=N-O-C(=Y)-N(-R'')-R", OR R-C6H4-C(-CF3)=

N-O-P(=Y)(-R'')-O-R"

WHERE X IS HALOGEN.

R-C6H4-CO-C(-X)3

WHEREIN R IS ONE SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, METHYL, ISOPROPYL, ETHYL, TRIFLUOROMETHYL, FLUORINE, CHLORINE, BROMINE, METHOXY, METHYLTHIO, NITRO, DIMETHYLAMINO, ETHOXY, AND ISOPROPYLOXY; R'' IS ONE SELECTED FROM THE GROUP CONSISTING OF OR", C1 TO C6 ALKYL, C6 TO C10 ARYL, SUBSTITUTED ALKYL OR ARYL WHEREIN SAID SUBSTITUENT GROUPS ARE SELECTED FROM THE GROUP CONSISTING OF METHYL, ETHYL, TRIFLUOROMETHYL, FLUORINE, CHLORINE, BROMINE; R" IS C1 TO C6 ALKYL, C6 TO C10 ARYL, SUBSTITUTED ALKYL, ARYL WHEREIN THE SUBSTITUENTS ARE THE SAME AS THAT ENUMERATED FOR R''; Y IS S OR O. THESE COMPOUNDS HAVE SHOWN ACTIVITY AS INSECTICIDES. SUCH OXIME CARBAMATES AND PHOSPHATES CAN BE PREPARED FROM KETONES SUCH AS THOSE OF THE FORMULA: