SYNTHESIS OF BORON DIPYRROMETHENES WITH LASER PROPERTIES
    1.
    发明申请
    SYNTHESIS OF BORON DIPYRROMETHENES WITH LASER PROPERTIES 有权
    具有激光特性的硼氢化二异氰酸酯的合成

    公开(公告)号:US20120245362A1

    公开(公告)日:2012-09-27

    申请号:US13498969

    申请日:2010-09-30

    IPC分类号: C07F5/02

    摘要: A family of three 8-alkyl boron dipyrromethenes 1, 2, and 3 has been prepared. These compounds are characterized by emission in the green region of the electromagnetic radiation spectrum and exhibit an almost double laser efficiency than other commercial dyes and much greater photostability. The 8-alkyl boron dipyrromethenes are prepared by catalytic hydrogenation (reduction) of the corresponding 8-alkenyl boron dipyrromethenes, which are obtained by Liebeskind-Srogl coupling of thiomethylboron dipyrromethene with an alkenyl boronic acid.

    摘要翻译: 已经制备了三个8-烷基硼二吡咯二甲苯1,2和3的族。 这些化合物的特征在于在电磁辐射光谱的绿色区域发射并且表现出比其它商业染料几乎双倍的激光效率和更大的光稳定性。 通过催化氢化(还原)通过硫代甲基硼二吡咯亚甲基与烯基硼酸的Liebeskind-Srogl偶合获得的相应的8-链烯基二氢二苯并呋喃来制备8-烷基硼二吡咯并苯。

    Synthesis of boron dipyrromethenes with laser properties
    2.
    发明授权
    Synthesis of boron dipyrromethenes with laser properties 有权
    合成具有激光性能的硼二吡咯

    公开(公告)号:US08664385B2

    公开(公告)日:2014-03-04

    申请号:US13498969

    申请日:2010-09-30

    IPC分类号: C07F5/02

    摘要: A family of three 8-alkyl boron dipyrromethenes 1, 2, and 3 has been prepared. These compounds are characterized by emission in the green region of the electromagnetic radiation spectrum and exhibit an almost double laser efficiency than other commercial dyes and much greater photostability. The 8-alkyl boron dipyrromethenes are prepared by catalytic hydrogenation (reduction) of the corresponding 8-alkenyl boron dipyrromethenes, which are obtained by Liebeskind-Srogl coupling of thiomethylboron dipyrromethene with an alkenyl boronic acid.

    摘要翻译: 已经制备了三个8-烷基硼二吡咯二甲苯1,2和3的族。 这些化合物的特征在于在电磁辐射光谱的绿色区域发射并且表现出比其它商业染料几乎双倍的激光效率和更大的光稳定性。 通过催化氢化(还原)通过硫代甲基硼二吡咯亚甲基与烯基硼酸的Liebeskind-Srogl偶合获得的相应的8-链烯基二氢二苯并呋喃来制备8-烷基硼二吡咯并苯。