公开(公告)号：US5176895A

公开(公告)日：1993-01-05

申请号：US726839

申请日：1991-07-08

申请人： Franz-Josef Biermanns ,  Hans-Heinz Heidbuechel ,  Heinz-Gerd Emans ,  Ralf Weber

发明人： Franz-Josef Biermanns ,  Hans-Heinz Heidbuechel ,  Heinz-Gerd Emans ,  Ralf Weber

IPC分类号： C01B21/08

CPC分类号： C01B21/08

摘要： The present invention deals with the continuous production of sodium azide from sodium amide and nitrous oxide. This reaction takes place on a support material for sodium amide consisting of a mixture of sodium azide and sodium hydroxide. This mixture is passed through a reactor maintained at temperatures of between 200.degree. and 270.degree. C.; a portion of the reaction product and the support material are transferred out of the system at an end of the reactor, and a primary quantity of the reaction product and support material are returned to the reactor inlet where the material is combined with fresh, heated sodium amide in an amount corresponding to the quantity of sodium azide transferred-out with the reaction product and support material. With the aid of this continuous process, higher space-time yields of sodium azide can be obtained than in case of the conventional methods without increasing the danger of no longer controllable explosions.

摘要翻译： 本发明涉及从氨基钠和一氧化二氮连续生产叠氮化钠。 该反应发生在由叠氮化钠和氢氧化钠的混合物组成的酰胺的载体材料上。 将该混合物通过保持在200至270℃温度的反应器; 反应产物和载体材料的一部分在反应器的末端被转移出系统，并且反应产物和载体材料的一次量返回到反应器入口，其中材料与新鲜的加热的钠 酰胺，其量对应于用反应产物和载体材料转出的叠氮化钠的量。 借助于该连续方法，可以获得比常规方法更高的叠氮化钠的时空产率，而不增加不再可控的爆炸的危险。