Abstract:
A system for a fuel-cell subgasket active area edge with through-plane proton conduction is provided. The system includes a fuel-cell membrane-subgasket assembly. The assembly includes an active area including a proton exchange membrane and a first portion of a transitional proton-conductive material attached to the proton exchange membrane. The assembly further includes a non-active subgasket boundary surrounding the active area, configured for preventing a flow of gaseous material and liquid material therethrough. The non-active subgasket boundary includes a non-conductive subgasket and a second portion of the transitional proton-conductive material attached to the subgasket.
Abstract:
Presented are systems for manufacturing membrane electrode assemblies for fuel cells, control logic for operating such systems, methods for making such MEAs, and fuel cell systems employing such MEAs. A method of manufacturing a membrane electrode assembly (MEA) for a fuel cell system includes receiving a standalone membrane (SAM) with a semipermeable proton-exchange membrane having opposing first and second faces and a backing layer attached to the first face. A SAM may be characterized by a lack of cathode and anode electrodes upon receipt of the membrane. The second face of the SAM is placed across a vacuum plate; the vacuum plate applies a predefined vacuum pressure to the SAM. While vacuum pressure is being applied to the SAM by the vacuum plate, the backing layer is removed from the SAM. A subgasket is then attached to the first face of the SAM after the backing layer is removed.
Abstract:
Disclosed are methods for fabricating a reinforced membrane electrode assembly having one or more freestanding external reinforcement layers. The method comprises providing a freestanding external reinforcement layer, and depositing a catalyst solution and membrane solution onto at least a portion of the freestanding external reinforcement layer.
Abstract:
Membrane electrode assemblies for fuel cells and components thereof are provided. In one example, a membrane electrode assembly includes a generally planar gas-permeable body having opposed first and second faces defining in-plane directions and a through-plane direction, a side face extending about an outer perimeter of the body and adjoining each of the first and second faces, and an active region bounded in the through-plane direction by the first and second faces and in the in-plane directions by an active region perimeter defined generally within the outer perimeter. The active region includes a distribution of a composite compound additive dispersed across at least one of the in-plane and through-plane directions. The composite compound additive includes a metal oxide-containing sub-compound and a tungsten-containing sub-compound.
Abstract:
A method for forming a modified solid polymer includes a step of contacting a solid fluorinated polymer with a sodium sodium-naphthalenide solution to form a treated fluorinated solid polymer. The treated fluorinated solid polymer is contacted with carbon dioxide, sulfur dioxide, or sulfur trioxide to form a solid grafted fluorinated polymer. Characteristically, the grafted fluorinated polymer includes appended CO2H or SO2H or SO3H groups. The solid grafted fluorinated polymer is advantageously incorporated into a fuel cell as part of the ion-conducting membrane or a water transport membrane in a humidifier.
Abstract:
A membrane electrode assembly component for a fuel cell includes a generally planar gas-permeable body having opposed first and second faces defining in-plane and through-plane directions, a side face extending about an outer perimeter of the body and adjoining each of the first and second faces, and an active region bounded by the first and second faces and an active region perimeter defined generally within the outer perimeter. The active region includes a distribution of cerium-zirconium oxide nanofibers dispersed across at least one of the in-plane and through-plane directions, wherein the cerium-zirconium oxide nanofibers have a molecular formula of CexZryO4.
Abstract:
Disclosed are methods for fabricating a reinforced membrane electrode assembly having one or more freestanding external reinforcement layers. The method comprises providing a freestanding external reinforcement layer, and depositing a catalyst solution and membrane solution onto at least a portion of the freestanding external reinforcement layer.