公开(公告)号：US4402924A

公开(公告)日：1983-09-06

申请号：US204246

申请日：1980-11-03

申请人： Gary B. McVicker ,  Joseph J. Eggert

发明人： Gary B. McVicker ,  Joseph J. Eggert

IPC分类号： B01J27/12 ,  C01B9/08 ,  C01B11/24 ,  C01F5/28 ,  C01F7/50 ,  C01G1/06 ,  C01G23/02 ,  C01G35/02 ,  C01G43/06

CPC分类号： B01J27/12 ,  C01B11/24 ,  C01B9/08 ,  C01F5/28 ,  C01F7/50 ,  C01G1/06 ,  C01G23/028 ,  C01G35/02 ,  C01G43/06

摘要： A method is described for the preparation of high surface area metal fluorides and metal oxyfluorides comprising reacting high surface area metal oxides with a fluorocarbon vapor wherein the fluorocarbon is selected from the group consisting of CH.sub.4-Q F.sub.Q wherein Q is 1 to 3 and totally or partially fluorinated C.sub.2 -C.sub.6 alkanes, alkenes and alkynes and C.sub.5 -C.sub.6 cyclic alkanes, preferably fluoroform (CHF.sub.3) wherein the metal oxides and the fluorocarbon vapors are contacted at a temperature of from about 300.degree. to about 800.degree. C., for a time sufficient to effect the essentially complete conversion of the metal oxides into metal fluorides or the partial conversion of the metal oxides into metal oxyfluorides. The metal oxides converted into metal fluorides may be selected from the group consisting of the oxides of sodium, potassium, lithium, cesium, magnesium, calcium, barium, strontium, tin, antimony, bismuth, titanium, zirconium, vanadium, chromium, manganese, iron, cobalt, rhodium, mercury, nickel, copper, silver, zinc, cadmium, lead, uranium, europium, indium, lutetium, neodymium, thallium and mixtures thereof. The metal oxides converted into metal oxyfluorides may be selected from the group recited above and further include silicon, niobium, hafnium, tantalum, molybdenum, tungsten, technetium, rhenium, osmium, iridium, lanthanum and ruthenium. The above metal oxides may also be utilized in combination with alumina and silica. The fluorocarbon partial pressure in the treatment vapor may be in the range of from about 0.001 to about 100 atmosphere. By the practice of the instant invention high surface area metal fluoride extrudates are prepared by the conversion of metal oxide extrudate, particularly aluminum fluoride extrudates from alumina extrudates.

摘要翻译： 描述了用于制备高表面积金属氟化物和金属氟氧化物的方法，其包括使高表面积金属氧化物与碳氟化合物蒸气反应，其中氟碳选自CH4-QFQ，其中Q为1至3，全部或部分 氟化C 2 -C 6烷烃，烯烃和炔烃和C 5 -C 6环烷烃，优选氟代（CHF 3），其中金属氧化物和碳氟化合物蒸气在约300至约800℃的温度下接触足够的时间 以实现金属氧化物基本上完全转化为金属氟化物或将金属氧化物部分转化成金属氟氧化物。 转化为金属氟化物的金属氧化物可以选自钠，钾，锂，铯，镁，钙，钡，锶，锡，锑，铋，钛，锆，钒，铬，锰， 铁，钴，铑，汞，镍，铜，银，锌，镉，铅，铀，铕，铟，镥，钕，铊及其混合物。 转化为金属氟氧化物的金属氧化物可以选自上述的基团，还包括硅，铌，铪，钽，钼，钨，锝，铼，锇，铱，镧和钌。 上述金属氧化物也可以与氧化铝和二氧化硅组合使用。 处理蒸气中的氟碳分压可以在约0.001至约100个气氛的范围内。 通过本发明的实践，通过将金属氧化物挤出物，特别是来自氧化铝挤出物的氟化铝挤出物的转化制备高表面积金属氟化物挤出物。

公开(公告)号：US4275046A

公开(公告)日：1981-06-23

申请号：US869776

申请日：1978-01-16

申请人： Gary B. McVicker ,  Joseph J. Eggert

发明人： Gary B. McVicker ,  Joseph J. Eggert

IPC分类号： B01J27/12 ,  C01B9/08 ,  C01B11/24 ,  C01F5/28 ,  C01F7/50 ,  C01F7/56 ,  C01G1/06 ,  C01G23/02 ,  C01G35/02 ,  C01G43/06

CPC分类号： C01G35/02 ,  B01J27/12 ,  C01B11/24 ,  C01B9/08 ,  C01F5/28 ,  C01F7/50 ,  C01G1/06 ,  C01G23/028 ,  C01G43/06

摘要： A method is described for the preparation of high surface area metal fluorides and metal oxyfluorides comprising reacting high surface area metal oxides with a fluorocarbon vapor wherein the fluorocarbon is selected from the group consisting of CH.sub.4-Q F.sub.Q wherein Q is 1 to 3 and totally or partially fluorinated C.sub.2 -C.sub.6 alkanes, alkenes and alkynes and C.sub.5 -C.sub.6 cyclic alkanes, preferably fluoroform (CHF.sub.3) wherein the metal oxides and the fluorocarbon vapors are contacted at a temperature of from about 300.degree. to about 800.degree. C., for a time sufficient to effect the essentially complete conversion of the metal oxides into metal fluorides or the partial conversion of the metal oxides into metal oxyfluorides. The metal oxides converted into metal fluorides may be selected from the group consisting of the oxides of sodium, potassium, lithium, cesium, magnesium, calcium, barium, strontium, tin, antimony, bismuth, titanium, zirconium, vanadium, chromium, manganese, iron, cobalt, rhodium, mercury, nickel, copper, silver, zinc, cadmium, lead, uranium, europium, idium, lutetium, neodymium, thallium and mixtures thereof. The metal oxides converted into metal oxyfluorides may be selected from the group recited above and further include silicon, niobium, hafnium, tantalum, molybdenum, tungsten, technetium, rhenium, osmium, iridium, lanthanum and ruthenium. The above metal oxides may also be utilized in combination with alumina and silica. The fluorocarbon partial pressure in the treatment vapor may be in the range of from about 0.001 to about 100 atmosphere. By the practice of the instant invention high surface area metal fluoride extrudates are prepared by the conversion of metal oxide extrudate, particularly aluminum fluoride extrudates from alumina extrudates.

摘要翻译： 描述了用于制备高表面积金属氟化物和金属氟氧化物的方法，其包括使高表面积金属氧化物与碳氟化合物蒸气反应，其中氟碳选自CH4-QFQ，其中Q为1至3，全部或部分 氟化C 2 -C 6烷烃，烯烃和炔烃和C 5 -C 6环烷烃，优选氟代（CHF 3），其中金属氧化物和碳氟化合物蒸气在约300至约800℃的温度下接触足够的时间 以实现金属氧化物基本上完全转化为金属氟化物或将金属氧化物部分转化成金属氟氧化物。 转化为金属氟化物的金属氧化物可以选自钠，钾，锂，铯，镁，钙，钡，锶，锡，锑，铋，钛，锆，钒，铬，锰， 铁，钴，铑，汞，镍，铜，银，锌，镉，铅，铀，铕，ium，镥，钕，铊及其混合物。 转化为金属氟氧化物的金属氧化物可以选自上述的基团，还包括硅，铌，铪，钽，钼，钨，锝，铼，锇，铱，镧和钌。 上述金属氧化物也可以与氧化铝和二氧化硅组合使用。 处理蒸气中的氟碳分压可以在约0.001至约100个气氛的范围内。 通过本发明的实践，通过将金属氧化物挤出物，特别是来自氧化铝挤出物的氟化铝挤出物的转化制备高表面积金属氟化物挤出物。