公开(公告)号：US3665028A

公开(公告)日：1972-05-23

申请号：US3665028D

申请日：1968-03-06

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L

IPC: C07C27/12 ,  C07C27/00 ,  C07C29/52 ,  C07C67/00 ,  C07F5/04

CPC classification number: C07C29/52 ,  C07C2601/14 ,  C07C35/08

Abstract: This invention relates to the oxidation of hydrocarbons in the presence of boron compounds. More specifically, the invention teaches a method of improving the selectivity of the reaction and the distribution of the oxidation products.

公开(公告)号：US3397954A

公开(公告)日：1968-08-20

申请号：US39375164

申请日：1964-09-01

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L ,  FEDER JACK B

IPC: C01B35/10

CPC classification number: C01B35/06 ,  C01B35/10

公开(公告)号：US3256327A

公开(公告)日：1966-06-14

申请号：US44669565

申请日：1965-04-08

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L ,  HARRY OLENBERG

IPC: C07C51/353

CPC classification number: C07C51/353 ,  C07C57/15

公开(公告)号：US3420897A

公开(公告)日：1969-01-07

申请号：US3420897D

申请日：1965-05-07

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L ,  OLENBERG HARRY

IPC: C07C29/52 ,  C07C35/08

CPC classification number: C07C29/52 ,  C07C2601/14 ,  C07C35/08

公开(公告)号：US3288724A

公开(公告)日：1966-11-29

申请号：US45594465

申请日：1965-05-14

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L ,  MITCHELL BECKER

IPC: B01J23/22 ,  C07C51/265

CPC classification number: B01J23/22 ,  C07C51/265 ,  C07C63/16

公开(公告)号：US3458534A

公开(公告)日：1969-07-29

申请号：US3458534D

申请日：1968-04-10

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L ,  WINNICK CHARLES N

IPC: C07C39/14 ,  C07C51/31 ,  C07D301/19 ,  C07D5/34

CPC classification number: C07D301/19 ,  C07C39/14 ,  C07C51/313 ,  C07C63/16

公开(公告)号：US3141037A

公开(公告)日：1964-07-14

申请号：US9302961

申请日：1961-03-03

Applicant: HALCON INTERNATIONAL INC

Inventor： HARRY OLENBERG ,  RUSSELL JOSEPH L ,  MITCHELL BECKER

IPC: C07C51/353

CPC classification number: C07C51/353 ,  C07C57/15

公开(公告)号：US3140300A

公开(公告)日：1964-07-07

申请号：US6925660

申请日：1960-11-15

Applicant: HALCON INTERNATIONAL INC

Inventor： MANFRED GANS ,  RUSSELL JOSEPH L

IPC: C07C51/573

CPC classification number: C07C51/573 ,  C07C57/145

公开(公告)号：US3497544A

公开(公告)日：1970-02-24

申请号：US3497544D

申请日：1967-01-27

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L

IPC: C07C29/52 ,  C07C27/12 ,  C07C27/26

CPC classification number: C07C29/52 ,  C07C2601/14 ,  C07C35/08

公开(公告)号：US3488740A

公开(公告)日：1970-01-06

申请号：US3488740D

申请日：1966-11-23

Applicant: HALCON INTERNATIONAL INC

Inventor： RUSSELL JOSEPH L

IPC: C07C27/12 ,  C07C27/00 ,  C07C29/52 ,  C07C67/00

CPC classification number: C07C29/52 ,  C07C2601/14 ,  C07C2601/20 ,  C07C35/08 ,  C07C35/205

Abstract: 1,210,673. Partial oxidation of hydrocarbons. HALCON INTERNATIONAL Inc. 20 Nov., 1967 [23 Nov., 1966], No. 52594/67. Heading C2C. Oxygenated compounds including alcohols and ketones are produced in the continuous molecular oxygen oxidation of at least one saturated hydrocarbon supplied as a feed containing more than 95 molar per cent saturated hydrocarbons, wherein the hydrocarbon and molecular oxygen are reacted in the liquid phase in a plurality of separate oxidation satages, connected in series, in the presence of a boron adjuvant, wherein the amount of boron adjuvant present in the effluent from the first oxidation stage is sufficient to provide at least one gm. atom boron/three gm. moles of total hydrocarbon alcohol (defined as consisting of the mixture of hydrocarbon alcohol as such or in the form of the hydroperoxide and the borate esters of the hydrocarbon alcohol) in said effluent but less than an amount sufficient to result in the formation of a separate solids phase in said effluent and wherein additional boron adjuvant is added to at least one other of the oxidation stages, the. total amount of boron adjuvant employed in the oxidation being sufficient to provide at least one gram atom of boron per three gram moles of total hydrocarbon alcohol in the effluent from the last of the oxidation stages. The product alcohols are liberated by the hydrolysis of the reaction mixture. Examples use cyclohexane, cyclododecane and a C 12-14 paraffinic petroleum naphtha.