Benzoxanthene and benzothioxanthene dyestuffs and process for their manufacture
    2.
    发明授权
    Benzoxanthene and benzothioxanthene dyestuffs and process for their manufacture 失效
    苯并噻唑和苯并噻唑的制备及其制备方法

    公开(公告)号:US3888863A

    公开(公告)日:1975-06-10

    申请号:US32057873

    申请日:1973-01-02

    申请人: HOECHST AG

    发明人: TROSTER HELMUT

    IPC分类号: C07D491/06 C07D39/00

    CPC分类号: C07D491/06

    摘要: IN WHICH X represents an oxygen or sulfur atom, Y represents

    Valuable benzoxanthene and benzothioxanthene dyestuffs of the general formula

    D R A W I N G
    GROUPS, WHEREIN R stands for a hydrogen atom or an alkyl, cycloalkyl or aryl group which may be substituted, a heterocyclic radical, a hydroxyl or amino group, R1 and R2 each represent hydrogen atoms, halogen atoms, especially chlorine or bromine atoms, alkyl or alkoxy groups, and n stands for a number of 1 to 3, which dyestuffs are suitable for dyeing and printing of plastic materials and excellently suitable as fluorescing dyestuffs in the dyeing of condensation resins which when dyed are distinguished by excellent fastness to bleeding and good fastness to light.

    Perinone dyestuffs and process for preparing them
    3.
    发明授权
    Perinone dyestuffs and process for preparing them 失效
    围Per素染料及其制备方法

    公开(公告)号:US3920662A

    公开(公告)日:1975-11-18

    申请号:US38479473

    申请日:1973-08-02

    申请人: HOECHST AG

    发明人: TROSTER HELMUT

    CPC分类号: C09B57/00

    摘要: Dyestuffs consisting of the mixture of isomers of the formulae
    wherein R5 and R6 are hydrogen, alkyl or hydroxyalkyl with 1 to 4 carbon atoms or phenyl, or together are piperidine, morpholine or piperazine. The new dyestuffs are very suitable for the dyeing of synthetic materials such as polyethylene-glycol terephthalate, acetyl cellulose or polyamides. They yield brilliant greenish yellow to orange red shades which have a good fastness to light and to thermofixation. They are also very suitable for the dyeing of fibre-forming polymers such as for example polyethylene-glycol terephthalate in the mass. Furthermore, a big part of the dyestuffs can be used for dyeing synthetic fibre materials such as polyester fibers from organic solvents, for example perchloroethylene.

    WHEREIN R1 is hydrogen, alkyl with 1 to 20 carbon atoms, alkoxyalkyl or alkoxycarbonyl each with up to 4 carbon atoms, benzyl, alkoxycarbonyl with up to 20 carbon atoms or phenyl, R2 is alkoxycarbonyl with up to 20 carbon atoms, cyano, alcanoyl, alkoxyalkoxycarbonyl each with up to 4 carbon atoms, carbonamido, phenylcarbonamido, mono- or dialkylcarbonamido with up to 8 carbon atoms or cyclohexylcarbonamido, R3 and R4 are identical and are hydrogen or alkoxy with 1 to 4 carbon atom atoms or R3 is alkoxy with 1 to 4 carbon atoms and R4 is hydrogen and R is phenylthio which may be substituted by one or two chlorine or bromine atoms, alkyl, alkoxy, carbalkoxy, alkylsulfonyl groups and with up to 4 carbon atoms or a cyano, trifluoromethyl or nitro group; naphthylthio, pyridinethio, benzimidazolyl-2-thio, benzoxazolyl-2-thio, benzthiazolyl-2-thio or an amino group of the formula

    摘要翻译: 由式WHEREIN R1为氢的异构体与碳原子数1〜20的烷基,烷氧基烷基或烷氧基羰基,最多含有4个碳原子的苄基,至多20个碳原子的烷氧羰基或苯基组成的染料,R2为烷氧基羰基, 最多20个碳原子,氰基,烷酰基,烷氧基烷氧基羰基,各自具有至多4个碳原子,碳酰氨基,苯基碳酰氨基,具有至多8个碳原子的单或二烷基酰氨基或环己基碳酰氨基,R3和R4相同,为氢或烷氧基, 碳原子或R3是具有1至4个碳原子的烷氧基,R4是氢,R是可被一个或两个氯或溴原子,烷基,烷氧基,烷氧基,烷基磺酰基和至多4个碳原子取代的苯硫基, 氰基,三氟甲基或硝基; 萘硫基,吡啶硫基,苯并咪唑-2-硫基,苯并恶唑基-2-硫代,苯并噻唑基-2-硫代或式R 5 -N ANGLE R 6的氨基,其中R 5和R 6是氢,具有1至4个碳原子的烷基或羟基烷基或 苯基或一起是哌啶,吗啉或哌嗪。