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    Rapid curing adhesive compositions comprising the reaction product of a ketone aldehyde condensation polymer and a primary aromatic amine
    1.
    发明授权
    Rapid curing adhesive compositions comprising the reaction product of a ketone aldehyde condensation polymer and a primary aromatic amine 失效
    快速固化粘合剂组合物，包括酮酮醛缩合聚合物和主要芳族胺的反应产物

    公开(公告)号：US3931110A

    公开(公告)日：1976-01-06

    申请号：US408407

    申请日：1973-10-23

    申请人： Harlan G. Freeman ,  Gene F. Baxter ,  George Graham Allen

    发明人： Harlan G. Freeman ,  Gene F. Baxter ,  George Graham Allen

    IPC分类号： B29C65/00 ,  C09J161/22 ,  C08G6/02

    CPC分类号： C09J161/22

    摘要： This invention describes resin products having particular utility as rapid curing adhesives for wood and other materials, and processes for making the resin compositions. The reaction products are made by reacting an aldehyde condensation polymer, such as a phenol-formaldehyde condensation polymer, with a primary aromatic amine having the formula: ##SPC1##WhereX.sub.1 is --NH.sub.2 --CH.sub.2 NH.sub.2 ;X.sub.2 is --X.sub.1 --OH--alkoxy;X.sub.3 is -X.sub.1 COOH NHCOCH.sub.3 NO.sub.2 OH C.sub.1 to C.sub.5 alkyl H -halogen halogenated alkyl alkoxy X.sub.4 is C.sub.1 to C.sub.4 alkyl, --H--aryl; andA is ##EQU1## where Y.sub.1 and Y.sub.2 are hydrogen or alkyl radicals having from 1 to 3 carbon atoms and Z is an integer from 0 to 2,--SO.sub.2 ----NH----O----S---- C----S--S----N=N--, to obtain an amine-modified polymer. On blending an appropriate hardening agent with the amine-modified polymer, the composition cures very rapidly at ambient temperature. When pieces of wood or other materials are spread with the preferred adhesives employing the resin compositions of this invention and brought into contact with another wood or other surface the bond strength develops within minutes.