公开(公告)号：US06348537B2

公开(公告)日：2002-02-19

申请号：US09774069

申请日：2001-01-31

申请人： Hideyuki Sugamoto ,  Osamu Kawai ,  Tetsuya Sawano

发明人： Hideyuki Sugamoto ,  Osamu Kawai ,  Tetsuya Sawano

IPC分类号： C08K334

CPC分类号： C08F290/147 ,  C08F283/002 ,  C08F290/06 ,  C08F290/067 ,  C08F290/14 ,  C08F2222/1013 ,  C08F2222/1086 ,  C09D4/06 ,  C08F2230/085

摘要： A coating agent comprising 50 to 99 parts by weight of a monomer or monomer mixture (M) composed of 50 to 100% by weight of a polyfunctional (meth)acrylate monomer (m-1) having two or more (meth)acryloyloxy groups and 0 to 50% by weight of a monofunctional (meth)acrylate monomer (m-2), and 1 to 50 parts by weight of colloidal silica, wherein the colloidal silica contains colloidal silica in a narrow and long form having an average diameter of 5 to 20 nm and an average length of 40 to 300 nm in an amount of 5 to 100% by weight based on the total colloidal silica weight; and a resin molded article having a coated layer obtained by hardening this coating agent, are disclosed. This colloidal silica-containing coating agent is excellent in appearance, hardness, abrasion resistance, weather resistance, adhesion with a substrate, no need of a solvent, and the like.

摘要翻译： 包含50至99重量份由50至100重量％的具有两个或多个（甲基）丙烯酰氧基的多官能（甲基）丙烯酸酯单体（m-1）组成的单体或单体混合物（M）的涂料， 0〜50重量％的单官能（甲基）丙烯酸酯单体（m-2），和1〜50重量份胶体二氧化硅，其中，胶体二氧化硅含有平均粒径为5〜 至20nm，平均长度为40〜300nm，相对于总胶体二氧化硅重量为5〜100重量％ 并且公开了具有通过使该涂布剂硬化而得到的涂布层的树脂成形品。 这种胶态二氧化硅的涂布剂的外观，硬度，耐磨性，耐候性，与基材的粘合性，不需要溶剂等都是优异的。

公开(公告)号：US08231981B2

公开(公告)日：2012-07-31

申请号：US12171074

申请日：2008-07-10

申请人： Hideyuki Sugamoto ,  Osamu Kawai ,  Hiroki Hatakeyama

发明人： Hideyuki Sugamoto ,  Osamu Kawai ,  Hiroki Hatakeyama

IPC分类号： B23B27/00 ,  B23B27/08

CPC分类号： G06F3/045 ,  C08F220/18 ,  Y10T428/31855 ,  Y10T428/31909

摘要： A method of producing an acrylic resin plate, comprising a step of adding 0.001 to 1 part by weight of a polymerization initiator having 10 hours half life temperature of 80° C. or more and 0.015 to 0.2 parts by weight of cyclohexadiene or terpenoid-based compound into 100 parts by weight of a mixture composed of an alkyl methacrylate having a C1-4 alkyl group and a poly-functional (meth)acrylate to give a polymerizable mixture, and a step of polymerizing said polymerizable mixture; an acrylic resin comprising 3 to 30 wt % of an alkyl methacrylate unit having a C8-20 alkyl group, 2 to 35 wt % of a mono-ethylenically unsaturated monomer unit containing an alkyl methacrylate unit having a C1-4 alkyl group and 35 to 95 wt % of a poly-functional (meth)acrylate unit; an acrylic resin plate made of the resin and production process the same, and a transparent electrode plate for touch panel and a touch panel having them.

摘要翻译： 一种丙烯酸树脂板的制造方法，其特征在于，包括将0.001〜1重量份的10分钟半衰期为80℃以上的聚合引发剂和0.015〜0.2重量份的环己二烯或萜类系 将100重量份由具有C1-4烷基的甲基丙烯酸烷基酯和多官能（甲基）丙烯酸酯组成的混合物混合，得到可聚合的混合物，以及使所述可聚合混合物聚合的步骤; 包含3至30重量％的具有C8-20烷基的甲基丙烯酸烷基酯单元，2至35重量％的含有具有C 1-4烷基的甲基丙烯酸烷基酯单元的单烯属不饱和单体单元和35至 95重量％的多官能（甲基）丙烯酸酯单元; 由树脂制成的丙烯酸树脂板和制造方法相同，以及用于触摸面板的透明电极板和具有它们的触摸面板。

公开(公告)号：US20080278457A1

公开(公告)日：2008-11-13

申请号：US12171074

申请日：2008-07-10

申请人： Hideyuki Sugamoto ,  Osamu Kawai ,  Hiroki Hatakeyama

发明人： Hideyuki Sugamoto ,  Osamu Kawai ,  Hiroki Hatakeyama

IPC分类号： G06F3/044 ,  B29D11/00

CPC分类号： G06F3/045 ,  C08F220/18 ,  Y10T428/31855 ,  Y10T428/31909

摘要： A method of producing an acrylic resin plate, comprising a step of adding 0.001 to 1 part by weight of a polymerization initiator having 10 hours half life temperature of 80° C. or more and 0.015 to 0.2 parts by weight of cyclohexadiene or terpenoid-based compound into 100 parts by weight of a mixture composed of an alkyl methacrylate having a C1-4 alkyl group and a poly-functional (meth)acrylate to give a polymerizable mixture, and a step of polymerizing said polymerizable mixture; an acrylic resin comprising 3 to 30 wt % of an alkyl methacrylate unit having a C8-20 alkyl group, 2 to 35 wt % of a mono-ethylenically unsaturated monomer unit containing an alkyl methacrylate unit having a C1-4 alkyl group and 35 to 95 wt % of a poly-functional (meth)acrylate unit; an acrylic resin plate made of the resin and production process the same, and a transparent electrode plate for touch panel and a touch panel having them.

摘要翻译： 一种丙烯酸树脂板的制造方法，其特征在于，包括将0.001〜1重量份的10分钟半衰期为80℃以上的聚合引发剂和0.015〜0.2重量份的环己二烯或萜类系 将100重量份由具有C1-4烷基的甲基丙烯酸烷基酯和多官能（甲基）丙烯酸酯组成的混合物混合，得到可聚合的混合物，以及使所述可聚合混合物聚合的步骤; 包含3至30重量％的具有C8-20烷基的甲基丙烯酸烷基酯单元，2至35重量％的含有具有C 1-4烷基的甲基丙烯酸烷基酯单元的单烯属不饱和单体单元和35至 95重量％的多官能（甲基）丙烯酸酯单元; 由树脂制成的丙烯酸树脂板和制造方法相同，以及用于触摸面板的透明电极板和具有它们的触摸面板。

公开(公告)号：US20060041067A1

公开(公告)日：2006-02-23

申请号：US10534525

申请日：2003-11-10

申请人： Hideyuki Sugamoto ,  Osamu Kawai

发明人： Hideyuki Sugamoto ,  Osamu Kawai

IPC分类号： C08L61/00 ,  C08K5/07

CPC分类号： G06F3/045 ,  C08F220/18 ,  Y10T428/31855 ,  Y10T428/31909

摘要： A method of producing an acrylic resin plate, comprising a step of adding 0.001 to 1 part by weight of a polymerization initiator having 10 hours half life temperature of 80° C. or more and 0.015 to 0.2 parts by weight of cyclohexadiene or terpenoid-based compound into 100 parts by weight of a mixture composed of an alkyl methacrylate having a C1-4 alkyl group and a poly-functional (meth)acrylate to give a polymerizable mixture, and a step of polymerizing said polymerizable mixture; an acrylic resin comprising 3 to 30 wt % of an alkyl methacrylate unit having a C8-20 alkyl group, 2 to 35 wt % of a mono-ethylenically unsaturated monomer unit containing an alkyl methacrylate unit having a C1-4 alkyl group and 35 to 95 wt % of a poly-functional (meth)acrylate unit; an acrylic resin plate made of the resin and production process the same, and a transparent electrode plate for touch panel and a touch panel having them.

摘要翻译： 一种丙烯酸树脂板的制造方法，其特征在于，包括将0.001〜1重量份的10分钟半衰期为80℃以上的聚合引发剂和0.015〜0.2重量份的环己二烯或萜类系 将100重量份由具有C1-4烷基的甲基丙烯酸烷基酯和多官能（甲基）丙烯酸酯组成的混合物混合，得到可聚合的混合物，以及使所述可聚合混合物聚合的步骤; 包含3至30重量％的具有C8-20烷基的甲基丙烯酸烷基酯单元，2至35重量％的含有具有C 1-4烷基的甲基丙烯酸烷基酯单元的单烯属不饱和单体单元和35至 95重量％的多官能（甲基）丙烯酸酯单元; 由树脂制成的丙烯酸树脂板和制造方法相同，以及用于触摸面板的透明电极板和具有它们的触摸面板。