公开(公告)号：US6013748A

公开(公告)日：2000-01-11

申请号：US46658

申请日：1998-03-24

申请人： Hiroo Matsuda ,  Takashi Fukuda ,  Shinji Yamada ,  Tatsumi Kimura ,  Masao Kato ,  Xuan-Ming Duan ,  Shuji Okada ,  Hachiro Nakanishi

发明人： Hiroo Matsuda ,  Takashi Fukuda ,  Shinji Yamada ,  Tatsumi Kimura ,  Masao Kato ,  Xuan-Ming Duan ,  Shuji Okada ,  Hachiro Nakanishi

IPC分类号： C07C69/92 ,  C07C205/43 ,  C07C255/55 ,  C08F2/00 ,  G02F1/361

CPC分类号： C07C255/55 ,  C07C205/43 ,  C07C69/92 ,  G02F1/3615

摘要： Disclosed is a novel aromatic ester compound represented by the general formula ##STR1## in which Pn is a 1,4-phenylene group, R.sup.1 is an alkyl group having 1 to 4 carbon atoms, R.sup.2 is a group selected from the group consisting of perfluoroalkyl groups having 1 to 4 carbon atoms, cyano group, nitro group, 2,2-dicyanoethenyl group and methylsulfonyl group and the subscript n is a number of 2, 3 or 4. These aromatic ester compounds are useful as a second-order non-linear optical material in the ultraviolet wavelength range so that a resin film containing the compound has a good second-order non-linear optical coefficient d.sub.33 of 2-4.times.10.sup.-9 esu.

摘要翻译： 公开了一种由通式表示的新型芳族酯化合物，其中Pn是1,4-亚苯基，R1是具有1-4个碳原子的烷基，R2是选自具有1个碳原子的全氟烷基 至4个碳原子，氰基，硝基，2,2-二氰基乙烯基和甲基磺酰基，下标n为2,3或4.这些芳族酯化合物可用作二级非线性光学材料 在紫外线波长范围内，含有该化合物的树脂膜的二次非线性光学系数d33为2-4×10-9 esu。