公开(公告)号：US3645859A

公开(公告)日：1972-02-29

申请号：US3645859D

申请日：1970-07-01

Applicant: IBM

Inventor： DAMM EUGENE P JR ,  GROBIN ALLEN W JR ,  HEREL EDWIN H ,  RADOVSKY DAVID A

IPC: C25D11/34 ,  C23F17/00

CPC classification number: C25D11/34 ,  Y10S428/929

Abstract: Electrically functional and decorative surface coatings- which are durable, attractive in appearance and resistant to corrosion and most importantly have long-lasting retention of foregoing properties under service conditions- are produced by reactive absorption of unsaturated oils into oxides of certain metals and metal alloys. The oil-treated oxide surfaces- especially after periods of in-service use- have lower contact impedance, higher conductivity, better retention of appearance and greater resistance to wear and corrosion than the untreated oxides. It appears that a highly stable interfacial compound is formed between the oil, the oxide coating and possibly the unoxidized basic metallic material, which differs considerably from the oxide in stability and general physical composition. Existence of this compound is evidenced by the heightened ability of the treated finish to withstand corrosion and scratching, and the tendency of the finish to actually harden and acquire greater wear resistance and permanence of appearance with age.

Abstract translation: 电气功能和装饰性表面涂层，其耐用性，外观吸引力和耐腐蚀性，最重要的是在使用条件下对前述性能的持久保留 - 是通过将不饱和油反应吸收到某些金属和金属合金的氧化物中产生的。 经过油处理的氧化物表面 - 特别是在使用期间 - 具有比未处理的氧化物更低的接触阻抗，更高的导电性，更好的保持外观和更大的耐磨性和腐蚀性。 似乎在油，氧化物涂层和可能的未氧化的碱性金属材料之间形成高度稳定的界面化合物，其与氧化物的稳定性和一般物理组成显着不同。 这种化合物的存在通过处理后的表面处理耐腐蚀和划伤的能力提高，以及涂层实际上硬化和获得更大的耐磨性和耐老化性的趋势来证明。