公开(公告)号：US20190168202A1

公开(公告)日：2019-06-06

申请号：US16306037

申请日：2017-05-17

Applicant: IFP Energies Nouvelles

Inventor： Pierre-Alain BREUIL ,  David PRORIOL

IPC: B01J31/18 ,  B01J31/14 ,  C07F11/00 ,  C07C2/36

Abstract: The invention pertains to a composition that comprises at least one chromium precursor, at least one heteroatomic ligand, and, optionally, at least one activator. The invention also pertains to the method for preparation of the composition in accordance with the invention and the use of said composition in a method for oligomerization of olefins.

公开(公告)号：US20130217941A1

公开(公告)日：2013-08-22

申请号：US13852403

申请日：2013-03-28

Applicant: IFP ENERGIES NOUVELLES

Inventor： Fabien GRASSET ,  Stephane HARRY ,  David PRORIOL ,  Lionel MAGNA

IPC: C07C2/34

CPC classification number: C07C2/34 ,  B01J31/0212 ,  B01J2231/20 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07C2/32 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  Y02P20/52 ,  C07C11/02

Abstract: The invention describes a process for oligomerization of olefins into compounds or into a mixture of compounds of general formula CpH2p with 4≦p≦80 that employs a catalytic composition that comprises at least one organometallic complex of an element of group IV that is selected from among titanium, zirconium, or hafnium, whereby said organometallic complex contains at least one alkoxy-type ligand that is functionalized by a heteroatom that is selected from among nitrogen, oxygen, phosphorus or sulfur, or by an aromatic group.

Abstract translation: 本发明描述了一种使烯烃低聚成化合物或通过化学式CpH2p与4- @ 80的混合物的方法，该方法采用催化组合物，该催化组合物包含至少一种选自以下的第IV族元素的有机金属络合物： 钛，锆或铪，由此所述有机金属络合物含有至少一个由选自氮，氧，磷或硫的杂原子官能化的烷氧基型配体或芳族基团。