公开(公告)号：US20140364566A1

公开(公告)日：2014-12-11

申请号：US14296097

申请日：2014-06-04

申请人： INSTITUTO MEXICANO DEL PETROLEO

发明人： Cesar Andres FLORES SANDOVAL ,  Eugenio Alejandro FLORES OROPEZA ,  Alfonso LOPEZ ORTEGA ,  Jose Gonzalo HERNANDEZ CORTEZ ,  Aristeo ESTRADA BUENDIA ,  Laura Veronica CASTRO SOTELO ,  Reyna REYES MARTINEZ ,  Fernando ALVAREZ RAMIREZ ,  Arquimedes ESTRADA MARTINEZ ,  Flavio Salvador VAZQUEZ MORENO

IPC分类号： C08G81/00

CPC分类号： C08G81/00 ,  C08G65/08 ,  C08G65/333 ,  C08G65/3344 ,  C08G2650/50 ,  C08G2650/58 ,  C08L71/02

摘要： A chemical synthesis process is provided for the functionalization of monodispersed triblock copolymer (POEw-POPy-POEw) with secondary or tertiary amines at a semi-industrial level in glass reactors having a capacity between 1 L and 100 L. The process includes two stages where the first stage uses an alkylsulfonyl or arylsulfonyl chloride to obtain better leaving groups, and the second stage is the nucleophilic substitution with secondary or tertiary amines, to obtain the bifunctionalized triblock copolymers. The main advantage for this process is to reduce the quantity of unitary process done in each stage, the optimization of reaction times, and the stoichiometric relationships.

摘要翻译： 提供了一种化学合成方法，用于在具有1L和100L之间的容量的玻璃反应器中在半工业水平下用仲胺或叔胺官能化单分散三嵌段共聚物（POEw-POPy-POEw）。该方法包括两个阶段， 第一阶段使用烷基磺酰基或芳基磺酰氯获得更好的离去基团，第二阶段是用仲胺或叔胺进行亲核取代，得到双官能化三嵌段共聚物。 该过程的主要优点是减少每个阶段完成的单一过程数量，优化反应时间和化学计量关系。

公开(公告)号：US20150157961A1

公开(公告)日：2015-06-11

申请号：US14560179

申请日：2014-12-04

申请人： INSTITUTO MEXICANO DEL PETROLEO

发明人： Enrique CEVADA MAYA ,  Laura Veronica CASTRO SOTELO ,  Edgar Ivan HERNANDEZ RAMIREZ ,  Cesar Andres FLORES SANDOVAL ,  Alfonso LOPEZ ORTEGA ,  Aristeo ESTRADA BUENDIA ,  Fernando ALVAREZ RAMIREZ ,  Arquimedes ESTRADA MARTINEZ ,  Flavio Salvador VAZQUEZ MORENO

IPC分类号： B01D19/04 ,  C10G33/04

CPC分类号： B01D19/0404 ,  C10G29/22

摘要： The present invention relates to the application based on alkyl acrylate homopolymers, such as antifoaming agents in crude oils with densities of 10 to 40° API. Evaluation tests in “live” crude oil, under similar gas-liquid separation equipment conditions, showed that these polymers based on alkyl acrylate are effective foaming inhibitors in heavy and super-heavy crude oils, reducing the foam between 15 and 50% faster compared to crude oil without an antifoaming agent. Some acrylics show better performance than commercial silicon-based polymers, which suppress foam 20-25% faster than the blank. The antifoaming agents of this invention, based on alkyl acrylate and totally free of silicon, is an advantageous option, to replace the silicone-based foam inhibitors currently on the market.

摘要翻译： 本发明涉及基于丙烯酸烷基酯均聚物的应用，例如密度为10至40°API的原油中的消泡剂。 在类似的气 - 液分离设备条件下，“活”原油的评估测试表明，基于丙烯酸烷基酯的这些聚合物是重质和超重质原油中的有效发泡抑制剂，与泡沫相比，将泡沫减少15％至50％ 没有消泡剂的原油。 一些丙烯酸树脂显示出比商业硅基聚合物更好的性能，其抑制泡沫比空白快20-25％。 基于丙烯酸烷基酯并且完全不含硅的本发明的消泡剂是替代目前市场上的硅酮泡沫抑制剂的有利选择。