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公开(公告)号：US20170137572A1
公开(公告)日：2017-05-18
申请号：US15157224
申请日：2016-05-17
IPC分类号： C08G75/02
CPC分类号： C08G75/02
摘要： Thioaminal polymers are made from hexahydrotriazine precursors and dithiol precursors. The precursors are blended together and subjected to mild heating to make the polymers. An amine scavenger is used to remove amine byproducts from the reaction, thus promoting polymer growth to high molecular weight. The polymers have the general structure wherein each R1 is independently an organic or hetero-organic group, a plurality of R2 groups are substituents having molecular weight greater than about 120 Daltons, and n is an integer greater than or equal to 1. The polymers may be functionalized by adding a thiol-reactive group to either end or both ends.
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公开(公告)号：US20170121445A1
公开(公告)日：2017-05-04
申请号：US15353451
申请日：2016-11-16
IPC分类号： C08G12/06 , C08G12/00 , C07C251/18 , C08G12/08 , C07C251/24 , C07C251/04
CPC分类号： C08G12/06 , C07C251/04 , C07C251/08 , C07C251/18 , C07C251/24 , C07C2101/14 , C07C2601/14 , C08G12/00 , C08G12/08
摘要： Methods, compounds, and compositions described herein generally relate to polyalkylamines and syntheses thereof. In some embodiments, a chemical compound has the formula: Each instance of R is independently selected from the group consisting of aryl, alkyl, and polyether. Each instance of R′ is independently selected from the group consisting of hydrogen, alkyl, aryl, cycloalkyl, polyether, and alcohol. Each instance of Q and Z is independently a covalent bond or selected from the group consisting of alkyl and aralkyl.
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