公开(公告)号：US20020068805A1

公开(公告)日：2002-06-06

申请号：US09739257

申请日：2000-12-19

申请人： JSR Corporation

发明人： Satoshi Futami ,  Kouji Tamori ,  Katsuhiko Tsuruoka

IPC分类号： C08F226/02

CPC分类号： D21H19/42 ,  C08F257/02 ,  C08F265/04 ,  C08F265/08 ,  C08F271/00 ,  C08L51/003 ,  C09D151/003 ,  D21H21/54 ,  C08L2666/02

摘要： An object of the present invention is to provide cationic hollow crosslinked polymer particles that maintain a cationic property over a wide pH range, has adequate strength, and is favorable for use in filled paper, pigments for coating paper, additives for paints, fillers for resins, rubbers, and the like. Another object of the present invention is to provide a method of producing the abovementioned cationic hollow crosslinked polymer particles with excellent characteristics in a stable manner. The hollow crosslinked polymer particles of the present invention are characterized in that (I) the zeta potential as measured in an aqueous medium of pH 2 to 9 is in the range of null5 to null100 mV, (II) the volume hollowness is in the range of 1 to 80%, and (III) the average particle diameter is in the range of 0.03 to 10 nullm. This hollow crosslinked polymer particles are produced by a method that (a) 1 to 99.99 weight % of a crosslinking monomer, (b) 0.01 to 15 weight % of a cationic monomer, and (c) 0 to 98.99 weight % of a copolymerizable monomer that is non-crosslinking and nonionic (the total amount of the monomers being 100 weight %) are polymerized under the presence of polymer particles that are swellable by at least one of the above monomers. This hollow crosslinked cationic polymer particles are utilized for paint composition, cationic electrodeposition paint composition, resin composition, filled paper, paper coating composition, and coated paper, and the like.

摘要翻译： 本发明的目的是提供在宽pH范围内保持阳离子性能的阳离子中空交联聚合物颗粒，具有足够的强度，并且有利于用于填充纸，涂料用颜料，涂料用添加剂，树脂填料 ，橡胶等。 本发明的另一个目的是提供以稳定的方式制备具有优异特性的上述阳离子中空交联聚合物颗粒的方法。 本发明的中空交联聚合物颗粒的特征在于（I）在pH 2至9的水性介质中测得的ζ电位在+5至+ 100mV的范围内，（II）体积空心度在 1〜80％的范围，（III）的平均粒径为0.03〜10μm的范围。 该中空交联聚合物颗粒通过以下方法制备：（a）1至99.99重量％的交联单体，（b）0.01至15重量％的阳离子单体，和（c）0至98.99重量％的可共聚单体 即非交联和非离子（单体的总量为100重量％）在由至少一种上述单体可溶胀的聚合物颗粒的存在下聚合。 该中空交联阳离子聚合物颗粒用于涂料组合物，阳离子电沉积漆组合物，树脂组合物，填充纸，纸涂层组合物和涂布纸等。