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公开(公告)号：US09783548B2
公开(公告)日：2017-10-10
申请号：US15038107
申请日：2014-11-17
IPC分类号： C07D301/12 , C07D301/03 , C07D493/04 , B01J23/30
CPC分类号： C07D493/04 , B01J23/30 , C07D301/12
摘要： A method for producing an epoxy compound by reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of the compound having a carbon-carbon double bond, aqueous hydrogen peroxide, a powder of a solid catalyst support and a powder of a solid catalyst, wherein the solid catalyst comprises an isopolyacid, and the isopolyacid is produced from a catalyst raw material comprising (a) tungstic acid or a salt thereof and (b) at least one selected from the group consisting of a salt of an alkaline earth metal and a cationic polymer.
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公开(公告)号：US09266899B2
公开(公告)日：2016-02-23
申请号：US14402398
申请日：2013-04-26
IPC分类号： C07D303/00 , C07D493/04 , C07D301/12 , B01J23/30
CPC分类号： C07D493/04 , B01J23/30 , C07D301/12
摘要： In order to produce an epoxy compound with a less chlorine content at a higher reaction rate and yield, the present invention provides a method for producing an epoxy compound by reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of the compound having a carbon-carbon double bond, the hydrogen peroxide solution, a powdered solid catalyst support and a powdered solid catalyst all together, the solid catalyst comprising isopolyacids produced from (a) tungstic acid or a salt thereof and (b) a quaternary ammonium salt compound and/or a pyridinium salt, selected from halogen-free compounds.
摘要翻译： 为了以更高的反应速度和产率制备氯含量较低的环氧化合物，本发明提供了通过使碳 - 碳双键的化合物与过氧化氢共存而制备环氧化合物的方法 具有碳 - 碳双键的化合物，过氧化氢溶液，粉末状固体催化剂载体和粉末状固体催化剂都在一起，所述固体催化剂包含由（a）钨酸或其盐制备的异多酸和（b）季铵 盐化合物和/或选自无卤素化合物的吡啶鎓盐。
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公开(公告)号：US09284326B2
公开(公告)日：2016-03-15
申请号：US14402394
申请日：2013-04-26
IPC分类号： C07D303/00 , C07D493/04 , C07D301/12
CPC分类号： C07D493/04 , C07D301/12
摘要： The present invention provides a method for producing an epoxy compound by expoxidation of an olefin compound with good productivity wherein a compound having a carbon-carbon double bond is reacted with hydrogen peroxide in the coexistence of (a) a compound having a carbon-carbon double bond, (b) a hydrogen peroxide solution, (c) a powdered solid catalyst support and (d) a powdered catalyst and optionally (e) an organic solvent, the total mass of (c) and (d) being 100 percent by mass or less on the basis of the total mass of (a), (b) and (e).
摘要翻译： 本发明提供一种通过以高生产率对烯烃化合物进行过氧化生产环氧化合物的方法，其中具有碳 - 碳双键的化合物与过氧化氢反应，共同存在（a）具有碳 - 碳双键的化合物 （b）过氧化氢溶液，（c）粉末状固体催化剂载体和（d）粉末状催化剂和任选地（e）有机溶剂，（c）和（d）的总质量为100质量％ （a），（b）和（e）的总质量。
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公开(公告)号：US20150141677A1
公开(公告)日：2015-05-21
申请号：US14402481
申请日：2013-04-26
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , C07D493/04
摘要： A method is provided for carrying out epoxidation of an olefin compound with good productivity. The method produces an epoxy compound by reacting a compound having a carbon-carbon double bond with hydrogen peroxide by carrying out repeatedly or continuously the following steps: (1) reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of (a) the compound having a carbon-carbon double bond, (b) a hydrogen peroxide solution, (c) a powdered solid catalyst support, and (d) a powdered solid catalyst, and optionally further (e) an organic solvent to produce an epoxy compound; (2) separating the epoxy compound reaction product from the reaction mixture produced in (1); and (3) adding (d) and also adding (a), (b), (c), and optionally further (e) to the mixture of the powdered solid catalyst support and powdered solid catalyst after separating the reaction product in (2).
摘要翻译： 提供了以高生产率进行烯烃化合物的环氧化的方法。 该方法通过反复或连续地进行以下步骤使具有碳 - 碳双键的化合物与过氧化氢反应生成环氧化合物：（1）使具有碳 - 碳双键的化合物与过氧化氢共存 （a）具有碳 - 碳双键的化合物，（b）过氧化氢溶液，（c）粉末状固体催化剂载体和（d）粉末状固体催化剂，以及任选地进一步（e）有机溶剂以产生 环氧化合物; （2）从（1）中制备的反应混合物中分离环氧化合物反应产物; 和（3）在将（2）中的反应产物分离后，将粉末状固体催化剂载体和粉末状固体催化剂的混合物加入（d）并且还加入（a），（b），（c） ）。
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公开(公告)号：US20150141676A1
公开(公告)日：2015-05-21
申请号：US14402398
申请日：2013-04-26
IPC分类号： C07D493/04
CPC分类号： C07D493/04 , B01J23/30 , C07D301/12
摘要： In order to produce an epoxy compound with a less chlorine content at a higher reaction rate and yield, the present invention provides a method for producing an epoxy compound by reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of the compound having a carbon-carbon double bond, the hydrogen peroxide solution, a powdered solid catalyst support and a powdered solid catalyst all together, the solid catalyst comprising isopolyacids produced from (a) tungstic acid or a salt thereof and (b) a quaternary ammonium salt compound and/or a pyridinium salt, selected from halogen-free compounds.
摘要翻译： 为了以更高的反应速度和产率制备氯含量较低的环氧化合物，本发明提供了通过使碳 - 碳双键的化合物与过氧化氢共存而制备环氧化合物的方法 具有碳 - 碳双键的化合物，过氧化氢溶液，粉末状固体催化剂载体和粉末状固体催化剂都在一起，所述固体催化剂包含由（a）钨酸或其盐制备的异多酸和（b）季铵 盐化合物和/或选自无卤素化合物的吡啶鎓盐。
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公开(公告)号：US20150094479A1
公开(公告)日：2015-04-02
申请号：US14402394
申请日：2013-04-26
IPC分类号： C07D493/04
CPC分类号： C07D493/04 , C07D301/12
摘要： The present invention provides a method for producing an epoxy compound by expoxidation of an olefin compound with good productivity wherein a compound having a carbon-carbon double bond is reacted with hydrogen peroxide in the coexistence of (a) a compound having a carbon-carbon double bond, (b) a hydrogen peroxide solution, (c) a powdered solid catalyst support and (d) a powdered catalyst and optionally (e) an organic solvent, the total mass of (c) and (d) being 100 percent by mass or less on the basis of the total mass of (a), (b) and (e).
摘要翻译： 本发明提供一种通过以高生产率对烯烃化合物进行过氧化生产环氧化合物的方法，其中具有碳 - 碳双键的化合物与过氧化氢反应，共同存在（a）具有碳 - 碳双键的化合物 （b）过氧化氢溶液，（c）粉末状固体催化剂载体和（d）粉末状催化剂和任选地（e）有机溶剂，（c）和（d）的总质量为100质量％ （a），（b）和（e）的总质量。
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公开(公告)号：US09212188B2
公开(公告)日：2015-12-15
申请号：US14402376
申请日：2013-04-26
IPC分类号： C07D301/03 , C07D493/04 , C07D301/12 , B01J23/30
CPC分类号： C07D493/04 , B01J23/30 , C07D301/12
摘要： The present invention provides a method for producing an alicyclic diepoxy compound at a higher yield by carrying out epoxidation of an alicyclic olefin compound at a higher reaction rate. The method is a method for producing an alicyclic diepoxy compound represented by formula (1) below by reacting an alicyclic olefin compound represented by formula (2) below with hydrogen peroxide in the coexistence of the alicyclic olefin compound represented by formula (2) below, a hydrogen peroxide solution, a powdered solid catalyst support and a powdered solid catalyst all together: wherein R1 to R12 are each hydrogen, halogen, an alkyl group optionally having halogen or an alkoxy group optionally having a substituent.
摘要翻译： 本发明通过以更高的反应速率进行脂环式烯烃化合物的环氧化，提供了以更高的收率生产脂环式二环氧化合物的方法。 该方法是通过下述式（1）表示的脂环式二环氧化合物与下式（2）表示的脂环族烯烃化合物共存而使下述式（2）表示的脂环式烯烃化合物与过氧化氢反应来制造脂环式二环氧化合物的方法， 过氧化氢溶液，粉末状固体催化剂载体和粉末状固体催化剂都在一起：其中R1至R12各自为氢，卤素，任选具有卤素的烷基或任选具有取代基的烷氧基。
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公开(公告)号：US09187443B2
公开(公告)日：2015-11-17
申请号：US14402481
申请日：2013-04-26
IPC分类号： C07D303/00 , C07D301/12 , C07D493/04
CPC分类号： C07D301/12 , C07D493/04
摘要： A method is provided for carrying out epoxidation of an olefin compound with good productivity. The method produces an epoxy compound by reacting a compound having a carbon-carbon double bond with hydrogen peroxide by carrying out repeatedly or continuously the following steps: (1) reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of (a) the compound having a carbon-carbon double bond, (b) a hydrogen peroxide solution, (c) a powdered solid catalyst support, and (d) a powdered solid catalyst, and optionally further (e) an organic solvent to produce an epoxy compound; (2) separating the epoxy compound reaction product from the reaction mixture produced in (1); and (3) adding (d) and also adding (a), (b), (c), and optionally further (e) to the mixture of the powdered solid catalyst support and powdered solid catalyst after separating the reaction product in (2).
摘要翻译： 提供了以高生产率进行烯烃化合物的环氧化的方法。 该方法通过反复或连续地进行以下步骤使具有碳 - 碳双键的化合物与过氧化氢反应生成环氧化合物：（1）使具有碳 - 碳双键的化合物与过氧化氢共存 （a）具有碳 - 碳双键的化合物，（b）过氧化氢溶液，（c）粉末状固体催化剂载体和（d）粉末状固体催化剂，以及任选地进一步（e）有机溶剂以产生 环氧化合物; （2）从（1）中制备的反应混合物中分离环氧化合物反应产物; 和（3）在将（2）中的反应产物分离后，将粉末状固体催化剂载体和粉末状固体催化剂的混合物加入（d）并且还加入（a），（b），（c） ）。
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公开(公告)号：US20150141675A1
公开(公告)日：2015-05-21
申请号：US14402376
申请日：2013-04-26
IPC分类号： C07D493/04
CPC分类号： C07D493/04 , B01J23/30 , C07D301/12
摘要： The present invention provides a method for producing an alicyclic diepoxy compound at a higher yield by carrying out epoxidation of an alicyclic olefin compound at a higher reaction rate. The method is a method for producing an alicyclic diepoxy compound represented by formula (1) below by reacting an alicyclic olefin compound represented by formula (2) below with hydrogen peroxide in the coexistence of the alicyclic olefin compound represented by formula (2) below, a hydrogen peroxide solution, a powdered solid catalyst support and a powdered solid catalyst all together: wherein R1 to R12 are each hydrogen, halogen, an alkyl group optionally having halogen or an alkoxy group optionally having a substituent.
摘要翻译： 本发明通过以更高的反应速率进行脂环式烯烃化合物的环氧化，提供了以更高的收率生产脂环式二环氧化合物的方法。 该方法是通过下述式（1）表示的脂环式二环氧化合物与下式（2）表示的脂环族烯烃化合物共存而使下述式（2）表示的脂环式烯烃化合物与过氧化氢反应来制造脂环式二环氧化合物的方法， 过氧化氢溶液，粉末状固体催化剂载体和粉末状固体催化剂都在一起：其中R1至R12各自为氢，卤素，任选具有卤素的烷基或任选具有取代基的烷氧基。
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