公开(公告)号：US5462738A

公开(公告)日：1995-10-31

申请号：US215510

申请日：1994-03-22

申请人： James H. LeFiles ,  Evelyn J. Taylor ,  Mark A. Crawford

发明人： James H. LeFiles ,  Evelyn J. Taylor ,  Mark A. Crawford

IPC分类号： A01N25/08 ,  A01N25/10 ,  A01N25/14 ,  A01N25/22 ,  A01N59/20

CPC分类号： A01N59/20

摘要： There is disclosed a granular copper hydroxide dry flowable bactericide/fungicide having improved biological activity and a method for making and using same. A bactericide/fungicide is made by forming a homogeneous aqueous slurry containing between approximately 5% and 20% by weight (based on the total weight of all dry ingredients) of a first dispersant selected from the group consisting of partially neutralized polyacrylic acid having a pH of between approximately 5 and 10 and an average molecular weight of between approximately 1,000 and 10,000 and lignin sulfonate, between approximately 0% and 5% by weight (based on the total weight of all dry ingredients) of a second dispersant for bentonite clay, between approximately 40% and 80% by weight (based on the total weight of all dry ingredients) phosphate stabilized cupric hydroxide and between approximately 6% and 30% by weight (based on the total weight of all dry ingredients) bentonite clay; and spray drying the slurry to thereby form a dry free flowing granular bactericide/fungicide product. The slurry can also include antifoam and wetting agents. Other partially neutralized polycarboxylic acid polymers useful as the fast dispersant are also disclosed.

摘要翻译： 公开了具有改善的生物活性的颗粒状氢氧化铜干燥可流动杀菌剂/杀真菌剂及其制备和使用方法。 通过形成含有约5％至20％重量（基于所有干成分的总重量）的第一分散剂的均匀含水浆料制备杀菌剂/杀真菌剂，所述第一分散剂选自部分中和的具有pH的聚丙烯酸 在约5至10之间，平均分子量为约1,000至10,000和木质素磺酸盐，约0重量％至5重量％（基于所有干成分的总重量）的膨润土粘土的第二分散剂之间，介于 约40重量％和80重量％（基于所有干成分的总重量）磷酸盐稳定的氢氧化铜和约6重量％至30重量％（基于所有干成分的总重量）膨润土; 并喷雾干燥该浆料，从而形成干燥自由流动的颗粒状杀菌剂/杀真菌剂产品。 浆料还可以包括消泡剂和润湿剂。 还公开了可用作快速分散剂的其它部分中和的聚羧酸聚合物。

公开(公告)号：US5298253A

公开(公告)日：1994-03-29

申请号：US928148

申请日：1992-08-11

申请人： James H. LeFiles ,  Evelyn J. Taylor ,  Mark A. Crawford

发明人： James H. LeFiles ,  Evelyn J. Taylor ,  Mark A. Crawford

IPC分类号： A01N25/08 ,  A01N25/10 ,  A01N25/14 ,  A01N25/22 ,  A01N59/20 ,  A61K31/78

CPC分类号： A01N59/20

摘要： There is disclosed a granular copper hydroxide dry flowable bactericide/fungicide having improved biological activity and a method for making and using same. A bactericide/fungicide is made by forming a homogeneous aqueous slurry containing between approximately 5% and 20% by weight (based on the total weight of all dry ingredients) of a first dispersant selected from the group consisting of partially neutralized polyacrylic acid having a pH of between approximately 5 and 10 and an average molecular weight of between approximately 1,000 and 10,000 and lignin sulfonate, between approximately 0% and 5% by weight (based on the total weight of all dry ingredients) of a second dispersant for bentonite clay, between approximately 40% and 80% by weight (based on the total weight of all dry ingredients) phosphate stabilized cupric hydroxide and between approximately 6% and 30% by weight (based on the total weight of all dry ingredients) bentonite clay; and spray drying the slurry to thereby form a dry free flowing granular bactericide/fungicide product. The slurry can also include antifoam and wetting agents. Other partially neutralized polycarboxylic acid polymers useful as the first dispersant are also disclosed.

摘要翻译： 公开了具有改善的生物活性的颗粒状氢氧化铜干燥可流动杀菌剂/杀真菌剂及其制备和使用方法。 通过形成含有约5％至20％重量（基于所有干成分的总重量）的第一分散剂的均匀含水浆料制备杀菌剂/杀真菌剂，所述第一分散剂选自部分中和的具有pH的聚丙烯酸 在约5至10之间，平均分子量为约1,000至10,000和木质素磺酸盐，约0重量％至5重量％（基于所有干成分的总重量）的膨润土粘土的第二分散剂之间，介于 约40重量％和80重量％（基于所有干成分的总重量）磷酸盐稳定的氢氧化铜和约6重量％至30重量％（基于所有干成分的总重量）膨润土; 并喷雾干燥该浆料，从而形成干燥自由流动的颗粒状杀菌剂/杀真菌剂产品。 浆料还可以包括消泡剂和润湿剂。 还公开了可用作第一分散剂的其它部分中和的聚羧酸聚合物。

公开(公告)号：US06471976B1

公开(公告)日：2002-10-29

申请号：US08387397

申请日：1995-02-13

申请人： Evelyn J. Taylor ,  Mark A. Crawford

发明人： Evelyn J. Taylor ,  Mark A. Crawford

IPC分类号： A61K3144

CPC分类号： A01N37/04 ,  A01N59/20 ,  A01N2300/00

摘要： There is disclosed an improved copper complex bactericide/fungicide and a method of making and using the same. The improved bactericide/fungicide is prepared by forming an aqueous solution of a partially neutralized, water-soluble polycarboxylic acid having a molecular weight of between approximately 1,000 and 300,000 and a pH of between approximately 3 and 9. To this aqueous solution is added a copper-containing compound which when combined with said aqueous solution releases copper (II) ions which will form a water-soluble complex with said partially neutralized polycarboxylic acid. The water-soluble copper complex is applied to plants to prevent or inhibit bacterial and fungal disease growth thereon.

摘要翻译： 公开了一种改进的铜络合物杀菌剂/杀菌剂及其制备和使用方法。 改进的杀菌剂/杀真菌剂是通过形成分子量在大约1000和300,000之间的部分中和的水溶性多元羧酸的水溶液和约3和9之间的pH来制备的。向该水溶液中加入铜 当与所述水溶液组合时，会释放与所述部分中和的多元羧酸形成水溶性络合物的铜（II）离子。 将水溶性铜络合物施用于植物以防止或抑制其上的细菌和真菌疾病生长。