Process to produce aminocarboxylic acids containing low residual salt
    2.
    发明授权
    Process to produce aminocarboxylic acids containing low residual salt 失效
    生产含有低残留盐的氨基羧酸的方法

    公开(公告)号:US5491259A

    公开(公告)日:1996-02-13

    申请号:US305111

    申请日:1994-09-13

    CPC分类号: C07C227/40 C07C227/18

    摘要: A method for producing an aqueous solution of an aminocarboxylic acid from an aqueous solution of an alkali metal salt of the aminocarboxylic acid is disclosed. The first step of the method is to adjust the pH of the aqueous solution of the alkali metal salt of the aminocarboxylic acid to between about 1.0 and about 3.0. This is done by adding a monovalent inorganic acid to the aqueous solution of the alkali metal salt of the aminocarboxylic acid to form an aqueous feed solution containing protonated aminocarboxylic acid and an inorganic alkali salt having an inorganic anion and an alkali metal cation. The second step of the method is to pass the aqueous feed solution through at least one membrane using a diafiltration process to separate the aqueous feed solution into an aqueous permeate solution, containing the alkali metal cation, and an aqueous retentate solution containing the aminocarboxylic acid.

    摘要翻译: 公开了一种由氨基羧酸的碱金属盐的水溶液制备氨基羧酸的水溶液的方法。 该方法的第一步是将氨基羧酸的碱金属盐的水溶液的pH调节至约1.0至约3.0。 这是通过向氨基羧酸的碱金属盐的水溶液中加入一价无机酸形成含有质子化氨基羧酸的水性进料溶液和具有无机阴离子和碱金属阳离子的无机碱金属盐来进行的。 该方法的第二步是使用渗滤方法将含水进料溶液通过至少一个膜,以将含水进料溶液分离成含有碱金属阳离子的含水渗透液和含有氨基羧酸的含水滞留物溶液。

    Dialysis separation of heat stable organic amine salts in an acid gas
absorption process
    3.
    发明授权
    Dialysis separation of heat stable organic amine salts in an acid gas absorption process 失效
    酸性气体吸收过程中热稳定性有机胺盐的透析分离

    公开(公告)号:US5622681A

    公开(公告)日:1997-04-22

    申请号:US513165

    申请日:1995-08-09

    摘要: There is disclosed an organic amine scrubbing process for acid gas abatement of gas streams. The process comprises Donnan dialysis of an absorbent solution to separate and convert organic amine heat stable salts back to free amine absorbent using an anion exchange or neutral membrane. The organic amine absorbent may be an alkanolamine, a substituted or unsubstituted 5-7 member heterocyclic amine or any organic amine suitable for acid gas scrubbing. There is also disclosed a dialysis cell comprising a two compartment cell separated by a membrane. The cell includes a charge of an organic amine high in the organic amine heat stable salt concentration in one compartment and a charge of a base solution in the other compartment. Also disclosed is a process for abating acid gases wherein the organic amine absorbent is regenerated by Donnan dialysis, and an apparatus for effecting the regeneration.

    摘要翻译: 公开了一种用于气体消除气流的有机胺洗涤方法。 该方法包括使用阴离子交换或中性膜将吸收剂溶液的Donnan透析分离并将有机胺热稳定盐转化回游离胺吸收剂。 有机胺吸收剂可以是链烷醇胺,取代或未取代的5-7元杂环胺或适用于酸性气体洗涤的任何有机胺。 还公开了一种透析池,其包括由隔膜隔开的两室细胞。 电池包括在一个隔室中有机胺热稳定盐浓度高的有机胺的电荷和另一隔室中的碱溶液的电荷。 还公开了一种减轻酸性气体的方法,其中有机胺吸收剂由Donnan透析再生,以及用于进行再生的装置。