摘要:
Surfactant systems are provided that, upon contact with an oil, can produce a Windsor Type III middle phase microemulsion at a total surfactant concentration of 1.5% to 1.0% or less based on the weight of water in the surfactant system, without the need for a cosolvent or linking molecule. The microemulsions can have a separation time less than about 2 hours and even less than about 15 minutes.
摘要:
Some ground water sites are capable of achieving risk-based closure without remedial efforts due to the soil's natural intrinsic remediation. However, in many cases this may not be possible due to the magnitude of the contamination. Surfactant enhanced intrinsic remediation is capable of enhancing natural remediation in several ways. First, by introducing the surfactant above its Krafft temperature when the ground water temperature is below the surfactant Krafft temperature, it is possible to install a permeable, sorptive wall that significantly decreases the contaminant migration, thereby improving the opportunity for natural intrinsic remediation to mitigate the contamination. If the contaminant levels are too great for this approach, as may be the case when “source zone” soil contamination is present, the approach is coupled with active extraction/ surfactant enhanced intrinsic remediation of the “source” zone (e.g., surfactant flushing). Thus, either by itself or in combination with other activities, an enhanced intrinsic remediation approach will allow for a site to undergo risk-based closure.